纳米铁酸铜催化过硫酸盐降解酸性红FRL

黄晓东; 徐清艳

doi:10.12030/j.cjee.201412225

环境工程学报

纳米铁酸铜催化过硫酸盐降解酸性红FRL

黄晓东, 徐清艳. 纳米铁酸铜催化过硫酸盐降解酸性红FRL[J]. 环境工程学报, 2016, 10(5): 2435-2439. doi: 10.12030/j.cjee.201412225

引用本文:

黄晓东, 徐清艳. 纳米铁酸铜催化过硫酸盐降解酸性红FRL[J]. 环境工程学报, 2016, 10(5): 2435-2439. doi: 10.12030/j.cjee.201412225

Huang Xiaodong, Xu Qingyan. Degradation of Acid Red FRL by persulfate with nanometer copper ferrite as catalyst[J]. Chinese Journal of Environmental Engineering, 2016, 10(5): 2435-2439. doi: 10.12030/j.cjee.201412225

Citation:

Huang Xiaodong, Xu Qingyan. Degradation of Acid Red FRL by persulfate with nanometer copper ferrite as catalyst[J]. Chinese Journal of Environmental Engineering, 2016, 10(5): 2435-2439. doi: 10.12030/j.cjee.201412225

纳米铁酸铜催化过硫酸盐降解酸性红FRL

黄晓东¹,
徐清艳¹

1.
闽江学院化学与化学工程系, 福州 350108
基金项目:
福建省自然科学基金资助项目(2012D107)
中图分类号: X703.1

Degradation of Acid Red FRL by persulfate with nanometer copper ferrite as catalyst

Huang Xiaodong¹,
Xu Qingyan¹

1.
Department of Chemistry and Chemical Engineering, Minjiang University, Fuzhou 350108, China
Fund Project:

摘要: 采用共沉淀法-焙烧制备纳米铁酸铜催化剂,利用扫描电镜(SEM)、X射线光电子能谱(XPS)和X射线衍射 (XRD)对催化剂进行表征。以酸性红FRL为降解目标物,研究此催化剂催化过硫酸钠降解酸性红FRL的性能。考察了氧化剂浓度、催化剂用量和初始染料浓度对降解的影响。结果表明:催化剂经700 ℃焙烧3 h,可得到完整晶相的CuFe2O4;当初始污染物浓度为20 mg/L,过硫酸盐浓度为2.0 g/L,催化剂用量为2.0 g/L时,降解2.5 h,酸性红FRL染料溶液的降解率可达85.3%。实验所得催化剂可重复使用5次,同时酸性红FRL降解过程遵循准一级动力学方程。
- 铁酸铜 /
- 过硫酸钠 /
- 酸性红FRL
Abstract: Nanometer-sized copper ferrite catalysts were prepared through a co-precipitation-calcination method and were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and X-ray powder diffraction (XRD). The degradation performance by persulfate was investigated through the catalyst with Acid Red FRL as the target pollutant. The effects of factors such as concentration of oxidant, dosage of catalyst, and initial concentration of pollutants were studied. The results showed that the catalyst could achieve the complete crystal phase of CuFe2O4 after roasting for 3 h at 700 ℃. The degradation rate of Acid Red FRL reached 85.3% after 2.5 h under certain conditions (initial Acid Red FRL concentration of 20 mg/L, oxidant concentration of 2.0 g/L, catalyst dosage of 2.0 g/L). The catalyst could be used repeatedly five times, and the degradation of Acid Red FRL followed a pseudo-first-order kinetics equation.
- copper ferrite /
- sodium persulfate /
- Acid Red FRL

