高级搜索

Fe3O4@改性悬铃木果毛复合中空纤维的制备及其吸附性能

,  ,  ,  ,  , 

downloadPDF

上一篇

下一篇

杨莉, 汪子孺, 李旭, 李梦婕, 张长涛, 赵珊. Fe3O4@改性悬铃木果毛复合中空纤维的制备及其吸附性能[J]. 环境工程学报, 2016, 10(5): 2375-2382. doi: 10.12030/j.cjee.201512088
引用本文: 杨莉, 汪子孺, 李旭, 李梦婕, 张长涛, 赵珊. Fe3O4@改性悬铃木果毛复合中空纤维的制备及其吸附性能[J]. 环境工程学报, 2016, 10(5): 2375-2382. doi: 10.12030/j.cjee.201512088
shu
Yang Li, Wang Ziru, Li Xu, Li Mengjie, Zhang Changtao, Zhao Shan. Preparation and adsorption property of Fe3O4@modified seed's furs of plane trees based hollow fiber composite[J]. Chinese Journal of Environmental Engineering, 2016, 10(5): 2375-2382. doi: 10.12030/j.cjee.201512088
Citation: Yang Li, Wang Ziru, Li Xu, Li Mengjie, Zhang Changtao, Zhao Shan. Preparation and adsorption property of Fe3O4@modified seed's furs of plane trees based hollow fiber composite[J]. Chinese Journal of Environmental Engineering, 2016, 10(5): 2375-2382. doi: 10.12030/j.cjee.201512088
shu

Fe3O4@改性悬铃木果毛复合中空纤维的制备及其吸附性能

  • 1.

    长安大学环境科学与工程学院, 西安 710054

  • 2.

    天津大学环境科学与工程学院, 天津 300072

  • 基金项目:

    陕西省自然科学基金资助项目(2015JQ5173)

    2016年中央高校基本科研业务费专项资金项目(310829162016)

    陕西省2014年度留学人员科技活动择优资助项目(0308-11000152003)

    长安大学2015年大学生创新创业训练计划项目(201510710143)

  • 中图分类号: X703

Preparation and adsorption property of Fe3O4@modified seed's furs of plane trees based hollow fiber composite

  • 1.

    School of Environmental Science and Engineering, Chang'an University, Xi'an 710054, China

  • 2.

    School of Environmental Science and Engineering, Tianjin University, Tianjing 300072, China

  • Fund Project:

