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不同阴极对微生物燃料电池产电性能的影响比较

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黎嘉仪, 骆海萍, 袁也, 侯晓月, 刘广立, 侯燕萍, 张仁铎. 不同阴极对微生物燃料电池产电性能的影响比较[J]. 环境工程学报, 2014, 8(8): 3143-3148.
引用本文: 黎嘉仪, 骆海萍, 袁也, 侯晓月, 刘广立, 侯燕萍, 张仁铎. 不同阴极对微生物燃料电池产电性能的影响比较[J]. 环境工程学报, 2014, 8(8): 3143-3148.
shu
Li Jiayi, Luo Haiping, Yuan Ye, Hou Xiaoyue, Liu Guangli, Hou Yanping, Zhang Renduo. Comparison in performance of microbial fuel cells using different cathodes[J]. Chinese Journal of Environmental Engineering, 2014, 8(8): 3143-3148.
Citation: Li Jiayi, Luo Haiping, Yuan Ye, Hou Xiaoyue, Liu Guangli, Hou Yanping, Zhang Renduo. Comparison in performance of microbial fuel cells using different cathodes[J]. Chinese Journal of Environmental Engineering, 2014, 8(8): 3143-3148.
shu

不同阴极对微生物燃料电池产电性能的影响比较

  • 1.

    广东省环境污染控制与修复技术重点实验室, 中山大学环境科学与工程学院, 广州 510275

  • 基金项目:

    国家自然科学基金资助项目（51278500）

    广州市环保局污染防治新技术新工艺研究开发项目

    广州市科技计划项目（2012J4300115）

    广东省省部产学研项目（2012B091100036）

    中央高校基本科研业务费专项资金项目（13lgpy55）

  • 中图分类号: X703

Comparison in performance of microbial fuel cells using different cathodes

  • 1.

    Guangdong Province Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China

  • Fund Project:

