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刘洋, 胡筱敏, 赵研, 王军, 鲍佳. 全氟化合物及其替代品的处理技术[J]. 环境化学, 2018, 37(8): 1860-1868. doi: 10.7524/j.issn.0254-6108.2017122904
引用本文: 刘洋, 胡筱敏, 赵研, 王军, 鲍佳. 全氟化合物及其替代品的处理技术[J]. 环境化学, 2018, 37(8): 1860-1868. doi: 10.7524/j.issn.0254-6108.2017122904
shu
LIU Yang, HU Xiaomin, ZHAO Yan, WANG Jun, BAO Jia. Treatment techniques for perfluorinated compounds and their alternatives[J]. Environmental Chemistry, 2018, 37(8): 1860-1868. doi: 10.7524/j.issn.0254-6108.2017122904
Citation: LIU Yang, HU Xiaomin, ZHAO Yan, WANG Jun, BAO Jia. Treatment techniques for perfluorinated compounds and their alternatives[J]. Environmental Chemistry, 2018, 37(8): 1860-1868. doi: 10.7524/j.issn.0254-6108.2017122904
shu

全氟化合物及其替代品的处理技术

  • 1.

    东北大学资源与土木工程学院, 沈阳, 110819;

  • 2.

    沈阳工业大学理学院, 沈阳, 110870

  • 基金项目:

    国家自然科学基金（21507092，51678118）资助.

Treatment techniques for perfluorinated compounds and their alternatives

  • 1.

    School of Resources and Civil Engineering, Northeastern University, Shenyang, 110819, China;

  • 2.

    School of Science, Shenyang University of Technology, Shenyang, 110870, China

  • Fund Project: Supported by the National Natural Science Foundation of China (21507092, 51678118).

  • 摘要: 全氟化合物（PFCs）及其替代品是具有污染持久性、生物毒性和累积性的氟烃类化合物，严重威胁生态系统乃至人类健康.已有PFCs及其替代品的处理技术主要包括吸附、电化学氧化等，各技术的去除效果和适用范围不尽相同.目前我国缺少针对PFCs及其替代品处理技术的系统总结和对比研究.为了选择适合且有效的技术去除PFCs及其替代品污染物，本文详细介绍了近年来处理该类污染物的常用技术，从去除效果、去除机理及适用性等方面对比不同技术的优势与不足，并展望不同技术的发展趋势，为我国PFCs及其替代品的有效治理与控制提供科学依据.
    Abstract: Perfluorinated compounds (PFCs) and their alternatives are fluorinated hydrocarbons, which are persistent, toxic, and bioaccumulative, posing potential threats to the biosystems and even human health. So far, several treating techniques including adsorption and electrochemistry for PFCs and their alternatives have been developed, yet their removal efficiencies and applications are extremely different. Moreover, little systematic review and comparative research is available about the treating techniques for PFCs and their alternatives. In order to screen a suitable and effective removal technique for PFCs and their alternatives, extensive details were summarized from treating techniques in recent years. Based upon the comparisons among the removal efficiencies, removal mechanisms, applicability, advantages, and disadvantages of those techniques, and further analysis of their developing trends, a scientific basis for the effective treatment of PFCs and their alternatives could be provided.
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  • [1] CAMPO J, PEREZ F, MASIA A, et al. Perfluoroalkyl substance contamination of the Llobregat River ecosystem (Mediterranean area, NE Spain)[J]. Science of the Total Environment, 2015, 503-504:48-57.
    [2] 周秀鹃, 盛南, 王建设, 等.全氟和多氟化合物替代品的研究进展[J]. 生态毒理学报,2017,12(3):3-12.

    ZHOU X J, SHENG N, WANG J S, et al. The current research status of several kinds of fluorinated alternatives[J]. Asian Journal of Ecotoxicology, 2017, 12(3):3-12(in Chinese).

