粉末活性炭对水中氯酚的吸附

钟少芬, 莫健文, 李阳苹, 刘煜平. 粉末活性炭对水中氯酚的吸附[J]. 环境工程学报, 2016, 10(6): 2927-2932. doi: 10.12030/j.cjee.201501023
引用本文: 钟少芬, 莫健文, 李阳苹, 刘煜平. 粉末活性炭对水中氯酚的吸附[J]. 环境工程学报, 2016, 10(6): 2927-2932. doi: 10.12030/j.cjee.201501023
Zhong Shaofen, Mo Jianwen, Li Yangping, Liu Yuping. Adsorption of chlorophenols in water by powdered activated carbon[J]. Chinese Journal of Environmental Engineering, 2016, 10(6): 2927-2932. doi: 10.12030/j.cjee.201501023
Citation: Zhong Shaofen, Mo Jianwen, Li Yangping, Liu Yuping. Adsorption of chlorophenols in water by powdered activated carbon[J]. Chinese Journal of Environmental Engineering, 2016, 10(6): 2927-2932. doi: 10.12030/j.cjee.201501023

粉末活性炭对水中氯酚的吸附

  • 基金项目:

    国家火炬计划重大子项目 (2012GH722201)

    广东高校化工清洁生产与绿色化学品工程技术开发中心开放基金(201402)

    东莞市社会科技发展项目(2013108101032)

