高铁酸钾的超声辅助化学合成及其对餐厨垃圾渗滤液的处理效果

何则强, 滕瑶, 胡文勇, 吴玉先, 瞿忠心, 熊利芝. 高铁酸钾的超声辅助化学合成及其对餐厨垃圾渗滤液的处理效果[J]. 环境工程学报, 2016, 10(2): 551-558. doi: 10.12030/j.cjee.20160207
引用本文: 何则强, 滕瑶, 胡文勇, 吴玉先, 瞿忠心, 熊利芝. 高铁酸钾的超声辅助化学合成及其对餐厨垃圾渗滤液的处理效果[J]. 环境工程学报, 2016, 10(2): 551-558. doi: 10.12030/j.cjee.20160207
He Zeqiang, Teng Yao, Hu Wenyong, Wu Yuxian, Qu Zhongxin, Xiong Lizhi. Ultrasonic-assisted chemical synthesis of K2FeO4 and its treatment efficiency on kitchen waste leachate[J]. Chinese Journal of Environmental Engineering, 2016, 10(2): 551-558. doi: 10.12030/j.cjee.20160207
Citation: He Zeqiang, Teng Yao, Hu Wenyong, Wu Yuxian, Qu Zhongxin, Xiong Lizhi. Ultrasonic-assisted chemical synthesis of K2FeO4 and its treatment efficiency on kitchen waste leachate[J]. Chinese Journal of Environmental Engineering, 2016, 10(2): 551-558. doi: 10.12030/j.cjee.20160207

高铁酸钾的超声辅助化学合成及其对餐厨垃圾渗滤液的处理效果

  • 基金项目:

    国家自然科学基金资助项目(51364009,51262008,51202087,51472107)

    生态旅游湖南省重点实验室开放基金项目(JDSTLY1503)

    湖南省研究生培养创新基地开放基金项目(201508)

    吉首大学研究生培养创新基地项目(研通[2015]20号)

    湖南省重点学科建设项目(JSU0713)

    吉首大学校级研究生项目(15JDY024)

    湖南省高校科技创新团队支持计划项目([2014]207)

  • 中图分类号: X703

Ultrasonic-assisted chemical synthesis of K2FeO4 and its treatment efficiency on kitchen waste leachate