    [3] WANG S W, HUANG J, YANG Y, et al. First report of a chinese PFOS alternative overlooked for 30 years:its toxicity, persistence, and presence in the environment[J]. Environmetal Science and Technology, 2013, 47:10163-10170.
    [4] SHI G H, CUI Q Q, PAN Y T, et al. 6:2 Chlorinated polyfluorinated ether sulfonate a PFOS alternative induces embryo toxicity and disrupts cardiac development in zebrafish embryos[J]. Aquatic Toxicology, 2017, 185:67-75.
    [5] NELSON J W, HATCH E E, WEBSTER T F. Exposure to polyfluoroalkyl chemicals and cholesterol, body weight, and insulin resistance in the general U.S. population[J]. Environmental Health Perspectives, 2010, 118(2):197-202.
    [6] BAO J, LIU L, WANG X, et al. Human exposure to perfluoroalkyl substances near a fluorochemical industrial park in China[J]. Environmental Science and Pollution Research, 2017, 24(10):9194-9201.
    [7] TAKAGI S, ADACHI F, MIYANO K, et al. Perfluorooctane sulfonate and perfluorooctanoate in raw and treated tap water from Osaka, Japan[J]. Chemosphere, 2008, 72(10):1409-1412.
    [8] 王凯, 郭昌盛, 张远, 等.不同微生物处理工艺对全氟化合物的去除效果[J]. 环境科学研究,2015,28(1):110-116.

    WANG K, GUO C S, ZHANG Y, et al. Removal efficiency of perfluorinated compounds with different microbial treatment techniques[J]. Research of Environmental Sciences, 2015, 28(1):110-116(in Chinese).

    [9] DU Z W, DENG S B, BEI Y, et al. Adsorption behavior and mechanism of perfluorinated compounds on various adsorbents-A review[J]. Journal of Hazardous Materials, 2014, 274:443-454.
    [10] LIN H, WANG Y J, NIU J F, et al. Efficient Sorption and Removal of Perfluoroalkyl Acids (PFAAs) from aqueous solution by metal hydroxides generated in situ by electrocoagulation[J]. Environment Science and Technology, 2015, 49:10562-10569.
    [11] WANG Y J, LIN H, JIN F Y, et al. Electrocoagulation mechanism of perfluorooctanoate (PFOA) on a zinc anode:Influence of cathodes and anions[J]. Science of the Total Environment, 2016, 557-558(2016):542-550.
    [12] YANG B, HAN Y, YU G, et al. Efficient removal of perfluoroalkyl acids (PFAAs) from aqueous solution by electrocoagulation using iron electrode[J]. Chemical Engineering Journal, 2016, 303:384-390.
    [13] 余强.水中典型全氟化合物的吸附去除研究[D].北京:清华大学,2010. YU Q. Removal of representative perfluorinated compounds from water by sorption process[D]. Beijing:Tsinghua University, 2010(in Chinese).
    [14] PAN G, JIA C X, ZHAO D Y, et al. Effect of cationic and anionic surfactants on the sorption and desorption of perfluorooctane sulfonate (PFOS) on natural sediments[J]. Environmental Pollution, 2009, 157:325-330.
    [15] 童锡臻, 石宝友,解岳, 等.改性活性炭对水中PFOS的吸附去除研究[J]. 环境科学,2012,33(9):3132-3138.

    TONG Z X, SHI B Y, XIE Y, et al. Adsorption of perfluorooctanesulfonate (PFOS) onto modified activated carbons[J]. Environmental Science, 2012, 33(9):3132-3138(in Chinese).

    [16] 周艳萍, 温蓓, 胡晓宇, 等.全氟化合物在碳纳米管上的吸附研究[J]. 环境化学,2011,30(12):2003-2008.

    ZHOU Y P, WEN B, HU X Y, et al. Adsorption of perfluorinated compounds on multiwalled carbon nanotubes[J]. Environmental Chemistry, 2011, 30(12):2003-2008(in Chinese).

    [17] 周艳萍, 温蓓, 胡晓宇,等.全氟化合物在阳离子表面活性剂改性碳纳米管上的吸附[J]. 环境化学,2012,31(1):43-49.

    ZHOU Y P, WEN B, HU X Y, et al. Adsorption of perfluorinated compounds on cationic surfactant coated multiwalled carbon nanotubes[J]. Environmental Chemistry, 2012,31(1):43-49(in Chinese).