  • 中图分类号: X703

Adsorption of chlorophenols in water by powdered activated carbon

  • Fund Project:
  • 摘要: 2,4-二氯酚、2,4,6-三氯酚、五氯酚是氯酚类污染物的典型代表,鉴于其对人类身体健康的危害和对环境所造成的污染,已被很多国家列为环境优先控制污染物。研究粉末活性炭(PAC)对该3种氯酚的吸附过程以及投炭量、pH值和水质对PAC吸附性能的影响。结果表明:粉末活性炭可以有效去除水中的80%以上的氯酚;吸附行为符合Freundlich吸附等温线和Langmuir吸附等温线;以分子状态存在的氯酚比电离状态更容易被活性炭所吸附。
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  • [1] 王晓蓉. 环境化学. 南京: 南京大学出版社, 1997: 92-96
    [2] 张晓健. 松花江和北江水污染事件中的城市供水应急处理技术. 给水排水, 2006, 32(6): 6-12 Zhang Xiaojian. Emergent drinking water treatment in water pollution accidents in Songhuajiang River and Beijiang River. Water & Wastewater Engineering, 2006, 32(6): 6-12(in Chinese)
    [3] 刘百仓, 韩帮军, 马军, 等. 粉末活性炭吸附去除松花江原水中有机物的研究. 中国给水排水, 2008, 24(21): 38-41 Liu Baicang, Han Bangjun, Ma Jun, et al. Removal of organic pollutants from raw water of Songhua River by powdered activated carbon. China Water & Wastewater, 2008, 24(21): 38-41(in Chinese)
    [4] 蒋晓凤, 朱斌, 盛梅. 有机污染水源水的粉末活性炭处理技术研究. 工业水处理, 2009, 29(4): 74-75 Jiang Xiaofeng, Zhu Bin, Sheng Mei. Study on the treatment of polluted organic source water by powdered activated carbon. Industrial Water Treatment, 2009, 29(4): 74-75(in Chinese)
    [5] 郑淑平, 李亚静, 孙力平. 聚合氯化铝与粉末活性炭联合强化混凝处理垃圾渗滤液. 环境工程学报, 2013, 7(7): 2443-2446 Zheng Shuping, Li Yajing, Sun Liping. Enhanced coagulation of landfill leachate with combination of polyaluminum chloride and powdered activated carbon. Chinese Journal of Environmental Engineering, 2013, 7(7): 2443-2446(in Chinese)
    [6] Chang Sheng, Waite T. D., Ong P. E. A., et al. Assessment of trace estrogenic contaminants removal by coagulant addition, powdered activated carbon adsorption and powdered activated carbon/microfiltration processes. Journal of Environmental Engineering, 2004, 130(7): 736-742
    [7] Radhika M., Palanivelu K. Adsorptive removal of chlorophenols from aqueous solution by low cost adsorbent: Kinetics and isotherm analysis. Journal of Hazardous Materials, 2006, 138(1): 116-124
    [8] 刘振中, 邓慧萍, 詹健. 改性活性炭对2, 4, 6-三氯酚的吸附. 土木建筑与环境工程, 2009, 31(6): 123-127 Liu Zhenzhong, Deng Huiping, Zhan Jian. Performance analysis of 2, 4, 6-trichlorophenol adsorption by modified GAC. Journal of Civil, Architectural & Environmental Engineering, 2009, 31(6): 123-127(in Chinese)
    [9] 李勇, 张伯友, 肖贤明, 等. 氯酚化合物在活性炭上的吸附. 水处理技术, 2006, 32(3): 19-22 Li Yong, Zhang Boyou, Xiao Xianming, et al. Adsorption of chlorophenols on activated carbon. Technology of Water Treatment, 2006, 32(3): 19-22(in Chinese)
    [10] Srivastava S. K., Tyagi R. Competitive adsorption of substituted phenols by activated carbon developed from the fertilizer waste slurry. Water Research, 1995, 29(2): 483-488
    [11] Moreno-Castilla C., Rivera-Utrilla J., López-Ramón M. V., et al. Adsorption of some substituted phenols on activated carbons from a bituminous coal. Carbon, 1995, 33(6): 845-851
    [12] 何文杰, 谭浩强, 韩宏大, 等. 粉末活性炭对水中农药的吸附性能研究. 环境工程学报, 2010, 4(8): 1692-1696 He Wenjie, Tan Haoqiang, Han Hongda, et al. Study on adsorption of pesticides from water by powdered activated carbon. Chinese Journal of Environmental Engineering, 2010, 4(8): 1692-1696(in Chinese)
    [13] 陆朝阳, 李爱民. 活性炭对芳香有机物的吸附作用力研究进展. 离子交换与吸附, 2011, 27(5): 474-480 Lu Zhaoyang, Li Aimin. Progress in the research on adsorption force of aromatics by activated carbon. Ion Exchange and Adsorption, 2011, 27(5): 474-480(in Chinese)
    [14] Pelekanl C., Snoeyink V. L. Competitive adsorption in natural water: Role of activated carbon pore size. Water Research, 1999, 33(5): 1209-1219
    [15] Estevinho B. N., Ratola N., Alves A., et al. Pentachlorophenol removal from aqueous matrices by sorption with almond shell residues. Journal of Hazardous Materials, 2006, 137(2): 1175-1181
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出版历程
  • 收稿日期:  2015-03-20
  • 刊出日期:  2016-06-03
钟少芬, 莫健文, 李阳苹, 刘煜平. 粉末活性炭对水中氯酚的吸附[J]. 环境工程学报, 2016, 10(6): 2927-2932. doi: 10.12030/j.cjee.201501023
引用本文: 钟少芬, 莫健文, 李阳苹, 刘煜平. 粉末活性炭对水中氯酚的吸附[J]. 环境工程学报, 2016, 10(6): 2927-2932. doi: 10.12030/j.cjee.201501023
Zhong Shaofen, Mo Jianwen, Li Yangping, Liu Yuping. Adsorption of chlorophenols in water by powdered activated carbon[J]. Chinese Journal of Environmental Engineering, 2016, 10(6): 2927-2932. doi: 10.12030/j.cjee.201501023
Citation: Zhong Shaofen, Mo Jianwen, Li Yangping, Liu Yuping. Adsorption of chlorophenols in water by powdered activated carbon[J]. Chinese Journal of Environmental Engineering, 2016, 10(6): 2927-2932. doi: 10.12030/j.cjee.201501023

粉末活性炭对水中氯酚的吸附

  • 1.  东莞理工学院能源与化工系, 东莞 523808
  • 2.  东莞市清洁生产科技中心, 东莞 523808
  • 3.  五邑大学分析测试中心, 江门 529020
基金项目:

国家火炬计划重大子项目 (2012GH722201)

广东高校化工清洁生产与绿色化学品工程技术开发中心开放基金(201402)

东莞市社会科技发展项目(2013108101032)

摘要: 2,4-二氯酚、2,4,6-三氯酚、五氯酚是氯酚类污染物的典型代表,鉴于其对人类身体健康的危害和对环境所造成的污染,已被很多国家列为环境优先控制污染物。研究粉末活性炭(PAC)对该3种氯酚的吸附过程以及投炭量、pH值和水质对PAC吸附性能的影响。结果表明:粉末活性炭可以有效去除水中的80%以上的氯酚;吸附行为符合Freundlich吸附等温线和Langmuir吸附等温线;以分子状态存在的氯酚比电离状态更容易被活性炭所吸附。

English Abstract

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