  • 摘要: 选用对空气和人居环境具有污染的悬铃木果毛为基质,通过将四氧化三铁磁性纳米粒子在多巴胺改性悬铃木果毛表面的固载,制备得到具有中空结构的Fe3O4@改性悬铃木果毛复合吸附材料。用X射线衍射仪(XRD)、能谱(EDS)、电子扫描电镜(SEM)、红外光谱(FT-IR)和震动样品磁强计(VSM)等手段对样品进行了表征和分析,考察了Fe3O4@改性悬铃木果毛复合中空纤维对亚甲基蓝的吸附性能。结果表明:通过多巴胺对悬铃木果毛的化学改性,有效促进了反尖晶石型结构的四氧化三铁纳米粒子在其表面的固载,Fe3O4@改性悬铃木果毛复合中空纤维直径约为25.8 μm,其饱和磁化强度为12.51 emu/g, Fe3O4@改性悬铃木果毛对亚甲基蓝的吸附在140 min达到平衡,吸附容量可达12.6 mg/g,吸附动力学符合准二级动力学。
    Abstract: The seed's furs of plane trees, which are of great pollution to air and living environment, were employed as matrix for the preparation of novel magnetic hollow fiber composite in this study. Following the modification of seed's furs of plane trees with dopamine, ferromagnetic oxide nanoparticles were immobilized onto the surface of seed's furs to obtain Fe3O4@ modified seed's furs (Fe3O4@MSF) hollow fiber composite. Several techniques were used to characterize and probe into the properties of the as-produced samples including X-ray diffraction (XRD), energy spectrum (EDS), scanning electron microscopy (SEM), infrared spectroscopy (FT-IR) and vibrating sample magnetometer (VSM). And the adsorption capacity of Fe3O4@MSF was investigated through the adsorption experiments of methylene blue. Results indicated that the modification of seed's furs of plane tree with dopamine effectively promoted the anchoring of ferroferric oxide nanoparticles of inverse spinel phase onto the surface of hollow fibers. The as-synthesized Fe3O4@MSF maintained the morphology of original hollow seed furs with the average diameter about 25.8 μm, and held the advantage of convenient recovery with the saturation magnetization at 12.51 emu/g. Fe3O4@MSF showed good adsorption property in the adsorption experiments of methylene blue, and the adsorption capacity was up to 12.6 mg/g at the adsorption balance in 140 min. Adsorption isotherms of methylene blue on the adsorbent can be described by Langmuir equations and the adsorption kinetics followed pseudo-second order kinetics model.
  • 加载中
  • [1] 张守仕, 刘荣宁, 王利锋. 悬铃木研究进展. 河南农业, 2015(1): 48-50Zhang Shoushi, Liu Rongning, Wang Lifeng. Studies of the platanuss. Henan Nongye, 2015(1): 48-50(in Chinese)
    [2] 靳莉. 悬铃木的栽培与管理. 现代园艺, 2012(22): 40-41Jin Li. Cultivation and management of the platanus. Modern Gardening, 2012(22): 40-41(in Chinese)
    [3] 宿红艳, 王磊, 张萍, 等. 控制悬铃木果毛污染的研究进展及其展望. 江苏农业科学, 2005(6): 143-145Su Hongyan, Wang Lei, Zhang Ping, et al. Advances and prospects in the control of Platnus acerifolia's fruit hair pollution. Jiangsu Agricultural Sciences, 2005(6): 143-145(in Chinese)
    [4] 王长剑, 王大新. 悬铃木果毛污染防治新技术实验研究. 科技信息, 2010(12): 370-371Wang Changjian, Wang Daxin. Experimental studies on new technology of the Platanus fruit fiber pollution prevention and control. Science & Technology Information, 2010(12): 370-371(in Chinese)
    [5] 唐晓岚, 尤婷, 吴雯, 等. 南京2种常见行道树致敏性及其控制措施. 吉首大学学报(自然科学版), 2014, 35(3): 69-73Tang Xiaolan, You Ting, Wu Wen, et al. Allergenic property and two kinds of common street trees in Nanjing and the control. Journal of Jishou University (Natural Science Edition), 2014, 35(3): 69-73(in Chinese)
    [6] 张建甫, 刘元硕, 赵梁军. 悬铃木属植物果皮毛性状及其对小鼠肺部的致炎作用. 生态学报, 2009, 29(8): 4380-4385Zhang Jianfu, Liu Yuanshuo, Zhao Liangjun. The fruit fur characters of Platanus and its injury function on mice pulmonary. Acta Ecologica Sinica, 2009, 29(8): 4380-4385(in Chinese)
    [7] 曹剑波, 秦利鸿, 吴华, 等. 悬铃木成熟球果及果毛的形态学观察. 华中农业大学学报, 2008, 27(2): 313-316 Cao Jianbo, Qin Lihong, Wu Hua, et al. Observations on matured fruit and fruit fairs of Platanus acerifolia. Journal of Huazhong Agricultural University, 2008, 27(2): 313-316(in Chinese)
    [8] Likon M., Rem?kar M., Ducman V., et al. Populus seed fibers as a natural source for production of oil super absorbents. Journal of Environmental Management, 2013, 114: 158-167
    [9] 马延文, 熊传银, 黄雯, 等. 碳化法国梧桐絮制备碳微米管及作为超级电容器电极的研究. 无机化学学报, 2012, 28(3): 546-550Ma Yanwen, Xiong Chuanyin, Huang Wen, et al. Preparation of carbon microtubes by carbonizing the fluff of Chinar tree and their application as supercapacitor electrodes. Chinese Journal of Inorganic Chemistry, 2012, 28(3): 546-550(in Chinese)
    [10] 谭帼馨, 谭英, 宁成云, 等. 多孔钛表面聚多巴胺层修饰及其载银研究. 稀有金属材料与工程, 2015, 44(5): 1234-1238Tan Guoxin, Tan Ying, Ning Chengyun, et al. Polydopamine-assisted decoration of porous titanium surface and loading with Ag nanoparticles. Rare Metal Materials and Engineering, 2015, 44(5): 1234-1238(in Chinese)