  • Fund Project:
  • 摘要: 采用超声辅助化学合成法制备K2FeO4,用X-射线衍射、红外光谱和扫描电镜等对其进行表征。研究了K2FeO4对餐厨垃圾渗滤液中COD和氨氮的处理效果。结果表明,本法制备的K2FeO4具有四方结构,空间群为D2h(Pnma),其产率达到68.2%,纯度高达98.3%。扫描电镜表明,制备的K2FeO4由规则的条状颗粒组成,颗粒之间存在一定团聚。对餐厨渗滤液处理实验表明,在COD初始浓度为140.6 g/L的餐厨垃圾渗滤液中投加0.12 mol/L K2FeO4,调节pH为8.7,经处理24 min后COD去除率达到80.4%,氨氮的去除率达到75.9%。
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  • [1] He Manni, Sun Yanbin, Zou Dexun, et al. Influence of temperature on hydrolysis acidification of food waste. Procedia Environmental Sciences, 2012, 16: 85-94
    [2] Ghanem I. I. I., Gu Guowei, Zhu Jinfu. Leachate production and disposal of kitchen food solid waste by dry fermentation for biogas generation. Renewable Energy, 2001, 23(3-4): 673-684
    [3] 陈雪. 浅析餐厨垃圾无害化处理中渗滤液的处理技术. 环境科学与管理, 2010, 35(6): 99-101 Chen Xue. Analysis of the treatment technology of leachate during the food residue harmless processing. Environmental Science and Management, 2010, 35(6): 99-101(in Chinese)
    [4] 李晓红, 赵瑜, 卢义玉, 等. 城市垃圾填埋场渗滤液的污染及其控制. 地下空间与工程学报, 2008, 4(6): 1071-1075 Li Xiaohong, Zhao Yu, Lu Yiyu, et al. Control of pollution caused by landfill leachate of MSW. Chinese Journal of Underground Space and Engineering, 2008, 4(6): 1071-1075(in Chinese)
    [5] 马超. 餐厨垃圾渗滤液厌氧发酵研究. 南宁: 广西大学硕士学位论文, 2013 Ma Chao. Study on anerobic digestion of food waste leachate. Nanning: Master Dissertation of Guangxi University, 2013(in Chinese)
    [6] Kurniawan T. A., Lo W. H., Chan G. Y. Physico-chemical treatments for removal of recalcitrant conta minants from landfill leachate. Journal of Hazardous Materials, 2006, 129(1-3): 80-100
    [7] 刘亚丽, 张智, 段秀举. 垃圾填埋场渗滤液处理技术及应用. 水资源与水工程学报, 2008, 19(3): 15-19 Liu Yali, Zhang Zhi, Duan Xiuju. Treatment technology for the landfill leachate. Journal of Water Resources and Water Engineering, 2008, 19(3): 15-19(in Chinese)
    [8] Rikame S., Mungray A. A., Mungray A. K. Electricity generation from acidogenic food waste leachate using dual chamber mediator less microbial fuel cell. International Biodeterioration & Biodegradation, 2012, 75: 131-137
    [9] Chen Ye, Cheng J. J., Creamer K. S. Inhibition of anaerobic digestion process: A review. Bioresource Technology, 2008, 99(10): 4044-4064
    [10] Jiang Jiaqian, Lloyd B. Progress in the development and use of ferrate (VI) salt as an oxidant and coagulant for water and wastewater treatment. Water Research, 2002, 36(6): 1397-1408
    [11] 王利平, 徐金妹, 董旭, 等. 高铁酸钾药剂处理废水的研究现状. 工业水处理, 2007, 27(10): 9-13 Wang Liping, Xu Jinmei, Dong Xu, et al. Present research status of wastewater treatment with potassium ferrate. Industrial Water Treatment, 2007, 27(10): 9-13(in Chinese)
    [12] 温国蛟, 员建, 郭江. 高铁酸盐预氧化技术在饮用水处理中的应用. 环境科学与技术, 2010, 33(12F): 397-402 CWen Guojiao, Yuan Jian, Guo Jiang. Application of ferrate (VI) salts pre-oxidation technique in drinking water treatment. Environmental Science & Technology, 2010, 33(12F): 397-402(in Chinese)
    [13] 韩琦, 董文艺. 新型高效水处理剂高铁酸钾的研究进展. 环境科学与技术, 2012, 35(12J): 200-205 Han Qi, Dong Wenyi. Progress in development of potassium ferrate as new, highly efficient water treatment agent. Environmental Science & Technology, 2012, 35(12J): 200-205(in Chinese)
    [14] 陈颖, 李金莲, 王宝辉, 等. 高铁酸钾滤液氧化降解HPAM的研究. 化工进展, 2005, 24(1): 68-70 Chen Ying, Li Jinlian, Wang Baohui, et al. Oxidative degradation of partially hydrolyzed polyacrylamide in aqueous solution with filter liquor of ferrate (VI). Chemical Industry and Engineering Progress, 2005, 24(1): 68-70(in Chinese)
    [15] 田宝珍, 曲久辉. 化学氧化法制备高铁酸钾循环生产可能性的实验. 环境化学, 1999, 18(2): 173-177 Tian Baozhen, Qu Jiuhui. A study on the producing of potassium ferrate by chemical oxidation from a recycled solution. Environmental Chemistry, 1999, 18(2): 173-177(in Chinese)
    [16] 弓晓峰, 雷婷, 武和胜, 等. 高铁酸钾滤液处理垃圾渗滤液. 水处理技术, 2008, 34(6): 37-39 Gong Xiaofeng, Lei Ting, Wu Hesheng, et al. Study on the treatment of landfill leachate with the potassium ferrate filtrate. Technology of Water Treatment, 2008, 34(6): 37-39(in Chinese)
    [17] 吴小倩, 汪永辉, 刘振鸿, 等. 高铁酸钾深度处理垃圾渗滤液的实验研究. 中国给水排水, 2008, 24(5): 57-60 Wu Xiaoqian, Wang Yonghui, Liu Zhenhong, et al. Study on advanced treatment of landfill leachate by potassium ferrate. China Water & Wastewater, 2008, 24(5): 57-60(in Chinese)
    [18] 陈娟, 周爽. 高铁酸钾氧化处理垃圾渗滤液实验研究. 环境科学与管理, 2013, 38(7): 79-82 Chen Juan, Zhou Shuang. Experimental study on landfill leachate treatment with potassium ferrate oxidation method. Environmental Science and Management, 2013, 38(7): 79-82(in Chinese)
