2014 Volume 8 Issue 5
Article Contents

Shen Zhiyu, Shen Yaoliang, Guo Haijuan. Removal of trace endocrine disruptors from polluted water with nanofiltration process[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1877-1882.
Citation: Shen Zhiyu, Shen Yaoliang, Guo Haijuan. Removal of trace endocrine disruptors from polluted water with nanofiltration process[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1877-1882.

Removal of trace endocrine disruptors from polluted water with nanofiltration process

  • Received Date: 03/05/2013
    Accepted Date: 11/04/2013
    Available Online: 06/05/2014
    Fund Project:
  • Several factors such as temperature, pH, initial concentration, transmembrane pressure (TMP) and running time which affect membrane flux and retention efficiencies were investigated by using DL1210 nanofiltration membrane to remove dibutyl phthalate (DBP), phthalate, bis (2-ethylhexyl) ester (DEHP), dimethoate and atrazine. The results showed that the nanofiltration process is an effective method to remove traces DBP, DEHP, dimethoate and atrazine. The retention efficiencies of nanofiltration membrane on DBP, DEHP, dimethoate and atrazine decreased with an increase in pH and temperature. And the membrane retention efficiencies on DBP and DEHP also decreased with an increase in initial concentration. However, TMP and running time have no significant impact on the membrane flux and the retention efficiencies of target pollutants. Finally, The nanofiltration process achieved the best retention efficiencies on DBP, DEHP, dimethoate and atrazine under the condition of the initial pH of 5, the initial concentration of 5 μg/L, a temperature of 5℃ and TMP of 0.4 MPa with retention efficiencies of 91.8%, 89.8%, 98.02% and 77.6%, respectively. And the effluent concentrations of DBP, DEHP, dimethoate and atrazine were 0.41, 0.49, 0.099 and 1.12 μg/L, respectively.
  • 加载中
  • [1] 中华人民共和国卫生部.生活饮用水卫生标准(GB5749-2006), 2006 Ministry of Health of the People's Republic of China. Drinking Water Sanitary Standard (GB5749-2006), 2006(in Chinese)

    Google Scholar Pub Med

    [2] 李清雪, 李曼, 梁晓.二级出水中内分泌干扰物的检测和去除实验.山西建筑, 2008, 34(2):15-16 Li Q.X., Li M., Liang X.The study on determination methods and trestment of endocrine disrupting chemicals in secondary effluent water.Shanxi Architecture, 2008, 34(2): 15-16(in Chinese)

    Google Scholar Pub Med

    [3] 邵晓玲, 马军.松花江水中13种内分泌干扰物的初步调查.环境科学学报, 2008, 28 (9):1910-1915 Shao X.L., Ma J.Preliminary investugation on 13 endocrine disrupting chemicals in the SongHua River.Acta Scientiae Circumstantiae, 2008, 28 (9):1910-1915(in Chinese)

    Google Scholar Pub Med

    [4] Wang X., C. P. Jr Leslie Grady. Comparison of biosorption isotherms for dinbutyl phthalate by live and dead bacteria. Water Research, 1994, 128(5):1247-1251

    Google Scholar Pub Med

    [5] Chen C.Y., Chen C.C.Removal of phthalate esters by alpha-cyclodextrin-linked chitosan bead. Bioresource Technology, 2007, 98(13):2578-2583

    Google Scholar Pub Med

    [6] Zhang W., Xu Z., Pan B., et al.Equilibrium and heat of adsorption of diethyl phthalate on heterogeneous adsorbents. Journal of Colloid and Interface Science, 2008, 32(1):41-47

    Google Scholar Pub Med

    [7] 柴素芬, 曾锋, 傅家谟, 等.DEHP的微生物降解性研究. 中山大学学报(自然科学版), 2000, 39(4):57-60 Chai S.F., Zeng F., Fu J.M., et al.Study of biodegradability Di(2-Ethylhexyl) phthalate.Acta Scientiarum Naturalium Universitatis Sunyatseni, 2000, 39(4):57-60(in Chinese)

    Google Scholar Pub Med

    [8] Satoshi Kaneco, Ning Li, Kumi-ko Itoh, et al.Titanium dioxide mediated solar photocatalytic degradation of thiram in aqueous solution: Kinetics and mineralization. Chemical Engineering Journal, 2009, 148(1):50-56

    Google Scholar Pub Med

    [9] Peter Roslev, Katrin Vorkamp, Jakob Aarup, et al. Degradation of phthalate esters in an activated sludge wastewater treatment plant. Water Research, 2007, 41(5):969-976

    Google Scholar Pub Med

    [10] Roly Oliver, Eric May, John Williams. The occurrence and removal of phthalates in a trickle filter STW. Water Research, 2005, 39(18):4436-4444