    [11] Shaikh M. N., Bououdina M., Jimoh A. A., et al. The rhodium complex of bis(diphenylphosphinomethyl)dopamine-coated magnetic nanoparticles as an efficient and reusable catalyst for hydroformylation of olefins. New Journal Chemistry, 2015, 39(9): 7293-7299
    [12] Safari M., Ghiaci M., Jafari-Asl M., et al. Nanohybrid organic-inorganic chitosan/dopamine/TiO2 composites with controlled drug-delivery properties. Applied Surface Science, 2015, 28(3): 26-33
    [13] 李霞, 曹义鸣, 康国栋, 等. 基于多巴胺自聚合与表面接枝PHGH制备抗菌纳滤膜. 高等学校化学学报, 2014, 35(9): 2026-2030Li Xia, Cao Yiming, Kang Guodong, et al. Preparation of antimicrobial nanofiltration membrane via self-polymerization of dopamine and surface grafting of PHGH. Chemical Journal of Chinese Universities, 2014, 35(9): 2026-2030(in Chinese)
    [14] 田健, 王小龙, 毕美香. 一种高效TiO2基光催化剂的合成研究. 广东化工, 2014, 41(16): 5-6Tian Jian, Wang Xiaolong, Bi Meixiang. The study and synthesis of a novel visible-light responding TiO2 based photocatalysts. Guangdong Chemistry, 2014, 41(16): 5-6(in Chinese)
    [15] 李鹏莉, 于树玲, 石家华. 聚多巴胺改性碳纳米管对Pb2+的吸附性能. 河南大学学报(自然科学版), 2014, 44(4): 416-420Li Pengli, Yu Shuling, Shi Jiahua. Adsorption performance of polydopamine-modified carbon nanotubes for Pb2+ ions. Journal of Henan University (Natural Science), 2014, 44(4): 416-420(in Chinese)
    [16] 胡春平, 佟佳, 陈立钢, 等. 磁性羧甲基壳聚糖吸附分离孔雀石绿的研究. 离子交换与吸附, 2015, 31(1): 43-51Hu Chunping, Tong Jia, Chen Ligang, et al. Adsorption and separation of malachite green by magnetic carboxymethyl chitosan. Ion Exchange and Adsorption, 2015, 31(1): 43-51(in Chinese)
    [17] 周文, 郝春成. 纳米碳纤维表面四氧化三铁磁性修饰. 青岛科技大学学报(自然科学版), 2015, 36(4): 392-397Zhou Wen, Hao Chuncheng. Ferroferric oxide modification of surface of carbon nanofibers. Journal of Qingdao University of Science and Technology (Natural Science Edition), 2015, 36(4): 392-397(in Chinese)
    [18] 王家宏, 张迪, 尹小龙, 等. 污泥活性炭的制备及其对酸性红G的吸附行为. 环境工程学报, 2015, 9(1): 58-64Wang Jiahong, Zhang Di, Yin Xiaolong, et al. Preparation of activated carbon from activated sludge and its adsorption behavior for acid scarlet G. Chinese Journal of Environmental Engineering, 2015, 9(1): 58-64(in Chinese)
    [19] Liu Yun, Li Jianjun, Yang Yun, et al. Facile immobilization of polyaspartate onto silica gels via poly(dopamine) for the removal of methylene blue from aqueous solution. Applied Surface Science, 2015, 315: 831-839
    [20] Lagergren S. About the theory of so-called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens, Handlingar, 1898, 24: 1-39
    [21] Ho Y. S., McKay G. Kinetic models for the sorption of dye from aqueous solution by wood. Process Safety and Environmental Protection, 1998,, 76(2): 183-191
    [22] 冯云晓, 王莉, 腊明, 等. K2CO3-HNO3法制备活性炭及其对苯酚吸附动力学研究. 郑州大学学报(理学版), 2015, 47(2): 94-100Feng Yunxiao, Wang Li, La Ming, et al. Adsorption kinetic and mechanism studies of phenol onto K2CO3-HNO3 activated carbons. Journal of Zhengzhou University (National Science Edition), 2015, 47(2): 94-100(in Chinese)
    [23] 姚志鹏, 张颖, 王慧, 等. CoFe2O4-活性炭磁性纳米复合材料吸附去除罗丹明B染料. 西南大学学报(自然科学版), 2015, 37(7): 166-169Yao Zhipeng, Zhang Ying, Wang Hui, et al. Removal of rhodamine B by an activated carbon-CoFe2O4 magnetic nanocomposite. Journal of Southwest University (Natural Science Edition), 2015, 37(7): 166-169(in Chinese)
  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  1780
  • HTML全文浏览数:  1282
  • PDF下载数:  419
  • 施引文献:  0
出版历程
  • 收稿日期:  2016-01-29
  • 刊出日期:  2016-06-03
杨莉, 汪子孺, 李旭, 李梦婕, 张长涛, 赵珊. Fe3O4@改性悬铃木果毛复合中空纤维的制备及其吸附性能[J]. 环境工程学报, 2016, 10(5): 2375-2382. doi: 10.12030/j.cjee.201512088
引用本文: 杨莉, 汪子孺, 李旭, 李梦婕, 张长涛, 赵珊. Fe3O4@改性悬铃木果毛复合中空纤维的制备及其吸附性能[J]. 环境工程学报, 2016, 10(5): 2375-2382. doi: 10.12030/j.cjee.201512088
shu
Yang Li, Wang Ziru, Li Xu, Li Mengjie, Zhang Changtao, Zhao Shan. Preparation and adsorption property of Fe3O4@modified seed's furs of plane trees based hollow fiber composite[J]. Chinese Journal of Environmental Engineering, 2016, 10(5): 2375-2382. doi: 10.12030/j.cjee.201512088
Citation: Yang Li, Wang Ziru, Li Xu, Li Mengjie, Zhang Changtao, Zhao Shan. Preparation and adsorption property of Fe3O4@modified seed's furs of plane trees based hollow fiber composite[J]. Chinese Journal of Environmental Engineering, 2016, 10(5): 2375-2382. doi: 10.12030/j.cjee.201512088
shu

