改性锰砂滤料处理高铁锰煤矿矿井水

王建兵, 蒋雯婷, 李亚男, 高振凤, 许翠华, 徐泽升, 何绪文. 改性锰砂滤料处理高铁锰煤矿矿井水[J]. 环境工程学报, 2012, 6(11): 3843-3848.
引用本文: 王建兵, 蒋雯婷, 李亚男, 高振凤, 许翠华, 徐泽升, 何绪文. 改性锰砂滤料处理高铁锰煤矿矿井水[J]. 环境工程学报, 2012, 6(11): 3843-3848.
Wang Jianbing, Jiang Wenting, Li Yanan, Gao Zhenfeng, Xü Cuihua, Xu Zesheng, He Xuwen. Treatment of coal mine drainage with high concentrated iron and manganese by modified manganese sand filter[J]. Chinese Journal of Environmental Engineering, 2012, 6(11): 3843-3848.
Citation: Wang Jianbing, Jiang Wenting, Li Yanan, Gao Zhenfeng, Xü Cuihua, Xu Zesheng, He Xuwen. Treatment of coal mine drainage with high concentrated iron and manganese by modified manganese sand filter[J]. Chinese Journal of Environmental Engineering, 2012, 6(11): 3843-3848.

改性锰砂滤料处理高铁锰煤矿矿井水

  • 基金项目:

    国家"863"高技术研究发展计划项目(2008AA06Z305)

    国家自然科学基金资助项目(50678172)

  • 中图分类号: X752

Treatment of coal mine drainage with high concentrated iron and manganese by modified manganese sand filter