    [18] WANG H Y, LI X N, ZHANG Y B, et al. Electrochemically enhanced adsorption of PFOA and PFOS on multiwalled carbon nanotubes in continuous flow mode[J]. Chinese Science Bulletin, 2014, 59(23):2890-2897.
    [19] CHULARUEANGAKSORN P, TANAKA S, FUJⅡ S, et al. Adsorption of perfluorooctanoic acid (PFOA) onto anion exchange resin, non-ion exchange resin, and granular-activated carbon by batch and column[J]. Desalination and Water Treatment, 2013, 51:1-7.
    [20] ZAGGIA A, CONTE L, FALLETTI L, et al. Use of strong anion exchange resins for the removal of perffluoroalkylated substances from contaminated drinking water in batch and continuous pilot plants[J]. Water Research, 2016, 91:137-146.
    [21] GAO Y X, DENG S B, DU Z W, et al. Adsorptive removal of emerging polyfluoroalky substances F-53B and PFOS by anion-exchange resin:A comparative study[J]. Journal of Hazardous Materials, 2017, 323:550-557.
    [22] DENG S B, ZHUO Q, YU G, et al. Removal of perfluorooctanoate from surface water by polyaluminium chloride coagulation[J]. Water Research, 2011, 45:1774-1780.
    [23] XIAO F, SIMCIK M F, GULLIVER J S. Mechanisms for removal of perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) from drinking water by conventional and enhanced coagulation[J]. Water Research, 2013, 47:49-56.
    [24] ZHAO L X, BIAN J N, ZHANGY H, et al. Comparison of the sorption behaviors and mechanisms of perfluorosulfonates and perfluorocarboxylic acids on three kinds of clay minerals[J]. Chemosphere, 2014,114:51-58.
    [25] ARVANITI O S, HWANG Y, ANDERSEN H R, et al. Reductive degradation of perfluorinated compounds in water using Mg-aminoclay coated nanoscale zero valent iron[J]. Chemical Engineering Journal, 2015, 262:133-139.
    [26] 牛利.氨化吸附剂的制备及吸附重金属和全氟化合物研究[D].北京:清华大学,2011. NIU L. Aminated sorbents preparation and adsorption for heavy metals and PFCs[D]. Beijing:Tsinghua University, 2011(in Chinese).
    [27] NIU J F, LI Y, SHANG E X, et al. Electrochemical oxidation of perfluorinated compounds in water[J]. Chemosphere, 2016,146:526-538.
    [28] LIN H, NIU J F, DING S Y, et al. Electrochemical degradation of perfluorooctanoic acid (PFOA) by Ti/SnO2-Sb, Ti/SnO2-Sb/PbO2 and Ti/SnO2-Sb/MnO2 anodes[J]. Water Research, 2012, 46:2281-2289.
    [29] LIN H, NIU J F, XU J L, et al. Highly efficient and mild electrochemical mineralization of long-chain perfluorocarboxylic acids (C9-C10) by Ti/SnO2-Sb-Ce, Ti/SnO2-Sb/Ce-PbO2, and Ti/BDD electrodes[J]. Environment Science and Technology, 2013,47:13039-13046.
    [30] ZHUO Q F, DENG S B, YANG B, et al. Efficient electrochemical oxidation of perfluorooctanoate using a Ti/SnO2-Sb-Bi anode[J]. Environment Science and Technology, 2011, 45:2973-2979.
    [31] NIU J F, LIN H, GONG C, et al. Theoretical and experimental insights into the electrochemical mineralization mechanism of perfluorooctanoic acid[J]. Environmental Science and Technology, 2013, 47:14341-14349.
    [32] PARK S, LEE L S, MEDINA V F. Heat-activated persulfate oxidation of PFOA, 6:2 fluorotelomer sulfonate, and PFOS under conditions suitable for in-situ groundwater remediation[J]. Chemosphere, 2016, 82(6):376-383.
    [33] YAMAMOTO T, NOMA Y, SAKAI S, et al. Photodegradation of perfluorooctane sulfonate by UV irradiation in water and alkaline2-propanol[J]. Environmental Science and Technology, 2007, 41:5660-5665.
    [34] 宋洲. 紫外光化学氧化/还原处理全氟辛酸的研究[D].武汉:华中科技大学,2014. SONG Z. Photochemical oxidation or reduction degradation of perfluorooctanoic acid using UV irradiation[D]. Wuhan:Huazhong University of Science and Technology, 2014(in Chinese).
    [35] CHEN Y C, LO S L, KUO J. Effects of titanate nanotubes synthesized by a microwave hydrothermal method on photocatalytic decomposition of perfluorooctanoic acid[J]. Water Research,2011,45:4131-4140.
    [36] 张健, 赵长伟, 宋娜, 等.纳滤去除饮用水中的PFOS[J].环境工程学报,2013,7(11):4236-4240.

    ZHANG J, ZHAO C W, SONG N, et al. Nanofiltration membrane process for removal of PFOS from drinking water[J]. Chinese Journal of Environmental Engineering, 2013, 7(11):4236-4240(in Chinese).

    [37] HANG X F, CHEN X R, LUO J Q, et al. Removal and recovery of perfluorooctanoate from wastewater by nanofiltration[J]. Separation and Purification Technology, 2015,145:120-129.
    [38] 王涛, 李烨, 马文瑾, 等.PMIA中空纤维纳滤膜去除饮用水中的PFOS[J]. 水处理技术,2015,41(7):103-108.

