2018 Volume 12 Issue 7
Article Contents

CHEN Chuihan, SUN Jianyang, LI Ying, ZHAO Xu, WU Hongjuan. Adsorption of methylene blue on activated carbon prepared from printing sludge[J]. Chinese Journal of Environmental Engineering, 2018, 12(7): 1872-1878. doi: 10.12030/j.cjee.201710068
Citation: CHEN Chuihan, SUN Jianyang, LI Ying, ZHAO Xu, WU Hongjuan. Adsorption of methylene blue on activated carbon prepared from printing sludge[J]. Chinese Journal of Environmental Engineering, 2018, 12(7): 1872-1878. doi: 10.12030/j.cjee.201710068

Adsorption of methylene blue on activated carbon prepared from printing sludge

  • Accepted Date: 13/10/2017
    Available Online: 26/07/2018
    Fund Project:
  • The sludge activated carbon derived from print sludge and ZnCl2 (chemical activating reagent) was used as adsorbent for methylene blue removal. The morphology and crystalline structures of the obtained sludge activated carbon were studied by the scanning electron microscopy and X-ray powder diffraction. The results showed that the pore structure of sludge activated carbon was mesoporous, which is benefit for the adsorption of macromolecular dye. The effects of sawdust dosage, initial pH, absorption temperature and initial concentration on the adsorption of methylene blue were studied. The adsorption capacity of the obtained samples can be improved by addition of sawdust with 1% ratio, whereas the excess amount of sawdust show negative effect to the pore structure of activated carbon. The adsorption capacity of the prepared sludge activated carbon decreased with the increase of pH.In the range from 5 to 45 ℃, the adsorption capability of the sludge activated carbon was gradually increased with temperature increasing and the maximum adsorption capacity can be achieved when the temperature was up to 45 ℃.The adsorption behavior of the sludge activated carbon were investigated from the thermodynamic aspect, and the results indicated that the adsorption of the sludge activated carbon on methylene blue followed the Langmuir isotherm equation. The obtained results may provide some support for the treatment of the sludge generated from dye wastewater treatment.
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  • [1] 史玲, 董社英, 柏世厚, 等. 常温常压催化湿式氧化降解偶氮染料废水的研究 [J]. 环境工程学报,2011,5(6):1325-1329

    Google Scholar Pub Med

    [2] 邹华生, 闫晓满, 黎民乐. 超声场耦合曝气生物填料塔处理印染废水技术 [J]. 华南理工大学学报 (自然科学版),2009,37(10):140-144

    Google Scholar Pub Med

    [3] 郑先君, 姜巧娟, 魏丽芳, 等. 纳米 TiO2光催化降解印染废水的研究 [J]. 环境科学与技术,2009,32(4):159-162

    Google Scholar Pub Med

    [4] LUTTERBECK C A, MACHADO E L, KAMMERER K.Photodegradation of the antineoplastic cyclophosphamide:A comparative study of the efficiencies of UV/H2O2, UV/Fe2+/H2O2 and UV/TiO2 processes [J].Chemosphere,2015,120:538-546 10.1016/j.chemosphere.2014.08.076

    Google Scholar Pub Med

    [5] 张淑会, 吕庆, 胡晓. 吸附剂烟气脱砷的研究现状 [J]. 环境科学与技术,2011,4(3):197-204

    Google Scholar Pub Med

    [6] 刘宝河, 孟冠华, 陶冬民, 等. 污泥吸附剂对3种染料吸附动力学的研究 [J]. 环境工程学报,2011,5(1):95-99

    Google Scholar Pub Med

    [7] 王旺阳, 刘聪, 袁珮. 吸附法去除环境中多环芳烃的研究进展 [J]. 化工进展,2017,36(1):355-363

    Google Scholar Pub Med

    [8] 吴光前, 吴冠男, 张齐生, 等. 竹炭吸附对硝基苯胺的过程与机理研究 [J]. 环境工程学报,2017,11(1):251-259 10.12030/j.cjee.201509119

