钛磁铁矿异相Fenton法对亚甲基蓝模拟废水的脱色研究
DECOLORIZATION OF METHYLENE BLUE BY HETEROGENEOUS FENTON REACTION USING TITANOMAGNETITE
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摘要: 本研究运用紫外可见光谱、傅立叶转换红外光谱和13C核磁共振谱以及水相中溶解性有机碳和固相上元素碳分析等技术对钛磁铁矿异相Fenton法脱色亚甲基蓝的过程进行了研究.实验结果表明:钛磁铁矿异相Fenton法对亚甲基蓝的脱色速率远高于磁铁矿;在钛磁铁矿异相Fenton法脱色亚甲基蓝过程中,脱除的亚甲基蓝都已被降解,且钛磁铁矿没有发生相变;虽然钛磁铁矿异相Fenton法不能使亚甲基蓝矿化,但亚甲基蓝结构中的苯环已经被打开.
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关键词:
- 钛磁铁矿 /
- 合成 /
- 异相Fenton反应 /
- 亚甲基蓝
Abstract: In this study,titanomagnetite was synthesized using a soft chemical method. Then,synthetic titanomagnetite was firstly used as a new heterogeneous Fenton catalyst for the decolorization of methylene blue(MB). As compared with magnetite,titanomagnetite showed a more excellent catalytic activity for MB decolorization.Decolorization of MB by heterogeneous Fenton reaction using titanomagnetite was studied using UV-Vis spectra,Fourier transform infrared spectroscopy(FTIR),13C nuclear magnetic resonance spectra(13C NMR),dissolved organic carbon(DOC)and element C analyses. During the decolorization,most of MB removed from reaction solution was degraded and the phase transformation of titanomagnetite did not happen.Although MB was not mineralized,the aromatic rings in MB were destroyed completely.-
Key words:
- titanomagnetite /
- synthesis /
- heterogeneous Fenton reaction /
- methylene blue
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