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微波-Fenton对沼液中抗生素和激素的高级氧化

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林于廉, 田伟, 杨志敏, 陈玉成, 陈庆华, 李家杰. 微波-Fenton对沼液中抗生素和激素的高级氧化[J]. 环境工程学报, 2013, 7(1): 164-168.
引用本文: 林于廉, 田伟, 杨志敏, 陈玉成, 陈庆华, 李家杰. 微波-Fenton对沼液中抗生素和激素的高级氧化[J]. 环境工程学报, 2013, 7(1): 164-168.
shu
Lin Yulian, Tian Wei, Yang Zhimin, Chen Yucheng, Chen Qinghua, Li Jiajie. Advanced oxidation of olaquindox and tetracydline antibiotics in biogas slurry by microwave-Fenton[J]. Chinese Journal of Environmental Engineering, 2013, 7(1): 164-168.
Citation: Lin Yulian, Tian Wei, Yang Zhimin, Chen Yucheng, Chen Qinghua, Li Jiajie. Advanced oxidation of olaquindox and tetracydline antibiotics in biogas slurry by microwave-Fenton[J]. Chinese Journal of Environmental Engineering, 2013, 7(1): 164-168.
shu

微波-Fenton对沼液中抗生素和激素的高级氧化

  • 1.

    重庆大学城市建设与环境工程学院,重庆 400045

  • 2.

    重庆建筑工程职业学院, 重庆400039

  • 3.

    西南大学资源环境学院,重庆 400716

  • 基金项目:

    重庆市科技攻关重点项目(CSTC2009AB7027)

  • 中图分类号: X703

Advanced oxidation of olaquindox and tetracydline antibiotics in biogas slurry by microwave-Fenton

  • 1.

    College of Urban Construction and Environmental Engineering, Chongqing University, Chongqing 400045, China

  • 2.

    Chongqing Vocational College of Architechural Engineering, Chongqing 400039, China

  • 3.

    College of Resources and Environment, Southwest University, Chongqing 400716, China

  • Fund Project:

  • 摘要: 采用微波强化Fenton氧化处理系统,研究H2O2浓度、Fe2+浓度、初始pH、微波辐射时间和微波辐射功率对沼液中喹乙醇、土霉素、四环素及金霉素降解效果的影响。结果发现,采用微波强化Fenton氧化降解沼液中抗生素与激素的最优条件是:H2O2浓度为40 mg/L、Fe2+浓度为12 mg/L、初始pH为4、微波辐射时间为2 min、微波辐射功率为中火(445 W),沼液中喹乙醇、土霉素、四环素、金霉素和COD的去除率分别达到67%、93%、91%、88%和46%。在水浴条件下,与单独微波辐射和单独Fenton相比,微波强化Fenton氧化有明显的优越性。
    Abstract: An experimental system of microwave-assisted Fenton oxidation was designed to degrade olaquindox,oxytetracycline,tetracycline and chlortracycline in biogas slurry. The influences of H2O2 mass concentration,Fe2+ mass concentration,initial pH,microwave irradiation time and power on degradation efficiency were investigated. The optimal conditions were determined as follows:the H2O2 dosage of 40 mg/L,the Fe2+ dosage of 12 mg/L,initial pH of 4,microwave reaction of 2 min and power of 445 W. Under the optimum conditions,the removal rate was 67% for olaquindox,93% for oxytetracycline,91% for tetracycline,88% for chlortracycline and 46% for COD. It is known from the contrast experiments that microwave-assisted Fenton oxidation has obvious supority.
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出版历程
  • 收稿日期:  2012-01-01
  • 刊出日期:  2013-01-16
林于廉, 田伟, 杨志敏, 陈玉成, 陈庆华, 李家杰. 微波-Fenton对沼液中抗生素和激素的高级氧化[J]. 环境工程学报, 2013, 7(1): 164-168.
引用本文: 林于廉, 田伟, 杨志敏, 陈玉成, 陈庆华, 李家杰. 微波-Fenton对沼液中抗生素和激素的高级氧化[J]. 环境工程学报, 2013, 7(1): 164-168.
shu
Lin Yulian, Tian Wei, Yang Zhimin, Chen Yucheng, Chen Qinghua, Li Jiajie. Advanced oxidation of olaquindox and tetracydline antibiotics in biogas slurry by microwave-Fenton[J]. Chinese Journal of Environmental Engineering, 2013, 7(1): 164-168.
Citation: Lin Yulian, Tian Wei, Yang Zhimin, Chen Yucheng, Chen Qinghua, Li Jiajie. Advanced oxidation of olaquindox and tetracydline antibiotics in biogas slurry by microwave-Fenton[J]. Chinese Journal of Environmental Engineering, 2013, 7(1): 164-168.
shu

微波-Fenton对沼液中抗生素和激素的高级氧化

  • 1.  重庆大学城市建设与环境工程学院,重庆 400045
  • 2.  重庆建筑工程职业学院, 重庆400039
  • 3.  西南大学资源环境学院,重庆 400716
  • 收稿日期:  2012-01-01
基金项目:

重庆市科技攻关重点项目(CSTC2009AB7027)

摘要: 采用微波强化Fenton氧化处理系统,研究H2O2浓度、Fe2+浓度、初始pH、微波辐射时间和微波辐射功率对沼液中喹乙醇、土霉素、四环素及金霉素降解效果的影响。结果发现,采用微波强化Fenton氧化降解沼液中抗生素与激素的最优条件是:H2O2浓度为40 mg/L、Fe2+浓度为12 mg/L、初始pH为4、微波辐射时间为2 min、微波辐射功率为中火(445 W),沼液中喹乙醇、土霉素、四环素、金霉素和COD的去除率分别达到67%、93%、91%、88%和46%。在水浴条件下,与单独微波辐射和单独Fenton相比,微波强化Fenton氧化有明显的优越性。

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