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生物炭的制备温度及酸处理对卡马西平的吸附动力学影响

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陈建, 王朋, 曹艳贝, 郭秉林, 张迪. 生物炭的制备温度及酸处理对卡马西平的吸附动力学影响[J]. 环境化学, 2016, 35(7): 1461-1467. doi: 10.7524/j.issn.0254-6108.2016.07.2015112401
引用本文: 陈建, 王朋, 曹艳贝, 郭秉林, 张迪. 生物炭的制备温度及酸处理对卡马西平的吸附动力学影响[J]. 环境化学, 2016, 35(7): 1461-1467. doi: 10.7524/j.issn.0254-6108.2016.07.2015112401
shu
CHEN Jian, WANG Peng, CAO Yanbei, GUO Binglin, ZHANG Di. Impact of pyrolytic temperature and acid wash on adsorption kinetics of carbamazepine on biochar[J]. Environmental Chemistry, 2016, 35(7): 1461-1467. doi: 10.7524/j.issn.0254-6108.2016.07.2015112401
Citation: CHEN Jian, WANG Peng, CAO Yanbei, GUO Binglin, ZHANG Di. Impact of pyrolytic temperature and acid wash on adsorption kinetics of carbamazepine on biochar[J]. Environmental Chemistry, 2016, 35(7): 1461-1467. doi: 10.7524/j.issn.0254-6108.2016.07.2015112401
shu

生物炭的制备温度及酸处理对卡马西平的吸附动力学影响

  • 1.

    昆明理工大学, 环境科学与工程学院, 昆明, 650500

  • 基金项目:

    国家自然科学基金（41303093），云南省自然科学基金（2014FB121），昆明理工大学人才启动经费（14118762），昆明理工大学课外学术科技创新基金（2015BA082）资助

Impact of pyrolytic temperature and acid wash on adsorption kinetics of carbamazepine on biochar

  • 1.

    Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming, 650500, China

  • Fund Project: Supported by the National Scientific Foundation of China(41303093), Scientific Foundation of Yunnan Province (2014FB121) and Scientific Foundation of Kunming University of Science and Technology (14118762), Extracurricular Scientific Innovation Foundation of Kunming University of Science and Technology(2015BA082).

  • 摘要: 本研究考察了卡马西平（CBZ）在9种不同条件（裂解温度200、300、500℃，无酸，HCI和HCI-HF）处理的生物炭上的吸附动力学，分别应用拟一级、拟二级和双室一级3种动力学模型对实验数据进行拟合.研究结果表明，双室一级动力学模型对吸附动力学提供了更精确的描述.裂解温度和酸处理对CBZ的吸附动力学有显著影响，具体表现为不同酸洗导致矿物含量发生显著变化，矿物对生物炭吸附CBZ的快室吸附单元起主要作用，生物炭内部的芳香环随生物炭的升高而更加致密，生物炭内部的芳香环结构主要贡献于慢室吸附单元.生物炭的矿物组分一方面屏蔽了有机质上的一些吸附点位，另一方面矿物自身可以有效地吸附污染物，酸洗去矿物对生物炭吸附污染物的表观影响可能取决于两个方面的平衡.
    Abstract: The adsorption kinetics of carbamazepine (CBZ) on 9 biochars produced at different charred temperature(200, 300 and 500℃) and deashed with different acids(HCI and HCI-HF) were investigated in this study. The pseudo-first-order model, pseudo-second-order model and two-compartment first order model were applied to fit the adsorption kinetic data. The results showed that the two-compartment first order model fitted the adsorption kinetic data better than other two models. The pyrolytic temperature and acid treatment had significant impact on adsorption kinetics of CBZ. Specifically, the mineral content altered significantly after deashing treatment with different acids, and was responsible for the rapid adsorption of CBZ on biochars. The aromatic ring structure of biochars become more condensed with increasing pyrolytic temperature and mainly contributed to the slow adsorption. On the one hand, the mineral of biochars likely blocked some adsorption sites of organic matter. On the other hand, the mineral could effectively adsorb organic contaminants. Thus, the effects of mineral on the apparent adsorption of contaminants on biochars were likely controlled by the balance of the two aspects.
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  • [1] 吴春英. 膜-生物反应器(MBR)和序批式生物反应器(SBR)去除城市污水中典型药品和个人护理品的对比[J]. 环境化学, 2013, 32(9):1674-1679.

