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典型类雌激素的降解方法及其影响因素研究进展

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熊美昱, 夏雨琪, 彭程. 典型类雌激素的降解方法及其影响因素研究进展[J]. 环境化学, 2020, (3): 610-623. doi: 10.7524/j.issn.0254-6108.2019101303
引用本文: 熊美昱, 夏雨琪, 彭程. 典型类雌激素的降解方法及其影响因素研究进展[J]. 环境化学, 2020, (3): 610-623. doi: 10.7524/j.issn.0254-6108.2019101303
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XIONG Meiyu, XIA Yuqi, PENG Cheng. Degradation methods and influence factors of typical estrogen-like substances[J]. Environmental Chemistry, 2020, (3): 610-623. doi: 10.7524/j.issn.0254-6108.2019101303
Citation: XIONG Meiyu, XIA Yuqi, PENG Cheng. Degradation methods and influence factors of typical estrogen-like substances[J]. Environmental Chemistry, 2020, (3): 610-623. doi: 10.7524/j.issn.0254-6108.2019101303
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典型类雌激素的降解方法及其影响因素研究进展

  • 1. 东华大学环境科学与工程学院, 国家环境保护纺织工业污染防治工程技术中心, 上海, 201620;

  • 2. 上海污染控制与生态安全研究院, 上海, 200092

    • 通讯作者: 彭程, E-mail: cpeng@dhu.edu.cn
  • 基金项目:

    国家自然科学基金（41807461），上海市青年科技英才扬帆计划（18YF1401000）和中央高校基本科研业务费专项资金（2232018D3-19）资助.

Degradation methods and influence factors of typical estrogen-like substances

  • 1. Textile Pollution Controlling Engineering Center of Ministry of Environmental Protection, College of Environmental Science and Engineering, Donghua University, Shanghai, 201620, China;

  • 2. Shanghai Institute of Pollution Control and Ecological Security, Shanghai, 200092, China

    • Corresponding author: PENG Cheng, cpeng@dhu.edu.cn
  • Fund Project: Supported by National Natural Science Foundation of China (41807461), Shanghai Sailing Program (18YF1401000) and Fundamental Research Funds for the Central Universities (2232018D3-19).

  • 摘要: 类雌激素是一类新兴污染物，目前在环境中普遍存在，且在极低浓度下可对生物体和环境产生重大威胁.本文重点介绍了酚类、天然类固醇类和邻苯二甲酸酯等3种典型类雌激素的来源、环境分布特征及其生物毒性，综述了典型类雌激素的最新化学降解法（直接光解法和高级氧化法）和生物降解法（菌类降解法和藻类降解法）及其特点.直接光解法操作简便，但降解效果不佳；高级氧化法能快速高效地去除类雌激素，但操作相对复杂、影响因素较多；生物降解法的应用性强，但处理周期长、受环境因素影响大.此外还阐述了类雌激素的降解机理及其影响因素，最后对典型类雌激素的多种高效联合降解技术提出了展望.
    Abstract: Estrogen-like substances, as a kind of emerging contaminants, are extensively present in the environment, which can pose a great threat to organisms even at extreme low environmental concentration. This review introduced the sources, environmental distribution characteristics and biotoxicity of typical estrogen-like substances such as phenols, natural steroids and phthalates, and summarized the recent studies on the chemical degradation and biodegradation of these estrogen-like substances. Thereinto, the direct photolysis method is simple to use but without a good degradation effect, while the advanced oxidation processes can rapidly and efficiently remove estrogen-like substances but its application is relatively complicated and affects by many factors; the biodegradation method has a high applicability but with long-term processing period and is susceptible to environmental factors. In addition, the paper clarified the degradation mechanism of estrogen-like substances and their impact factors. Finally, the research prospected on various highly efficient degradation by combined methods of typical estrogen-like substances.
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  • 收稿日期:  2019-10-13

典型类雌激素的降解方法及其影响因素研究进展

    通讯作者: 彭程, E-mail: cpeng@dhu.edu.cn
  • 1. 东华大学环境科学与工程学院, 国家环境保护纺织工业污染防治工程技术中心, 上海, 201620;
  • 2. 上海污染控制与生态安全研究院, 上海, 200092
  • 收稿日期:  2019-10-13
基金项目:

国家自然科学基金（41807461），上海市青年科技英才扬帆计划（18YF1401000）和中央高校基本科研业务费专项资金（2232018D3-19）资助.

摘要: 类雌激素是一类新兴污染物，目前在环境中普遍存在，且在极低浓度下可对生物体和环境产生重大威胁.本文重点介绍了酚类、天然类固醇类和邻苯二甲酸酯等3种典型类雌激素的来源、环境分布特征及其生物毒性，综述了典型类雌激素的最新化学降解法（直接光解法和高级氧化法）和生物降解法（菌类降解法和藻类降解法）及其特点.直接光解法操作简便，但降解效果不佳；高级氧化法能快速高效地去除类雌激素，但操作相对复杂、影响因素较多；生物降解法的应用性强，但处理周期长、受环境因素影响大.此外还阐述了类雌激素的降解机理及其影响因素，最后对典型类雌激素的多种高效联合降解技术提出了展望.

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