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Fenton氧化法修复石油污染土壤的研究进展

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李方敏, 柳红霞. Fenton氧化法修复石油污染土壤的研究进展[J]. 环境化学, 2012, 31(11): 1759-1766.
引用本文: 李方敏, 柳红霞. Fenton氧化法修复石油污染土壤的研究进展[J]. 环境化学, 2012, 31(11): 1759-1766.
shu
LI Fangmin, LIU Hongxia. Remediation of petroleum contaminated soil by Fenton oxidation method: A review[J]. Environmental Chemistry, 2012, 31(11): 1759-1766.
Citation: LI Fangmin, LIU Hongxia. Remediation of petroleum contaminated soil by Fenton oxidation method: A review[J]. Environmental Chemistry, 2012, 31(11): 1759-1766.
shu

Fenton氧化法修复石油污染土壤的研究进展

  • 1.

    长江大学化学与环境工程学院, 荆州, 434023;

  • 2.

    长江中游湿地农业教育部工程技术研究中心, 荆州, 434025

  • 基金项目:

    中国科学院生态环境研究中心城市与区域生态国家重点实验室开放基金(SKLURE2012-2-2)和国家自然科学基金(41271482)资助.

Remediation of petroleum contaminated soil by Fenton oxidation method: A review

  • 1.

    School of Chemical and Environmental Engineering, Yangtze University, Jingzhou, 434023, China;

  • 2.

    Engineering Research Center of Wetland Agriculture in Central Yangtze, Ministry of Education, Jingzhou, 434025, China

  • Fund Project:

  • 摘要: 传统的Fenton氧化法(Fe2+/H2O2)因反应速度过快、需要定期补充Fe2+、控制pH值≤3等方面的限制而影响到石油烃类污染土壤的修复效果.本文综述了近年来Fenton反应中氧化剂、催化剂的改进及其对土壤中石油污染物的去除效率,揭示了土壤性质、反应条件、污染物结构及非均相催化剂比表面积等因素对去除效率的影响,介绍了超声波前置处理后,Fenton试剂与土壤上解吸的石油污染物接触几率的增加及石油烃类可生物降解性的提高,促进了微生物的后续处理效果,并对该领域的研究趋势进行了展望.
    Abstract: The traditional Fenton oxidation (Fe2+/H2O2) reaction has some drawbacks when used for soil remediation, including rapid reaction rate, regular additions of Fe2+and the requirement of low pH≤3, which limited its remediation efficiency for petroleum hydrocarbons contaminated soil. In this paper, recent progress on modified oxidants and catalysts of the Fenton reaction, and effects of the modification on removal efficiencies in petroleum-contaminated soils were reviewed. Soil properties, reaction conditions, pollutant structure and the heterogeneous catalyst specific surface areas were major factors influencing the removal efficiencies. The method of ultrasonic pre-treatment was introduced, which increases the contact probability of Fenton reagent with the petroleum contaminants desorbed from soils,and it improves biodegradability of petroleum hydrocarbon pollutants by the subsequent microbial processes. The research trends in this field were also prospected.
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  • 收稿日期:  2012-02-05
李方敏, 柳红霞. Fenton氧化法修复石油污染土壤的研究进展[J]. 环境化学, 2012, 31(11): 1759-1766.
引用本文: 李方敏, 柳红霞. Fenton氧化法修复石油污染土壤的研究进展[J]. 环境化学, 2012, 31(11): 1759-1766.
shu
LI Fangmin, LIU Hongxia. Remediation of petroleum contaminated soil by Fenton oxidation method: A review[J]. Environmental Chemistry, 2012, 31(11): 1759-1766.
Citation: LI Fangmin, LIU Hongxia. Remediation of petroleum contaminated soil by Fenton oxidation method: A review[J]. Environmental Chemistry, 2012, 31(11): 1759-1766.
shu

Fenton氧化法修复石油污染土壤的研究进展

  • 1.  长江大学化学与环境工程学院, 荆州, 434023;
  • 2.  长江中游湿地农业教育部工程技术研究中心, 荆州, 434025
  • 收稿日期:  2012-02-05
基金项目:

中国科学院生态环境研究中心城市与区域生态国家重点实验室开放基金(SKLURE2012-2-2)和国家自然科学基金(41271482)资助.

摘要: 传统的Fenton氧化法(Fe2+/H2O2)因反应速度过快、需要定期补充Fe2+、控制pH值≤3等方面的限制而影响到石油烃类污染土壤的修复效果.本文综述了近年来Fenton反应中氧化剂、催化剂的改进及其对土壤中石油污染物的去除效率,揭示了土壤性质、反应条件、污染物结构及非均相催化剂比表面积等因素对去除效率的影响,介绍了超声波前置处理后,Fenton试剂与土壤上解吸的石油污染物接触几率的增加及石油烃类可生物降解性的提高,促进了微生物的后续处理效果,并对该领域的研究趋势进行了展望.

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