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4种因子对猪场沼液产磷化氢的影响

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万金保, 杨怡, 邓觅, 万莉. 4种因子对猪场沼液产磷化氢的影响[J]. 环境工程学报, 2016, 10(9): 4902-4906. doi: 10.12030/j.cjee.201504106
引用本文: 万金保, 杨怡, 邓觅, 万莉. 4种因子对猪场沼液产磷化氢的影响[J]. 环境工程学报, 2016, 10(9): 4902-4906. doi: 10.12030/j.cjee.201504106
shu
WAN Jinbao, YANG Yi, DENG Mi, Wan Li. Effects of four factors on the production of PH3 in the treatment of pig breeding bio-slurry[J]. Chinese Journal of Environmental Engineering, 2016, 10(9): 4902-4906. doi: 10.12030/j.cjee.201504106
Citation: WAN Jinbao, YANG Yi, DENG Mi, Wan Li. Effects of four factors on the production of PH3 in the treatment of pig breeding bio-slurry[J]. Chinese Journal of Environmental Engineering, 2016, 10(9): 4902-4906. doi: 10.12030/j.cjee.201504106
shu

4种因子对猪场沼液产磷化氢的影响

  • 1.

    南昌大学资源环境与化工学院, 鄱阳湖环境与资源利用教育部重点实验室, 南昌 330031

  • 基金项目:

    江西省教育厅科技落地计划项目（GJJ12001326）

  • 中图分类号: X131.2

Effects of four factors on the production of PH3 in the treatment of pig breeding bio-slurry

  • 1.

    Key Laboratory of Poyang Lake of Ministry of Education, School of Resources Environment & Chemical Engineering, Nanchang University, Nanchang 330031, China

  • Fund Project:

  • 摘要: 以猪场沼液为研究对象，在ASBR（厌氧序批式反应器）内采用充氩吹托带出PH3的方式，在680 nm处用分光光度法测定PH3氧化成磷酸盐后的浓度，以研究pH、TP、COD、Cu2+这4种因素对猪场沼液产磷化氢的影响，为揭示PH3转化过程对猪场废水中其他形态磷的补充提供有效的理论依据。结果表明：在偏酸性的实验条件下，PH3产量明显较中性和碱性条件下产量多；PH3产量与TP在一定程度上呈正相关；COD在270~620 mg·L-1范围时能促进PH3的产生，而在630~980 mg·L-1范围时则抑制PH3的产生；Cu2+浓度处于1.2~4.0 mg·L-1时，Cu2+浓度与PH3产量呈负相关。
    Abstract: Piggery biogas slurry was used as the research object. The PH3 was stripped from the ASBR reactor by argon, and the concentration of phosphate, oxidated from the PH3, was determined by spectrophotometry under a wavelength of 680 nm. The effects of pH, TP, COD, and Cu2+ on the production of PH3 were evaluated. Taking the results into account, a number of comments can be made. The production of PH3 in a meta-acid condition was clearly higher compared with those of the alkaline or neutral conditions. The production of PH3 and the concentration of TP were positively correlated to a certain extent. The COD could stimulate the production of PH3, when the concentration was in the range 270 to 620 mg·L-1. However, it could inhibit the production of PH3 when the concentration was higher (630 to 980 mg·L-1). The relationship between PH3 production and the concentration of Cu2+ was negatively correlated when the concentration of Cu2+ was in the range from 1.2 to 4.0 mg·L-1.
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  • [1] ARCHANGEL SKIJ A. D., KOPCENOVA E. V. Note on organic substances, phosphorus and vanadium deposits in the Black Sea. Isv. Akad Nauk SSSR, 1930:205-512
    [2] 曹海峰, 刘季昂, 庄亚辉, 等. 环境中磷化氢的源及厌氧条件下前体物类型的研究. 中国科学(B辑), 2000, 30(1):63-68 CAO Haifeng, LIU Ji'ang, ZHUANG Yahui, et al. Research on environment phosphine precursors under anaerobic conditions and type of source. Science in China (Series B), 2000, 30(1):63-68(in Chinese)
    [3] 俞志明, 宋秀贤. 一种海洋环境中易被忽略的磷化合物:磷化氢. 海洋与湖沼, 2002, 33(5):562-568 YU Zhiming, SONG Xiuxian. Phosphine, a phosphorus compound which used to be overlooked in study of marine environmental sciences. Oceanologia et Limnologia Sinica, 2002, 33(5):562-568(in Chinese)
    [4] 牛晓君, 耿金菊, 马宏瑞, 等. 富营养浅水湖泊中新发现的磷化氢. 中国环境科学, 2004, 24(1):85-88 NIU Xiaojun, GENG Jinju, MA Hongrui, et al. Discovery of a new phosphide-phosphine in eutrophic lakes. China Environmental Science, 2004, 24(1):85-88(in Chinese)
    [5] NIU Xiaojun, CHEN Jinju, WANG Xiaorong, et al. Temporal and spatial distributions of phosphine in Taihu Lake, China. Science of the Total Environment, 2004, 323(1/2/3):169-178
    [6] 丁丽丽, 朱益新, 梁瀚文, 等. 大型UASB系统磷化氢分布及磷平衡研究. 南京大学学报(自然科学), 2005, 41(6):620-626 DING Lili, ZHU Yixin, LIANG Hanwen, et al. Distribution of phosphine and phosphorus balance in a full-scale UASB system. Journal of Nanjing University (Natural Sciences), 2005, 41(6):620-626(in Chinese)
    [7] RUTISHAUSER B. V., BACHOFEN R. Phosphine formation from sewage sludge cultures. Anaerobe, 1999, 5(5):525-531
    [8] JENKINS R. O., MORRIS T. A., CRAIG P. J. Phosphine generation by mixed- and monoseptic-cultures of anaerobic bacteria. The Science of the Total Environment, 2000, 250(1/2/3):73-81
    [9] 孙亮. 磷化氢的释放机理及其过程研究. 广州:广州大学硕士学位论文, 2012 SUN Liang. Study on mechanism and progress of the phos-phine released. Guangzhou:Master Dissertation of Guangzhou University, 2012(in Chinese)
    [10] 杨丽萍, 易红宏, 唐晓龙, 等. 铜基改性活性炭吸附净化黄磷尾气中的PH3. 中南大学学报(自然科学版), 2011, 42(5):1489-1494 YANG Liping, YI Honghong, TANG Xiaolong, et al. Absorptive purification of PH3in yellow phosphorus off-gas by Cu-based modified activated carbon. Journal of Central South University (Science and Technology), 2011, 42(5):1489-1494(in Chinese)