  • 摘要: 阴极催化性能及材料对微生物燃料电池（microbial fuel cells，MFCs）的产电特性及制造成本有很大影响。本研究选用金属铂（Pt）、活性炭作为催化剂、聚四氟乙烯（PTFE）和道康宁1-2577作为阴极的扩散层、碳布和不锈钢网作为阴极的基体材料制备得4种阴极，分别考察了相应MFC的产电性能和阴极特性。结果表明，采用传统Pt催化剂+PTFE扩散层+碳布制备成的阴极（Pt-PTC），MFC的最大输出电压为560 mV，最大功率密度为808 mW/m2，而采用活性炭+道康宁1-2577+不锈钢网制备成的阴极（AC-DCS），MFC的最大输出电压为510 mV，最大功率密度为726 mW/m2，两者的MFC产电性能极为接近。SEM结果表明，活性炭催化层表面和道康宁1-2577扩散层分别比Pt催化层及PTFE扩散层的更均匀光滑。阴极线性伏安测定结果表明，AC-DCS与Pt-PTC的电化学氧化性能较为接近。AC-DCS阴极成本仅为Pt-PTC的1/300左右，是一种低成本扩大化生产MFC阴极的新方法。
    Abstract: The catalytic properties and materials of cathode have great effect on the power generation and the investment of microbial fuel cells (MFCs). The performance of four types of cathodes in MFCs were examined in this study. The cathodes were prepared using the platinum and activated carbon as the catalysts, polytetrafluoroethylene (PTFE) and Dow Corning 1-2577 as the diffusion layers, carbon cloth and stainless steel mesh as the basements. Results showed that the MFC using traditional cathode made by Pt catalyst + PTFE diffusion layers + carbon cloth (Pt-PTC) could obtain the maximum voltage of 560 mV and the maximum power density of 808 mW/m2.The maximum voltage and the maximum power density achieved by the MFC with the cathode made by activated carbon catalyst + Dow Corning 1-2577 diffusion layers + stainless steel mesh (AC-DCS) was 510 mV and 726 mW/m2, respectively. The performance of the AC-DCS cathode was comparable to that of the conventional Pt-PTC cathode. The SEM photos demonstrated that the surface of the activated carbon catalyst layer and the Dow Corning diffusion layer were more uniform and smoother than that of the Pt catalyst layer and PTFE diffusion layer, respectively. The linear sweep voltammetry (LSV) result indicated that the electrochemical oxidation of the AC-DCS cathode was similar to that of the Pt-PTC one. The construction of the AC-DCS cathode could be a promising low-cost method for the pilot-scale MFC setup, since its cost was estimated to be as low as 1/300 of that of the Pt-PTC cathode.
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  • [1] Liu Hong, Logan Bruce E. Electricity generation using an aircathode single chamber microbial fuel cell in the presence and absence of a proton exchange membrane. Environmental Science & Technology, 2004,38(14): 4040-4046
    [2] Liu Hong, Cheng Shaoan, Logan Bruce E. Production of electricity from acetate or butyrate using a single-chamber microbial fuel cell. Environmental Science & Technology, 2005, 39(2): 658-662
    [3] Cheng Shaoan, Liu Hong, Logan Bruce E.Increased performance of single-chamber microbial fuel cells using an improved cathode structure. Electrochemistry Communications, 2006, 8(3):489-494
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    [5] 尹航,胡翔.不同阳极微生物燃料电池产电性能的研究.环境工程学报,2013,7(2):608-612 Yin Hang, Hu Xiang. Comparison of power generation performance of different types of anode in microbial fuel cells. Chinese Journal of Environmental Engineering, 2013, 7(2): 608-612(in Chinese)
    [6] 李冬梅,史海凤,殷瑶,等. 磷酸活化石墨的氧还原特性以及用于微生物燃料电池阴极. 环境工程学报,2012,6(7):2454-2460 Li Dongmei, Shi Haifeng, Yin Yao, et al. Graphite-granule activated by H3PO4 for oxygen reduction reaction and as the cathodic material in microbial fuel cells. Chinese Journal of Environmental Engineering, 2012, 6(7): 2454-2460(in Chinese)
    [7] 骆海萍,刘广立,张仁铎,等. 2种不同结构的微生物燃料电池的产电性能比较,环境科学,2009,30(2):621-624 Luo Haiping, Liu Guangli, Zhang Renduo, et al. Comparison of power generation in microbial fuel cells of two different structures. Environmental Science, 2009, 30(2): 621-624(in Chinese)
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    [10] 唐玉兰,何亚婷,于鹏飞,等.铁碳布空气阴极微生物燃料电池的产电性能.环境工程学报,2013,7(4):1241-1244 Tang Yulan, He Yating, Yu Pengfei, et al. Electricity generation performance of microbial fuel cells with carbon cloth as air-cathode and iron as cathode catalyst. Chinese Journal of Environmental Engineering, 2013, 7(4): 1241-1244(in Chinese)
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  • 收稿日期:  2013-08-08
  • 刊出日期:  2014-07-31
黎嘉仪, 骆海萍, 袁也, 侯晓月, 刘广立, 侯燕萍, 张仁铎. 不同阴极对微生物燃料电池产电性能的影响比较[J]. 环境工程学报, 2014, 8(8): 3143-3148.
引用本文: 黎嘉仪, 骆海萍, 袁也, 侯晓月, 刘广立, 侯燕萍, 张仁铎. 不同阴极对微生物燃料电池产电性能的影响比较[J]. 环境工程学报, 2014, 8(8): 3143-3148.
shu
Li Jiayi, Luo Haiping, Yuan Ye, Hou Xiaoyue, Liu Guangli, Hou Yanping, Zhang Renduo. Comparison in performance of microbial fuel cells using different cathodes[J]. Chinese Journal of Environmental Engineering, 2014, 8(8): 3143-3148.
Citation: Li Jiayi, Luo Haiping, Yuan Ye, Hou Xiaoyue, Liu Guangli, Hou Yanping, Zhang Renduo. Comparison in performance of microbial fuel cells using different cathodes[J]. Chinese Journal of Environmental Engineering, 2014, 8(8): 3143-3148.
shu

不同阴极对微生物燃料电池产电性能的影响比较

  • 1. 广东省环境污染控制与修复技术重点实验室, 中山大学环境科学与工程学院, 广州 510275
  • 收稿日期:  2013-08-08
基金项目:

国家自然科学基金资助项目（51278500）

广州市环保局污染防治新技术新工艺研究开发项目

广州市科技计划项目（2012J4300115）

广东省省部产学研项目（2012B091100036）

中央高校基本科研业务费专项资金项目（13lgpy55）

摘要: 阴极催化性能及材料对微生物燃料电池（microbial fuel cells，MFCs）的产电特性及制造成本有很大影响。本研究选用金属铂（Pt）、活性炭作为催化剂、聚四氟乙烯（PTFE）和道康宁1-2577作为阴极的扩散层、碳布和不锈钢网作为阴极的基体材料制备得4种阴极，分别考察了相应MFC的产电性能和阴极特性。结果表明，采用传统Pt催化剂+PTFE扩散层+碳布制备成的阴极（Pt-PTC），MFC的最大输出电压为560 mV，最大功率密度为808 mW/m2，而采用活性炭+道康宁1-2577+不锈钢网制备成的阴极（AC-DCS），MFC的最大输出电压为510 mV，最大功率密度为726 mW/m2，两者的MFC产电性能极为接近。SEM结果表明，活性炭催化层表面和道康宁1-2577扩散层分别比Pt催化层及PTFE扩散层的更均匀光滑。阴极线性伏安测定结果表明，AC-DCS与Pt-PTC的电化学氧化性能较为接近。AC-DCS阴极成本仅为Pt-PTC的1/300左右，是一种低成本扩大化生产MFC阴极的新方法。

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