    [19] 屈勇军, 罗志勇, 林永胜, 等. 高铁酸钾氧化处理危废填埋场渗滤液研究. 广州化工, 2013, 41(22): 73-75 Qu Yongjun, Luo Zhiyong, Lin Yongsheng, et al. Study on oxidation of leachate in hazardous waste landfill by potassium ferrate (VI). Guangzhou Chemical Industry, 2013, 41(22): 73-75(in Chinese)
    [20] 张洋, 罗志勇, 屈勇军, 等. 高铁酸钾预处理垃圾渗滤液. 环境工程学报, 2014, 8(6): 2451-2455 Zhang Yang, Luo Zhiyong, Qu Yongjun, et al. Pretreatment of landfill leachate by potassium ferrate (VI). Chinese Journal of Environmental Engineering, 2014, 8(6): 2451-2455(in Chinese)
    [21] 肖瑜, 章波, 苏诚, 等. 高铁酸钾氧化-沸石吸附联合处理垃圾渗滤液. 桂林理工大学学报, 2011, 31(1): 123-127 Xiao Yu, Zhang Bo, Su Cheng, et al. Combined treatment of landfill leachate by potassium ferrate oxidation and mullock adsorption. Journal of Guilin University of Technology, 2011, 31(1): 123-127(in Chinese)
    [22] 马骥. 电解合成高铁酸盐及强化氧化垃圾渗滤液. 重庆: 重庆大学硕士学位论文, 2007 Ma Ji. The study on electrochemical synthesis of ferrate and oxidation processes for landfill leachate. Chongqing: Master Dissertation of Chongqing University, 2007(in Chinese)
    [23] 粟杰文. 高铁酸盐预氧化结合光催化降解垃圾渗滤液研究. 武汉: 华中科技大学硕士学位论文, 2008 Su Jiewen. Treatment of municipal landfill leachate by photochemical oxidation combined with ferrate pre-treatment. Wuhan: Master Dissertation of Huazhong University of Science and Technology, 2008(in Chinese)
    [24] 张红. 组合物化法强化预处理垃圾渗滤液. 昆明: 昆明理工大学硕士学位论文, 2007 Zhang Hong. The Intensified Pre-treatment with landfill leachate by the combined physical chemistry way. Kun ming: Master Dissertation of Kunming University of Science and Technology, 2007(in Chinese)
    [25] 武和胜. 高铁酸钾在垃圾渗滤液处理中的应用及改进. 南昌: 南昌大学硕士学位论文, 2007 Wu Hesheng. Research on the application and improvement of potassium ferrate in landfill leachate treatment. Nanchang: Master Dissertation of Nanchang University, 2007(in Chinese)
    [26] Li C., Li X. Z., Graham N. A study of the preparation and reactivity of potassium ferrate. Chemosphere, 2005, 61(4): 537-543
    [27] 董娟, 汪永辉, 吴小倩. 高铁酸钾水处理剂的制备及稳定性研究. 环境科学与管理, 2006, 31(8): 136-140 Dong Juan, Wang Yonghui, Wu Xiaoqian. Study on the preparation and stability of K2FeO4. Environmental Science and Management, 2006, 31(8): 136-140(in Chinese)
    [28] Audette R. J., Quail J. W. Potassium, rubidium, cesium, and barium ferrates (VI). Preparations, infrared spectra, and magnetic susceptibilities. Inorganic Chemistry, 1972, 11(8): 1904-1908
    [29] Licht S., Naschitz V., Halperin L., et al. Analysis of ferrate (VI) compounds and super-iron Fe(VI) battery cathodes: FTIR, ICP, titrimetric, XRD, UV/VIS and electrochemical characterization. Journal of Power Sources, 2001, 101(2): 167-176
    [30] Walz K. A., Suyama A. N., Suyama W. E., et al. Characterization and performance of high power iron (VI) ferrate batteries. Journal of Power Sources, 2004, 134(2): 318-323
    [31] Cavdar P., Yilmaz E., Tugtas A. E., et al. Acidogenic fermentation of municipal solid waste and its application to bio-electricity production via microbial fuel cells (MFCs). Water Science and Technology, 2011, 64(4): 789-795
    [32] Yoon J., Cho S., Cho Y., et al. The characteristics of coagulation of Fenton reaction in the removal of landfill leachate organics. Water Science and Technology, 1998, 38(2): 209-214
    [33] 杜娴. 高铁酸盐溶液处理难降解有机废水的研究. 重庆: 重庆大学硕士学位论文, 2006 Du Xian. Study on the refractory organic wastewater treatment with ferrate solution. Chongqing: Master Dissertation of Chongqing University, 2006(in Chinese)
    [34] 孙德智. 环境工程中的高级氧化技术. 北京: 化学工业出版社, 2002
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出版历程
  • 收稿日期:  2014-12-07
  • 刊出日期:  2016-03-10
何则强, 滕瑶, 胡文勇, 吴玉先, 瞿忠心, 熊利芝. 高铁酸钾的超声辅助化学合成及其对餐厨垃圾渗滤液的处理效果[J]. 环境工程学报, 2016, 10(2): 551-558. doi: 10.12030/j.cjee.20160207
引用本文: 何则强, 滕瑶, 胡文勇, 吴玉先, 瞿忠心, 熊利芝. 高铁酸钾的超声辅助化学合成及其对餐厨垃圾渗滤液的处理效果[J]. 环境工程学报, 2016, 10(2): 551-558. doi: 10.12030/j.cjee.20160207
He Zeqiang, Teng Yao, Hu Wenyong, Wu Yuxian, Qu Zhongxin, Xiong Lizhi. Ultrasonic-assisted chemical synthesis of K2FeO4 and its treatment efficiency on kitchen waste leachate[J]. Chinese Journal of Environmental Engineering, 2016, 10(2): 551-558. doi: 10.12030/j.cjee.20160207
Citation: He Zeqiang, Teng Yao, Hu Wenyong, Wu Yuxian, Qu Zhongxin, Xiong Lizhi. Ultrasonic-assisted chemical synthesis of K2FeO4 and its treatment efficiency on kitchen waste leachate[J]. Chinese Journal of Environmental Engineering, 2016, 10(2): 551-558. doi: 10.12030/j.cjee.20160207