Fe3O4@改性悬铃木果毛复合中空纤维的制备及其吸附性能

  • 1. 长安大学环境科学与工程学院, 西安 710054
  • 2. 天津大学环境科学与工程学院, 天津 300072
  • 收稿日期:  2016-01-29
基金项目:

陕西省自然科学基金资助项目(2015JQ5173)

2016年中央高校基本科研业务费专项资金项目(310829162016)

陕西省2014年度留学人员科技活动择优资助项目(0308-11000152003)

长安大学2015年大学生创新创业训练计划项目(201510710143)

摘要: 选用对空气和人居环境具有污染的悬铃木果毛为基质,通过将四氧化三铁磁性纳米粒子在多巴胺改性悬铃木果毛表面的固载,制备得到具有中空结构的Fe3O4@改性悬铃木果毛复合吸附材料。用X射线衍射仪(XRD)、能谱(EDS)、电子扫描电镜(SEM)、红外光谱(FT-IR)和震动样品磁强计(VSM)等手段对样品进行了表征和分析,考察了Fe3O4@改性悬铃木果毛复合中空纤维对亚甲基蓝的吸附性能。结果表明:通过多巴胺对悬铃木果毛的化学改性,有效促进了反尖晶石型结构的四氧化三铁纳米粒子在其表面的固载,Fe3O4@改性悬铃木果毛复合中空纤维直径约为25.8 μm,其饱和磁化强度为12.51 emu/g, Fe3O4@改性悬铃木果毛对亚甲基蓝的吸附在140 min达到平衡,吸附容量可达12.6 mg/g,吸附动力学符合准二级动力学。

English Abstract

    全文HTML

参考文献 (23)

返回顶部

目录

/

返回文章
返回

Copyright © 2019 中国科学院生态环境研究中心