  • Fund Project:
  • 摘要: 采用KMnO4溶液浸渍法制备了新型改性锰砂滤料,研究了滤料表面性能和过滤处理高铁锰矿井水的效果。结果表明,锰砂滤料除铁锰性能优于石英砂、陶粒以及瓷砂,采用KMnO4溶液浸渍能够提高锰砂滤料的过滤性能,最优的浸渍浓度为5%。5%KMnO4改性锰砂滤料过滤处理高铁锰矿井水的最佳工艺参数为:过滤周期24 h,反冲洗强度3.2 L/(s·m2),反冲洗时间5 min;通过比表面积测试分析和SEM表征分析发现,KMnO4溶液浸渍能够提高锰砂滤料比表面积,并在锰砂滤料表面形成了氧化膜,从而提高除铁除锰效果,而且浸渍液浓度越高,这种作用越明显。
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  • [1] 李丹, 何绪文, 王春荣, 等. 高浊高铁锰矿井水回用处理试验研究.中国矿业大学学报,2008,37(1) :125-128 Li D., He X.W., Wang C.R., et al. Study of the reclamation of coal mine wastewater with high turbidity, high Iron and high manganese concentration. Journal of China University of Mining & Technology,2008,37(1):125-128(in Chinese)
    [2] 李福勤, 杨静, 何绪文, 等. 高矿化度高铁锰矿井水回用处理工艺研究.中国矿业大学学报,2006,35(5) :637-641 Li F.Q., Yang J., He X.W., et al. Study of the reclamation and reuse of mine water with high-TDS, iron and manganese content. Journal of China University of Mining & Technology,2006,35(5) :637-641(in Chinese)
    [3] Aleya B. M.,Nurul A.Selected elemental composition of the muscle tissue of three species of fish,Tilapia nilotica,Cirrhina mrigala and Clarius batrachus,from the fresh water Dhanmondi Lake in Bangladesh.Food Chemistry,2005,93(3):439-443
    [4] 谷勇霞,周忠宁,李意民.采空区处理矿井水的资源化利用.煤炭科学技术,2007,35(4) :90-92 Gu Y.X., Zhou Z.N., Li Y.M. Research on resource utilization of mine water in goaf. Coal Science and Technology,2007,35(4) :90-92(in Chinese)
    [5] Youn S., Constantions V. Virus transport in unsaturated porous media. Water Resources Research,2000,36(1):173-179
    [6] Hallberg K. B., Johnson D. B. Biological manganese removal from acid mine drainage in constructed wetlands and prototype bioreactors. Science of the Total Environment,2005,338(1-2):115-124
    [7] 毛艳丽,罗世田,师军帅.不同滤料去除地下水中铁锰效果的实验研究.平顶山学院学报,2006,21(5) :41 Mao Y.L., Luo S.T., Shi J. S. A study of the effect of different filtration materials used in removing iron and manganese in groundwater.Journal of Pingdingshan Teachers’College,2006,21(5) :41(in Chinese)
    [8] Tahir S. S., Rauf N. Removal of Fe(Ⅱ) from the wastewater of a galvanized pipe manufacturing Industry by adsorption onto bentonite clay. Journal of Environmental Management,2004,73(4):285-292
    [9] Mohan D., Chander S. Single, binary and multicomponent sorption of iron and manganese on lignite. Journal of Colloid and Interface Science,2006,299(1):76-87
    [10] Potgieter J. H., Potgieter-Vermaak S. S., Modise J., et al. Removal of iron and manganese from water with a high organic carbon loading: The effect of various adsorbents and nanofiltration membranes. Water, Air and Soil Pollution,2005,162(1-4):61-70
    [11] Resende P. C., Barrado F. S., Martins A. H. Sulfuric activation of a Brazilian manganese ore for heavy metals removal. Hydrometallurgy,1999,51(3):325-333
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    [14] Sharma Y. C., Uma S., Singh N., et al. Fly ash for the removal of Mn(Ⅱ) from aqueous solutions and wastewaters. Chemical Engineering Journal,2007,132(1-3):319-323
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出版历程
  • 收稿日期:  2012-02-16
  • 刊出日期:  2012-11-09
王建兵, 蒋雯婷, 李亚男, 高振凤, 许翠华, 徐泽升, 何绪文. 改性锰砂滤料处理高铁锰煤矿矿井水[J]. 环境工程学报, 2012, 6(11): 3843-3848.
引用本文: 王建兵, 蒋雯婷, 李亚男, 高振凤, 许翠华, 徐泽升, 何绪文. 改性锰砂滤料处理高铁锰煤矿矿井水[J]. 环境工程学报, 2012, 6(11): 3843-3848.
Wang Jianbing, Jiang Wenting, Li Yanan, Gao Zhenfeng, Xü Cuihua, Xu Zesheng, He Xuwen. Treatment of coal mine drainage with high concentrated iron and manganese by modified manganese sand filter[J]. Chinese Journal of Environmental Engineering, 2012, 6(11): 3843-3848.
Citation: Wang Jianbing, Jiang Wenting, Li Yanan, Gao Zhenfeng, Xü Cuihua, Xu Zesheng, He Xuwen. Treatment of coal mine drainage with high concentrated iron and manganese by modified manganese sand filter[J]. Chinese Journal of Environmental Engineering, 2012, 6(11): 3843-3848.

改性锰砂滤料处理高铁锰煤矿矿井水

  • 1. 中国矿业大学(北京)化学与环境工程学院,北京 100083
基金项目:

国家"863"高技术研究发展计划项目(2008AA06Z305)

国家自然科学基金资助项目(50678172)

摘要: 采用KMnO4溶液浸渍法制备了新型改性锰砂滤料,研究了滤料表面性能和过滤处理高铁锰矿井水的效果。结果表明,锰砂滤料除铁锰性能优于石英砂、陶粒以及瓷砂,采用KMnO4溶液浸渍能够提高锰砂滤料的过滤性能,最优的浸渍浓度为5%。5%KMnO4改性锰砂滤料过滤处理高铁锰矿井水的最佳工艺参数为:过滤周期24 h,反冲洗强度3.2 L/(s·m2),反冲洗时间5 min;通过比表面积测试分析和SEM表征分析发现,KMnO4溶液浸渍能够提高锰砂滤料比表面积,并在锰砂滤料表面形成了氧化膜,从而提高除铁除锰效果,而且浸渍液浓度越高,这种作用越明显。

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