高铁酸钾的超声辅助化学合成及其对餐厨垃圾渗滤液的处理效果

  • 1. 吉首大学生物资源与环境科学学院, 吉首 416000
基金项目:

国家自然科学基金资助项目(51364009,51262008,51202087,51472107)

生态旅游湖南省重点实验室开放基金项目(JDSTLY1503)

湖南省研究生培养创新基地开放基金项目(201508)

吉首大学研究生培养创新基地项目(研通[2015]20号)

湖南省重点学科建设项目(JSU0713)

吉首大学校级研究生项目(15JDY024)

湖南省高校科技创新团队支持计划项目([2014]207)

摘要: 采用超声辅助化学合成法制备K2FeO4,用X-射线衍射、红外光谱和扫描电镜等对其进行表征。研究了K2FeO4对餐厨垃圾渗滤液中COD和氨氮的处理效果。结果表明,本法制备的K2FeO4具有四方结构,空间群为D2h(Pnma),其产率达到68.2%,纯度高达98.3%。扫描电镜表明,制备的K2FeO4由规则的条状颗粒组成,颗粒之间存在一定团聚。对餐厨渗滤液处理实验表明,在COD初始浓度为140.6 g/L的餐厨垃圾渗滤液中投加0.12 mol/L K2FeO4,调节pH为8.7,经处理24 min后COD去除率达到80.4%,氨氮的去除率达到75.9%。

English Abstract

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