    WU C Y. Comparisons between membrane bioreactor and sequencing batch reactor on removal of typical pharmaceuticals and personal care products in municipal wastewater[J]. Environmental Chemistry, 2013, 32(9):1674-1679(in Chinese).

    [2] WILLIAMS C,WATSON J,NELSON S. Comparison of equilibrium and non-equilibrium distribution coefficients for the human drug carbamazepine in soil[J]. Chemosphere, 2014, 95:166-173.
    [3] TERNES TA,JOSS A,SIEGRIST H. Peer reviewed:Scrutinizing pharmaceuticals and personal care products in wastewater treatment[J]. Environmental Science & Technology, 2004, 38(20):392-399.
    [4] CHEFETZ B,MUALEM T,BEN-ARI J. Sorption and mobility of pharmaceutical compounds in soil irrigated with reclaimed wastewater[J]. Chemosphere, 2008, 73(8):1335-1343.
    [5] SUN K,KANG M,ZHANG Z,et al.Impact of deashing treatment on biochar structural properties and potential sorption mechanisms of phenanthrene[J]. Environmental Science & Technology, 2013, 47(20):11473-11481.
    [6] SCHMIDT M W,NOACK A G. Black carbon in soils and sediments:Analysis, distribution, implications, and current challenges[J]. Global Biogeochemical Cycles, 2000, 14(3):777-793.
    [7] ZHANG P,SUN H,YU L,et al.Adsorption and catalytic hydrolysis of carbaryl and atrazine on pig manure-derived biochars:Impact of structural properties of biochars[J]. Journal of Hazardous Materials, 2013, 244:217-224.
    [8] ZHENG H,WANG Z,ZHAO J,et al.Sorption of antibiotic sulfamethoxazole varies with biochars produced at different temperatures[J]. Environmental Pollution, 2013, 181:60-67.
    [9] SUN K,JIN J,KANG M,et al.Isolation and characterization of different organic matter fractions from a same soil source and their phenanthrene sorption[J]. Environmental Science & Technology, 2013, 47(10):5138-5145.
    [10] GRIFFITHS R A. Sorption and desorption by ideal two-compartment systems:Unusual behavior and data interpretation problems[J]. Chemosphere, 2004, 55(3):443-454.
    [11] CHUN Y,SHENG G,CHIOU C T,et al.Compositions and sorptive properties of crop residue-derived chars[J]. Environmental Science & Technology, 2004, 38(17):4649-4655.
    [12] PAN B,XING B. Adsorption kinetics of 17α-ethinyl estradiol and bisphenol A on carbon nanomaterials. I. Several concerns regarding pseudo-first order and pseudo-second order models[J]. Journal of Soils and Sediments, 2010, 10(5):838-844.
    [13] GAO B,WANG P,ZHOU H,et al.Sorption of phthalic acid esters in two kinds of landfill leachates by the carbonaceous sorbents[J]. Bioresource Technology, 2013, 136:295-301.
    [14] KEILUWEIT M,NICO P S,JOHNSON M G,et al.Dynamic molecular structure of plant biomass-derived black carbon (biochar)[J]. Environmental Science & Technology, 2010, 44(4):1247-1253.
    [15] GUNASEKARA A S,SIMPSON M J,XING B.Identification and characterization of sorption domains in soil organic matter using structurally modified humic acids[J]. Environmental Science & Technology, 2003, 37(5):852-858.
    [16] CHEN B,CHEN Z. Sorption of naphthalene and 1-naphthol by biochars of orange peels with different pyrolytic temperatures[J]. Chemosphere, 2009, 76(1):127-133.
    [17] JOHNSON M D,KEINATH T M,WEBER W J. A Distributed Reactivity Model for Sorption by Soils and Sediments. 14. Characterization and Modeling of Phenanthrene Desorption Rates[J]. Environmental Science & Technology, 2001, 35(8):1688-1695.
    [18] PAN B,XING B,LIU W,et al.Two-compartment sorption of phenanthrene on eight soils with various organic carbon contents[J]. Journal of Environmental Science and Health Part B, 2006, 41(8):1333-1347.
    [19] JESUS A L,REDINHA J. Charge-assisted intramolecular hydrogen bonds in disubstituted cyclohexane derivatives[J]. The Journal of Physical Chemistry A, 2011, 115(48):14069-14077.
    [20] JI L,WAN Y,ZHENG S,et al.Adsorption of tetracycline and sulfamethoxazole on crop residue-derived ashes:Implication for the relative importance of black carbon to soil sorption[J]. Environmental Science & Technology, 2011, 45(13):5580-5586.
    [21] PAN B,WANG P,WU M,et al.Sorption kinetics of ofloxacin in soils and mineral particles[J]. Environmental Pollution, 2012, 171:185-190.
    [22] PIGNATELLO J J,XING B. Mechanisms of slow sorption of organic chemicals to natural particles[J]. Environmental Science & Technology, 1995, 30(1):1-11.
    [23] XING B,PIGNATELLO J J. Dual-mode sorption of low-polarity compounds in glassy poly (vinyl chloride) and soil organic matter[J]. Environmental Science & Technology, 1997, 31(3):792-799.
    [24] HUANG W,YOUNG T M,SCHLAUTMAN M A,et al.A distributed reactivity model for sorption by soils and sediments. 9. General isotherm nonlinearity and applicability of the dual reactive domain model[J]. Environmental Science & Technology, 1997, 31(6):1703-1710.
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  • 收稿日期:  2015-11-24
  • 刊出日期:  2016-07-15
陈建, 王朋, 曹艳贝, 郭秉林, 张迪. 生物炭的制备温度及酸处理对卡马西平的吸附动力学影响[J]. 环境化学, 2016, 35(7): 1461-1467. doi: 10.7524/j.issn.0254-6108.2016.07.2015112401
引用本文: 陈建, 王朋, 曹艳贝, 郭秉林, 张迪. 生物炭的制备温度及酸处理对卡马西平的吸附动力学影响[J]. 环境化学, 2016, 35(7): 1461-1467. doi: 10.7524/j.issn.0254-6108.2016.07.2015112401
shu
CHEN Jian, WANG Peng, CAO Yanbei, GUO Binglin, ZHANG Di. Impact of pyrolytic temperature and acid wash on adsorption kinetics of carbamazepine on biochar[J]. Environmental Chemistry, 2016, 35(7): 1461-1467. doi: 10.7524/j.issn.0254-6108.2016.07.2015112401
Citation: CHEN Jian, WANG Peng, CAO Yanbei, GUO Binglin, ZHANG Di. Impact of pyrolytic temperature and acid wash on adsorption kinetics of carbamazepine on biochar[J]. Environmental Chemistry, 2016, 35(7): 1461-1467. doi: 10.7524/j.issn.0254-6108.2016.07.2015112401
shu

