RESEARCH PROGRESS ON MECHANISMS ABOUT THE EFFECT OF IONIC STRENGTH ON ADSORPTION

WU Zhijian; LIU Haining; ZHANG Huifang

2010 Volume 29 Issue 6

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WU Zhijian, LIU Haining, ZHANG Huifang. RESEARCH PROGRESS ON MECHANISMS ABOUT THE EFFECT OF IONIC STRENGTH ON ADSORPTION[J]. Environmental Chemistry, 2010, 29(6): 997-1003.

Citation:

WU Zhijian, LIU Haining, ZHANG Huifang. RESEARCH PROGRESS ON MECHANISMS ABOUT THE EFFECT OF IONIC STRENGTH ON ADSORPTION[J]. Environmental Chemistry, 2010, 29(6): 997-1003.

RESEARCH PROGRESS ON MECHANISMS ABOUT THE EFFECT OF IONIC STRENGTH ON ADSORPTION

1.
College of Materials Science and Engineering, Huaqiao University, Quanzhou, 362021, China;
2.
Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining, 810008, China;
3.
The Graduate University of Chinese Academy of Sciences, Beijing, 100049, China

Received Date: 24/12/2009

Fund Project:

Abstract

The effect of ionic strength on the adsorption at solid/liquid interface has been discussed based on the introduction of the hydration of molecules and ions, the Stern and classical triple-layer models at metal oxide/water solution interfaces, and inner and outer sphere surface complexes. Generally speaking, with the increase in ionic strength, the electrostatic interactions between adsorbents and adsorbates decrease, and the hydrophobic interactions increase, the complexation does not have any obvious changes. Electrolytes affect adsorption by ion exchange competition with adsorbate ions, by salting-in and salting-out effects on adsorbates, by changing adsorbate molecular size, and by forming ion pairs with adsorbates, etc.
- adsorption,
- ionic strength,
- electrostatic interaction,
- hydrophobic interaction,
- complexation

References

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沈阳化工大学材料科学与工程学院沈阳 110142

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RESEARCH PROGRESS ON MECHANISMS ABOUT THE EFFECT OF IONIC STRENGTH ON ADSORPTION

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