    Google Scholar Pub Med

    [9] 何品晶, 顾国维, 李笃中. 城市污泥处理与利用 [M]. 北京:科学出版社,2003

    Google Scholar Pub Med

    [10] 莫测辉, 吴启堂, 蔡全英, 等. 论城市污泥农用资源化与可持续发展 [J]. 应用生态学报,2000,11(1):157-160

    Google Scholar Pub Med

    [11] 任爱玲, 王启山, 贺君. 城市污水处理厂污泥制活性炭的研究 [J]. 环境科学,2004,25(S1):48-51

    Google Scholar Pub Med

    [12] 田甲蕊. 改性印染污泥干化和掺烧特性研究 [D].南京:东南大学,2015

    Google Scholar Pub Med

    [13] 陈勇. 印染废水污泥处理技术分析 [J]. 广东化工,2012,42(9):177-178

    Google Scholar Pub Med

    [14] 林乔乔, 朱化军. 印染污泥焚烧干化方法经济性分析 [J]. 环境卫生工程,2015,23(4):35-37

    Google Scholar Pub Med

    [15] 解建坤, 岳钦艳, 于慧, 等. 污泥活性炭对活性艳K-2BP染料的吸附特性研究 [J]. 山东大学学报(理学版),2007,42(3):64-70

    Google Scholar Pub Med

    [16] 尹炳奎. 污泥活性炭吸附剂材料的制备及其在废水处理中的应用 [D]. 上海:上海交通大学,2007

    Google Scholar Pub Med

    [17] CHEN X, JEYASEELAN S, GRAHAM N.Physical and chemical properties study of the activated carbon made from sewage sludge [J].Waste Management,2002,22(7):755-760 10.1016/S0956-053X(02)00057-0

    Google Scholar Pub Med

    [18] 焦李, 蔡海燕, 何丕文, 等. 脱水污泥/松木锯末水蒸气共气化研究 [J]. 环境科学学报,2013,33(4):1098-1103

    Google Scholar Pub Med

    [19] LI W H, YUE Q H, TU P, et al.Adsorption characteristics of dyes in columns of activated carbon prepared from paper mill sewage sludge [J].Chemical Engineering Journal,2011,178:197-203 10.1016/j.cej.2011.10.049

    Google Scholar Pub Med

    [20] LI, Y J, YUE Q H, LI W H, et al.Properties improvement of paper mill sludge-based granular activated carbon fillers for fluidized-bed bioreactor by bentonite (Na) added and acid washing [J].Journal of Hazardous Materials,2011,197:33-39 10.1016/j.jhazmat.2011.197.09.050

    Google Scholar Pub Med

    [21] SUN R Q, SUN L B, CHUN Y, et al.Catalytic performance of porous carbons obtained by chemical activation[J].Carbon,2008,46(13):1757-1764 10.1016/j.carbon.2008.07.029

    Google Scholar Pub Med

    [22] 骆红超, 宋磊, 吴雨琛. 还原和氧化改性活性炭对亚甲基蓝吸附性能的影响[J]. 化工新型材料,2013,31(1):76-79

    Google Scholar Pub Med

    [23] 刘亚纳, 周鸣, 汤红妍, 等. 亚甲基蓝在污泥活性炭上的吸附[J].环境工程学报,2012,6(7):2339-2344

    Google Scholar Pub Med

    [24] 叶宏萌, 李国平, 饶瑞晔,等. 松果活性炭对有机染料的吸附[J]. 环境工程学报,2016,10(12):6995-7000 10.12030/j.cjee.201507152

    Google Scholar Pub Med

    [25] 高宁, 卜龙利, 刘嘉栋,等. 颗粒活性炭对水中典型医药类物质的吸附特性[J]. 环境工程学报,2016,10(8):4289-4297 10.12030/j.cjee.201503145

    Google Scholar Pub Med

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Adsorption of methylene blue on activated carbon prepared from printing sludge

Fund Project:

Abstract: The sludge activated carbon derived from print sludge and ZnCl2 (chemical activating reagent) was used as adsorbent for methylene blue removal. The morphology and crystalline structures of the obtained sludge activated carbon were studied by the scanning electron microscopy and X-ray powder diffraction. The results showed that the pore structure of sludge activated carbon was mesoporous, which is benefit for the adsorption of macromolecular dye. The effects of sawdust dosage, initial pH, absorption temperature and initial concentration on the adsorption of methylene blue were studied. The adsorption capacity of the obtained samples can be improved by addition of sawdust with 1% ratio, whereas the excess amount of sawdust show negative effect to the pore structure of activated carbon. The adsorption capacity of the prepared sludge activated carbon decreased with the increase of pH.In the range from 5 to 45 ℃, the adsorption capability of the sludge activated carbon was gradually increased with temperature increasing and the maximum adsorption capacity can be achieved when the temperature was up to 45 ℃.The adsorption behavior of the sludge activated carbon were investigated from the thermodynamic aspect, and the results indicated that the adsorption of the sludge activated carbon on methylene blue followed the Langmuir isotherm equation. The obtained results may provide some support for the treatment of the sludge generated from dye wastewater treatment.

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