生物炭的制备温度及酸处理对卡马西平的吸附动力学影响

  • 1. 昆明理工大学, 环境科学与工程学院, 昆明, 650500
  • 收稿日期:  2015-11-24
基金项目:

国家自然科学基金（41303093），云南省自然科学基金（2014FB121），昆明理工大学人才启动经费（14118762），昆明理工大学课外学术科技创新基金（2015BA082）资助

摘要: 本研究考察了卡马西平（CBZ）在9种不同条件（裂解温度200、300、500℃，无酸，HCI和HCI-HF）处理的生物炭上的吸附动力学，分别应用拟一级、拟二级和双室一级3种动力学模型对实验数据进行拟合.研究结果表明，双室一级动力学模型对吸附动力学提供了更精确的描述.裂解温度和酸处理对CBZ的吸附动力学有显著影响，具体表现为不同酸洗导致矿物含量发生显著变化，矿物对生物炭吸附CBZ的快室吸附单元起主要作用，生物炭内部的芳香环随生物炭的升高而更加致密，生物炭内部的芳香环结构主要贡献于慢室吸附单元.生物炭的矿物组分一方面屏蔽了有机质上的一些吸附点位，另一方面矿物自身可以有效地吸附污染物，酸洗去矿物对生物炭吸附污染物的表观影响可能取决于两个方面的平衡.

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