[1]	Lin Yating, Liang Chenju, Chen J. H. Feasibility study of ultraviolet activated persulfate oxidation of phenol. Chemosphere, 2011, 82(8): 1168-1172
[2]	Ghauch A., Tuqan A. M., Kibbi N. Ibuprofen removal by heated persulfate in aqueous solution: A kinetics study. Chemical Engineering Journal, 2012, 197: 483-492
[3]	Xu Xiangrong, Li Xiangzhong. Degradation of azo dye Orange G in aqueous solutions by persulfate with ferrous ion. Separation and Purification Technology, 2010, 72(1): 105-111
[4]	Criquet J., Leitner N. K. V. Electron beam irradiation of aqueous solution of persulfate ions. Chemical Engineering Journal, 2011, 169(1-3): 258-262
[5]	Chen W. S., Su Yichang. Removal of dinitrotoluenes in wastewater by sono-activated persulfate. Ultrasonics Sonochemistry, 2012, 19(4): 921-927
[6]	Tan Chaoqun, Gao Naiyun, Chu Wenhai, et al. Degradation of diuron by persulfate activated with ferrous ion. Separation and Purification Technology, 2012, 95: 44-48
[7]	Oh S. Y., Kang S. G., Kim D. W., et al. Degradation of 2, 4-dinitrotoluene by persulfate activated with iron sulfides. Chemical Engineering Journal, 2011, 172(2-3): 641-646
[8]	Usman M., Faure P., Ruby C., et al. Application of magnetite-activated persulfate oxidation for the degradation of PAHs in contaminated soils. Chemosphere, 2012, 87(3): 234-240
[9]	黄晓东, 涂佳. 活性炭负载铁催化过硫酸盐降解酸性大红3R. 环境科学学报, 2014, 34(6): 1449-1454 Huang Xiaodong, Tu Jia. Degradation of acid red 3R by persulfate with Fe-loaded activated carbon as catalyst. Acta Scientiae Circumstantiae, 2014, 34(6): 1449-1454(in Chinese)
[10]	吉飞, 李朝林, 邓磊, 等. CuO/过硫酸氢钾体系催化氧化苯酚. 环境工程学报, 2014, 8(1): 27-31 Ji Fei, Li Chaolin, Deng Lei, et al. Catalytic oxidation of phenol by CuO/peroxymonosulfate system. Chinese Journal of Environmental Engineering, 2014, 8(1): 27-31(in Chinese)
[11]	Yan Jingchun, Lei Min, Zhu Lihua, et al. Degradation of sulfamonomethoxine with Fe₃O₄ magnetic nanoparticles as heterogeneous activator of persulfate. Journal of Hazardous Materials, 2011, 186(2-3): 1398-1404
[12]	林家敏, 谢吉民, 吕晓萌, 等. CuFe₂O₄纳米粉体的制备及其可见光催化性能. 环境科学与技术, 2008, 31(11): 21-23 Lin Jiamin, Xie Jimin, Lü Xiaomeng, et al. Spinel CuFe₂O₄ Nano-particles: Preparation and photocatalytic property under visible light irradiation. Environmental Science & Technology, 2008, 31(11): 21-23(in Chinese)
[13]	田喜强, 董艳萍, 赵东江, 等. 纳米铁酸锰的合成及其在污水处理中的应用. 工业水处理, 2010, 30(12): 70-73 Tian Xiqiang, Dong Yanping, Zhao Dongjiang, et al. Synthesis of nano-manganese ferrite and its application to wastewater treatment. Industrial Water Treatment, 2010, 30(12): 70-73(in Chinese)
[14]	李磊, 顾文秀, 吴婷婷, 等. 铁酸盐材料制备及应用进展. 现代化工, 2013, 33(2): 7-10 Li Lei, Gu Wenxiu, Wu Tingting, et al. Progress of preparation and application of ferrite materials. Modern Chemical Industry, 2013, 33(2): 7-10(in Chinese)
[15]	刘辉, 魏雨. 纳米级铁酸盐粉体材料合成的进展. 功能材料, 2000, 31(2): 124-126 Liu Hui, Wei Yu. Progress on synthesis methods of nanosized ferrite particals. Journal of Functional Materials, 2000, 31(2): 124-126(in Chinese)
[16]	廖辉伟, 穆兰, 宋玉亮, 等. 纳米CuFe₂O₄催化硫酸铜热分解及机理研究. 中国粉体技术, 2009, 15(3): 34-37 Liao Huiwei, Mu Lan, Song Yuliang, et al. Investigation on catalytic thermal decomposition behavior and mechanism of bluestone by CuFe₂O₄ Nano-particles. China Powder Science and Technology, 2009, 15(3): 34-37(in Chinese)

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黄晓东, 徐清艳. 纳米铁酸铜催化过硫酸盐降解酸性红FRL[J]. 环境工程学报, 2016, 10(5): 2435-2439. doi: 10.12030/j.cjee.201412225

引用本文:

黄晓东, 徐清艳. 纳米铁酸铜催化过硫酸盐降解酸性红FRL[J]. 环境工程学报, 2016, 10(5): 2435-2439. doi: 10.12030/j.cjee.201412225

Citation:

纳米铁酸铜催化过硫酸盐降解酸性红FRL

黄晓东¹,
徐清艳¹

1. 闽江学院化学与化学工程系, 福州 350108

收稿日期: 2015-01-20

基金项目:

福建省自然科学基金资助项目(2012D107)

关键词:

铁酸铜 /
过硫酸钠 /
酸性红FRL

摘要: 采用共沉淀法-焙烧制备纳米铁酸铜催化剂,利用扫描电镜(SEM)、X射线光电子能谱(XPS)和X射线衍射 (XRD)对催化剂进行表征。以酸性红FRL为降解目标物,研究此催化剂催化过硫酸钠降解酸性红FRL的性能。考察了氧化剂浓度、催化剂用量和初始染料浓度对降解的影响。结果表明:催化剂经700 ℃焙烧3 h,可得到完整晶相的CuFe2O4;当初始污染物浓度为20 mg/L,过硫酸盐浓度为2.0 g/L,催化剂用量为2.0 g/L时,降解2.5 h,酸性红FRL染料溶液的降解率可达85.3%。实验所得催化剂可重复使用5次,同时酸性红FRL降解过程遵循准一级动力学方程。

English Abstract

Degradation of Acid Red FRL by persulfate with nanometer copper ferrite as catalyst

Huang Xiaodong¹,
Xu Qingyan¹

1. Department of Chemistry and Chemical Engineering, Minjiang University, Fuzhou 350108, China

Received Date: 2015-01-20

Fund Project:

Keywords:

Abstract: Nanometer-sized copper ferrite catalysts were prepared through a co-precipitation-calcination method and were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and X-ray powder diffraction (XRD). The degradation performance by persulfate was investigated through the catalyst with Acid Red FRL as the target pollutant. The effects of factors such as concentration of oxidant, dosage of catalyst, and initial concentration of pollutants were studied. The results showed that the catalyst could achieve the complete crystal phase of CuFe2O4 after roasting for 3 h at 700 ℃. The degradation rate of Acid Red FRL reached 85.3% after 2.5 h under certain conditions (initial Acid Red FRL concentration of 20 mg/L, oxidant concentration of 2.0 g/L, catalyst dosage of 2.0 g/L). The catalyst could be used repeatedly five times, and the degradation of Acid Red FRL followed a pseudo-first-order kinetics equation.

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纳米铁酸铜催化过硫酸盐降解酸性红FRL

Degradation of Acid Red FRL by persulfate with nanometer copper ferrite as catalyst

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纳米铁酸铜催化过硫酸盐降解酸性红FRL

English Abstract

Degradation of Acid Red FRL by persulfate with nanometer copper ferrite as catalyst

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