    [11] 何华燕. 规模化猪场废水新型生物脱氮除磷技术研究. 南昌:南昌大学硕士学位论文, 2011 HE Huayan. Research on new technology of biological nitrogen and phosphors removal in full-scale swine wastewater. Nanchang:Master Dissertation of Nanchang University, 2011(in Chinese)
    [12] SCHMIDT J. E., AHRING B. K. Granular sludge formation in upflow anaerobic sludge blanket (UASB) reactors. Biotechnology and Bioengineering, 1996, 49(3):229-246
    [13] 万金保, 邓觅, 万莉, 等. 化学需氧量和总磷对猪场废水产磷化氢的影响. 工业水处理, 2014, 34(11):18-20 WAN Jinbao, DENG Mi, WAN Li, et al. Research on the effects of COD and TP on piggery wastewater produced phosphine. Industrial Water Treatment, 2014, 34(11):18-20(in Chinese)
    [14] 万金保, 邓觅, 何华燕, 等. 猪场废水中磷化氢释放的影响因素研究. 中国给水排水, 2013, 29(23):117-120 WAN Jinbao, DENG Mi, HE Huayan, et al. Factors Influencing release of phosphine in piggery wastewater. China Water & Wastewater, 2013, 29(23):117-120(in Chinese)
    [15] 陈琳. 上流式厌氧生物膜与生物接触氧化耦合工艺处理猪场废水的研究. 南昌:南昌大学硕士学位论文, 2011 CHEN Lin. Study of Up-flow anaerobic sludge bed and Biofilm with biological contact oxidation process in treatment of swine wastewater. Nanchang:Master Dissertation of Nanchang University, 2011(in Chinese)
    [16] 陈新焕,罗丽容,易征璇,等.工作场所空气中磷化氢测定方法的改进.光谱实验室, 2012, 29(5):2743-2745 CHEN Xinhuan, LUO Lirong, YI Zhengxuan, et al. Improvement of determination method of phosphine in the air of workplace. Spectroscopy Laboratory, 2012, 29(5):2743-2745(in Chinese)
    [17] LIU Y., YANG S. F., QIN L., et al. A thermodynamic interpretation of cell hydrophobicity in aerobic granulation. Applied Microbiology and Biotechnology, 2004, 64(3):410-415
    [18] 孙建平. 抗生素与重金属对猪场废水厌氧消化的抑制效应及其调控对策. 杭州:浙江大学博士学位论文, 2009 SUN Jianping. Inhibitory effect of antibiotics and heavy metals on anaerobic digestion of piggery wastewater and its control strategy. Hangzhou:Doctor Dissertation of Zhejiang University, 2009(in Chinese)
    [19] 李健中. 重金属对生物脱氮除磷系统中微生物的毒性影响. 广州:广州大学硕士学位论文, 2010 LI Jianzhong. Study on the Toxicity Effects of heavy metals on microbial in biological nitrogen and phosphorus removal system. Guangzhou:Master Dissertation of Guangzhou University, 2010(in Chinese)
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  • 收稿日期:  2015-05-20
  • 刊出日期:  2016-09-10
万金保, 杨怡, 邓觅, 万莉. 4种因子对猪场沼液产磷化氢的影响[J]. 环境工程学报, 2016, 10(9): 4902-4906. doi: 10.12030/j.cjee.201504106
引用本文: 万金保, 杨怡, 邓觅, 万莉. 4种因子对猪场沼液产磷化氢的影响[J]. 环境工程学报, 2016, 10(9): 4902-4906. doi: 10.12030/j.cjee.201504106
shu
WAN Jinbao, YANG Yi, DENG Mi, Wan Li. Effects of four factors on the production of PH3 in the treatment of pig breeding bio-slurry[J]. Chinese Journal of Environmental Engineering, 2016, 10(9): 4902-4906. doi: 10.12030/j.cjee.201504106
Citation: WAN Jinbao, YANG Yi, DENG Mi, Wan Li. Effects of four factors on the production of PH3 in the treatment of pig breeding bio-slurry[J]. Chinese Journal of Environmental Engineering, 2016, 10(9): 4902-4906. doi: 10.12030/j.cjee.201504106
shu

4种因子对猪场沼液产磷化氢的影响

  • 1. 南昌大学资源环境与化工学院, 鄱阳湖环境与资源利用教育部重点实验室, 南昌 330031
  • 收稿日期:  2015-05-20
基金项目:

江西省教育厅科技落地计划项目（GJJ12001326）

摘要: 以猪场沼液为研究对象，在ASBR（厌氧序批式反应器）内采用充氩吹托带出PH3的方式，在680 nm处用分光光度法测定PH3氧化成磷酸盐后的浓度，以研究pH、TP、COD、Cu2+这4种因素对猪场沼液产磷化氢的影响，为揭示PH3转化过程对猪场废水中其他形态磷的补充提供有效的理论依据。结果表明：在偏酸性的实验条件下，PH3产量明显较中性和碱性条件下产量多；PH3产量与TP在一定程度上呈正相关；COD在270~620 mg·L-1范围时能促进PH3的产生，而在630~980 mg·L-1范围时则抑制PH3的产生；Cu2+浓度处于1.2~4.0 mg·L-1时，Cu2+浓度与PH3产量呈负相关。

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