木屑黄原酸盐对双离子体系中铜镍的吸附

夏璐, 胡伊旭, 张博涵, 李国磊. 木屑黄原酸盐对双离子体系中铜镍的吸附[J]. 环境工程学报, 2014, 8(5): 1718-1722.
引用本文: 夏璐, 胡伊旭, 张博涵, 李国磊. 木屑黄原酸盐对双离子体系中铜镍的吸附[J]. 环境工程学报, 2014, 8(5): 1718-1722.
Xia Lu, Hu Yixü, Zhang Bohan, Li Guolei. Adsorption of Cu2+ and Ni2+ in dual ion system by sawdust xanthate[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1718-1722.
Citation: Xia Lu, Hu Yixü, Zhang Bohan, Li Guolei. Adsorption of Cu2+ and Ni2+ in dual ion system by sawdust xanthate[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1718-1722.

木屑黄原酸盐对双离子体系中铜镍的吸附

  • 基金项目:

    国家自然科学基金资助项目(41061044)

    广西自然科学基金重点资助项目(2010GXNSFD013016)

    广西自然科学基金面上项目(2012GXNSFAA053017)

  • 中图分类号: X703

Adsorption of Cu2+ and Ni2+ in dual ion system by sawdust xanthate

  • Fund Project:
  • 摘要: 利用木屑制备木屑黄原酸盐吸附剂,对其进行FTIR、XRD和BET分析,并考察了对双离子体系中铜镍离子的吸附情况,重点研究了木屑黄原酸盐吸附量的预测和吸附初始速率的计算。结果表明,在铜镍双离子体系中,利用扩展的Langmuir模型能很好地预测木屑黄原酸盐对铜镍离子的吸附;吸附之初,吸附速率很快,并且随着干扰离子的浓度增大,所考察离子的初始速率逐渐减小。吸附情况说明,木屑黄原酸盐是一种具有良好吸附性能的吸附材料。
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  • [1] 冯绮澜, 尹华, 秦华明, 等. 利用甘蔗渣制备微生物絮凝剂的预处理方法研究. 环境工程学报, 2011, 5(6): 1268-1272 Feng Qilan, Yin Hua, Qin Huaming, et al. Research on the pretreatment method of sugarcane bagasse for production of bioflocculant. Chinese Journal of Environmental Engineering. 2011, 5(6): 1268-1272(in Chinese)
    [2] 王攀, 于宏兵, 薛旭芳, 等. 废弃植物中药渣的热解特性与动力学研究. 环境工程学报, 2010, 4(9): 2115-2119 Wang Pan, Yu Hongbing, Xue Xufang, et al. Study on characteristics and kinetics of pyrolysis of herb residue. Chinese Journal of Environmental Engineering, 2010, 4(9): 2115-2119(in Chinese)
    [3] 鲁爱华, 袁兴中, 康广博, 等. 稻草经超声波辅助预处理后酶解过程的动力学研究. 环境工程学报, 2010, 4(6): 1399-1404 Lu Aihua, Yuan Xingzhong, Kang Guangbo, et al. Kinetic study on enzymatic hydrolysis of rice straw with ultrasound-assisted pretreatment. Chinese Journal of Environmental Engineering, 2010, 4(6): 1399-1404(in Chinese)
    [4] Wan-Ngah W. S., Hanafiah M. A. K. M. Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: A review. Bioresour. Technol., 2008, 99(10): 3935-3948
    [5] 钱晓荣, 王连军, 冒爱荣, 等. 季铵化木屑纤维素的制备及其对水中苯酚的吸附性能研究. 环境工程学报, 2009, 3(12): 2195-2197 Qian Xiaorong, Wang Lianjun, Mao Airong, et al. Study on preparation of quaternary ammonium wood cellulose and its adsorbing phenol in aqueous solutions. Chinese Journal of Environmental Engineering, 2009, 3(12): 2195-2197(in Chinese)
    [6] Zhou W. B., Ge X., Zhu D. W., et al. Metal adsorption by quasi cellulose xanthogenates derived from aquatic and terrestrial plant materials. Bioresour. Technol., 2011, 102(3): 3629-3631
    [7] Homagai P. L., Ghimire K. N., Inoue K. Adsorption behavior of heavy metals onto chemically modified sugarcane bagasse. Bioresour. Technol., 2010, 101(6): 2067-2069
    [8] Flynn C. M. Jr., Carnahan T. G., Lindstrom R. E. Adsorption of heavy metal ions by xanthate sawdust. United States Bureau of Mines, 1980
    [9] Bricka R.M., Hill D.O. Metal immobilization by solidification of hydroxide and xanthate sludges. Philadelphia: American Society for Testing and Materials, 1989
    [10] Langmuir I. The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc., 1918, 40(9): 115-124
    [11] Aksu Z., Acikel U., Kutsal T. Application of multicomponent adsorption isotherms to simultaneous biosorption of iron and chromium on C. vulgaris. J. Chem. Technol. Biotechnol., 1997, 70(4): 368-378
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出版历程
  • 收稿日期:  2013-05-26
  • 刊出日期:  2014-05-06
夏璐, 胡伊旭, 张博涵, 李国磊. 木屑黄原酸盐对双离子体系中铜镍的吸附[J]. 环境工程学报, 2014, 8(5): 1718-1722.
引用本文: 夏璐, 胡伊旭, 张博涵, 李国磊. 木屑黄原酸盐对双离子体系中铜镍的吸附[J]. 环境工程学报, 2014, 8(5): 1718-1722.
Xia Lu, Hu Yixü, Zhang Bohan, Li Guolei. Adsorption of Cu2+ and Ni2+ in dual ion system by sawdust xanthate[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1718-1722.
Citation: Xia Lu, Hu Yixü, Zhang Bohan, Li Guolei. Adsorption of Cu2+ and Ni2+ in dual ion system by sawdust xanthate[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1718-1722.

木屑黄原酸盐对双离子体系中铜镍的吸附

  • 1. 广西民族大学化学化工学院, 广西林产化学与工程自治区重点实验室, 化学与生物转化过程新技术广西高校重点实验室, 南宁 530008
基金项目:

国家自然科学基金资助项目(41061044)

广西自然科学基金重点资助项目(2010GXNSFD013016)

广西自然科学基金面上项目(2012GXNSFAA053017)

摘要: 利用木屑制备木屑黄原酸盐吸附剂,对其进行FTIR、XRD和BET分析,并考察了对双离子体系中铜镍离子的吸附情况,重点研究了木屑黄原酸盐吸附量的预测和吸附初始速率的计算。结果表明,在铜镍双离子体系中,利用扩展的Langmuir模型能很好地预测木屑黄原酸盐对铜镍离子的吸附;吸附之初,吸附速率很快,并且随着干扰离子的浓度增大,所考察离子的初始速率逐渐减小。吸附情况说明,木屑黄原酸盐是一种具有良好吸附性能的吸附材料。

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