    WANG T, LI Y, MA W J, et al. Removal of PFOS from drinking water using PMIA hollow fiber nanofiltration membrane[J]. Technology of Water Treatment, 2015, 41(7):103-108(in Chinese).

    [39] TANG C Y, FU Q S, ROBERTSON A P, et al. Use of reverse osmosis membranes to remove perfluorooctane sulfonate (PFOS) from semiconductor wastewater[J]. Environmental Science and Technology, 2006, 40(23):7343-7349.
    [40] LEE Y C, LO S L, CHIUEH P T, et al. Efficient decomposition of perfluorocarboxylic acids in aqueous solution using microwave-induced persulfate[J]. Water Research, 2009, 43:2811-2816.
    [41] LEE Y C, LO S L, CHIUEH P T, et al. Microwave-hydrothermal decomposition of perfluoroooctanoic acid in water by iron-actived persulfate oxidation[J]. Water Research, 2010, 44:886-892.
    [42] KRUSIC P J, MARCHIONE A A, ROE D C, et al. Gas-phase NMR studies of the thermolysis of perfluorooctanoic acid[J]. Journal of Fluorine Chemistry, 2005,126:1510-1516.
    [43] MORIWAKI H, TAKAGI Y, TANAKA M, et al. Sonochemical decomposition of perfluorooctane sulfonate and perfluorooctanoic acid[J]. Environmental Science and Technology, 2005, 39:3388-3392.
    [44] VECITIS C D, PARK H, CHENG J, et al. Kinetics and mechanism of the sonolytic conversion of the aqueous perfluorinated surfactants, perfluorooctanoate (PFOA), and perfluorooctane sulfonate (PFOS) into inorganic products[J]. Journal of Physical Chemistry A, 2008, 112(18):4261-4270.
    [45] ZHANG Z, CHEN J J, LYU X J, et al. Complete mineralization of perffluorooctanoic acid (PFOA) by gamma-irradiation in aqueous solution[J]. Scientific Reports, 2014, 4(7418):1-6.
    [46] YAN X, LIU X, QI C, et al. Mechanochemical destruction of achlorinated polyfluorinated ether sulfonate (F-53B, a PFOS alternative) assisted by sodium persulfate, Research Advances, 2015, 5:85785-85790.
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  • 收稿日期:  2017-12-29
  • 刊出日期:  2018-08-15
刘洋, 胡筱敏, 赵研, 王军, 鲍佳. 全氟化合物及其替代品的处理技术[J]. 环境化学, 2018, 37(8): 1860-1868. doi: 10.7524/j.issn.0254-6108.2017122904
引用本文: 刘洋, 胡筱敏, 赵研, 王军, 鲍佳. 全氟化合物及其替代品的处理技术[J]. 环境化学, 2018, 37(8): 1860-1868. doi: 10.7524/j.issn.0254-6108.2017122904
shu
LIU Yang, HU Xiaomin, ZHAO Yan, WANG Jun, BAO Jia. Treatment techniques for perfluorinated compounds and their alternatives[J]. Environmental Chemistry, 2018, 37(8): 1860-1868. doi: 10.7524/j.issn.0254-6108.2017122904
Citation: LIU Yang, HU Xiaomin, ZHAO Yan, WANG Jun, BAO Jia. Treatment techniques for perfluorinated compounds and their alternatives[J]. Environmental Chemistry, 2018, 37(8): 1860-1868. doi: 10.7524/j.issn.0254-6108.2017122904
shu

全氟化合物及其替代品的处理技术

  • 1.  东北大学资源与土木工程学院, 沈阳, 110819;
  • 2.  沈阳工业大学理学院, 沈阳, 110870
  • 收稿日期:  2017-12-29
基金项目:

国家自然科学基金（21507092，51678118）资助.

摘要: 全氟化合物（PFCs）及其替代品是具有污染持久性、生物毒性和累积性的氟烃类化合物，严重威胁生态系统乃至人类健康.已有PFCs及其替代品的处理技术主要包括吸附、电化学氧化等，各技术的去除效果和适用范围不尽相同.目前我国缺少针对PFCs及其替代品处理技术的系统总结和对比研究.为了选择适合且有效的技术去除PFCs及其替代品污染物，本文详细介绍了近年来处理该类污染物的常用技术，从去除效果、去除机理及适用性等方面对比不同技术的优势与不足，并展望不同技术的发展趋势，为我国PFCs及其替代品的有效治理与控制提供科学依据.

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