    Google Scholar Pub Med

    [11] 李海燕, 曲久辉.饮用水中微量内分泌干扰物质(DBP)的O3氧化去除研究.环境科学学报, 2003, 23(5):570-574 Li H.Y., Qu J.H.Ozonation of trace endocrine(DBP) in drinking water.Acta Scientiae Circumstantiae, 2003, 23(5):570-574(in Chinese)

    Google Scholar Pub Med

    [12] Ooka Chihiro, Yoshida Hisao, Suzuki Kenzi, et al. Highly hydrophobic TiO2 pillared clay for photocatalytic degradation of organic compounds in water. Microporous and Mesoporous Materials, 2004, 67(2-3):143-150

    Google Scholar Pub Med

    [13] 陶光华, 陆少鸣. 乐果微污染原水的碱解-活性炭处理究.水处理技术, 2010, 20(5):106-109 Tao G.H., Lu S.M.Study on the removal of dimethoate in the micro-pollution water.Technology of Water Treatment, 2010, 20(5):106-109(in Chinese)

    Google Scholar Pub Med

    [14] Chan K.H., Chu W. The system design of atrazine oxidation by catalytic oxidation process through a kinetic approach. Water Research, 2003, 37(16): 3997-4003

    Google Scholar Pub Med

    [15] L.Braeken, B.Vander Bruggen. Feasibility of nanofiltration for the removal of endocrine disrupting compounds. Desalination, 2009, 240(1-3):127-131

    Google Scholar Pub Med

    [16] 张阳, 胡锦英, 李光哲, 等.纳滤去除水中内分泌干扰物双酚A和四溴双酚A的研究.环境科学, 2010, 31(6): 1513-1517 Zang Y., Hu J.Y., Li G.Z., et al.Removal of bisphenol A and tetrabromobisphenol A by nanofiltration membrane from water source.Environmental Science, 2010, 31(6): 1513-1517(in Chinese)

    Google Scholar Pub Med

    [17] A.L.Ahmad, L.S. Tan, S.R.Abd. Shukor.Dimethoate and atrazine retention from aqueous solution by nanofiltration membranes. Journal of Hazardous Materials, 2008, 151(1):71-77

    Google Scholar Pub Med

    [18] Konstantinos V. Plakas, Anastasios J. Karabelas.A systematic study on triazine retention by fouled with humic substances NF/ULPRO membranes. Separation and Purification Technology, 2011, 80(2):46-261

    Google Scholar Pub Med

    [19] Konstantinos V. Plakas, Anastasios J. Karabelas. A systematic study on triazine retention by fouled with humic substances NF/ULPRO membranes. Separation and Purification Technology, 2011, 80(2):246-261

    Google Scholar Pub Med

    [20] Alexander Caus, Stefaan Vanderhaegen. Integrated nanofiltration cascades with low salt rejection for complete removalof pesticides in drinking water production. Desalination, 2009, 241(1-3):111-117

    Google Scholar Pub Med

    [21] 黄裕, 张晗, 董秉直.纳滤膜去除卡马西平的影响研究.环境科学, 2011, 32(3):705-710 Huang Yu, Zhang Han, Dong Bingzhi.Researches on factors affecting the removal of carbamazepine by nanofilatration membranes. Environmental Science, 2011, 32(3):705-710(in Chinese)

    Google Scholar Pub Med

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Article Metrics

Article views(1424) PDF downloads(768) Cited by(0)

Access History

Removal of trace endocrine disruptors from polluted water with nanofiltration process

Fund Project:

Abstract: Several factors such as temperature, pH, initial concentration, transmembrane pressure (TMP) and running time which affect membrane flux and retention efficiencies were investigated by using DL1210 nanofiltration membrane to remove dibutyl phthalate (DBP), phthalate, bis (2-ethylhexyl) ester (DEHP), dimethoate and atrazine. The results showed that the nanofiltration process is an effective method to remove traces DBP, DEHP, dimethoate and atrazine. The retention efficiencies of nanofiltration membrane on DBP, DEHP, dimethoate and atrazine decreased with an increase in pH and temperature. And the membrane retention efficiencies on DBP and DEHP also decreased with an increase in initial concentration. However, TMP and running time have no significant impact on the membrane flux and the retention efficiencies of target pollutants. Finally, The nanofiltration process achieved the best retention efficiencies on DBP, DEHP, dimethoate and atrazine under the condition of the initial pH of 5, the initial concentration of 5 μg/L, a temperature of 5℃ and TMP of 0.4 MPa with retention efficiencies of 91.8%, 89.8%, 98.02% and 77.6%, respectively. And the effluent concentrations of DBP, DEHP, dimethoate and atrazine were 0.41, 0.49, 0.099 and 1.12 μg/L, respectively.

Reference (21)

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint