短链氯化石蜡环境分析方法新进展

王迎军, 王亚韡, 曾力希, 李向军. 短链氯化石蜡环境分析方法新进展[J]. 环境化学, 2017, 36(8): 1700-1710. doi: 10.7524/j.issn.0254-6108.2016121201
引用本文: 王迎军, 王亚韡, 曾力希, 李向军. 短链氯化石蜡环境分析方法新进展[J]. 环境化学, 2017, 36(8): 1700-1710. doi: 10.7524/j.issn.0254-6108.2016121201
WANG Yingjun, WANG Yawei, ZENG Lixi, LI Xiangjun. New developments in environmental analysis of short chain chlorinated paraffins[J]. Environmental Chemistry, 2017, 36(8): 1700-1710. doi: 10.7524/j.issn.0254-6108.2016121201
Citation: WANG Yingjun, WANG Yawei, ZENG Lixi, LI Xiangjun. New developments in environmental analysis of short chain chlorinated paraffins[J]. Environmental Chemistry, 2017, 36(8): 1700-1710. doi: 10.7524/j.issn.0254-6108.2016121201

短链氯化石蜡环境分析方法新进展

  • 基金项目:

    国家自然科学基金(21377001,21577142,41522304)和北京市自然科学基金(8152029)资助.

New developments in environmental analysis of short chain chlorinated paraffins

  • Fund Project: Supported by the National Natural Science Foundation of China (21377001,21577142,41522304) and the Beijing Municipal Natural Science Foundation (8152029).
  • 摘要: 短链氯化石蜡(SCCPs)是链长10-13个碳原子的复杂直链烷烃工业产品,具有持久性、远距离迁移性、生物毒性、生物蓄积性等持久性有机污染物(POPs)特性.目前,国际上对SCCPs的环境行为和归趋的研究相对有限,主要的原因之一是SCCPs分析方法的局限.本文对近几年SCCPs的分析方法的发展,包括提取、净化、分离、检测、定量,进行详细的综述,为我国在此方面的研究提供参考.
  • 加载中
  • [1] DE BOER J, EL-SAYED AT, FILDER H, et al. Chlorinated Paraffins//de Boer J, ed. The handbook of environ chemistry[M]. Berlin:Springer-Verlag Press, 2010.
    [2] UNEP. Short-chained chlorinated paraffins:Revised draft risk profile UNEP/POP/PORC.8/6[C]. United Nations Environmental Programme Stockholm Convention on Persistent Organic Pollutants, Geneva, 2012.
    [3] FEO M L, ELJARRAT E, BARCELO D. Occurrence, fate and analysis of polychlorinated n-alkanes in the environment[J]. Trac-Trends in Analytical Chemistry, 2009, 28(6):778-791.
    [4] TOMY G T, STERN G A, LOCKHART W L, et al. Occurrence of C-10-C-13 polychlorinated n-alkanes in Canadian midlatitude and arctic lake sediments[J]. Environ Sci Technol, 1999, 33(17):2858-2863.
    [5] COOLEY H M, FISK A T, WIENS S C, et al. Examination of the behavior and liver and thyroid histology of juvenile rainbow trout (Oncorhynchus mykiss) exposed to high dietary concentrations of C-10-, C-11-, C-12-and C-14-polychlorinated n-alkanes[J]. Aquat Toxicol, 2001, 54(1-2):81-99.
    [6] WARNASURIYA G D, ELCOMBE B M, FOSTER J R, et al. A mechanism for the induction of renal tumours in male Fischer 344 rats by short-chain chlorinated paraffins[J]. Arch Toxicol, 2010, 84(3):233-243.
    [7] SHAW S D, BLUM A, WEBER R, et al. Halogenated flame retardants:Do the fire safety benefits justify the risks?[J]. Reviews on Environmental Health, 2010, 25(4):261-305.
    [8] GENG N, ZHANG H, ZHANG B, et al. Effects of short-chain chlorinated paraffins exposure on the viability and metabolism of human hepatoma HepG2 cells[J]. Environmental Science & Technology, 2015, 49(5):3076-3083.
    [9] IOZZA S, MULLER C E, SCHMID P, et al. Historical profiles of chlorinated paraffins and polychlorinated biphenyls in a dated sediment core from Lake Thun (Switzerland)[J]. Environ Sci Technol, 2008, 42(4):1045-1050.
    [10] HOUDE M, MUIR D C G, TOMY G T, et al. Bioaccumulation and trophic magnification of short-and medium-chain chlorinated paraffins in food webs from Lake Ontario and Lake Michigan[J]. Environ Sci Technol, 2008, 42(10):3893-3899.
    [11] FISK A T, CYMBALISTY C D, BERGMAN A, et al. Dietary accumulation of C-12-and C-16-chlorinated alkanes by juvenile rainbow trout (Oncorhynchus mykiss)[J]. Environ Toxicol Chem, 1996, 15(10):1775-1782.
    [12] FISK A T, CYMBALISTY C D, TOMY G T, et al. Dietary accumulation and depuration of individual C-10-, C-11-and C-14-polychlorinated alkanes by juvenile rainbow trout (Oncorhynchus mykiss)[J]. Aquat Toxicol, 1998, 43(2-3):209-221.
    [13] RENBERG L, TARKPEA M, SUNDSTROM G. The use of the bivalve Mytilus-edulis as a test organism for bioconcentration studies.2. The bioconcentration of 2 C-14-labeled chlorinated paraffins[J]. Ecotox Environ Safe, 1986, 11(3):361-372.
    [14] 仝宣昌, 胡建信, 刘建国,等. 我国短链氯化石蜡的环境暴露与风险分析[J]. 环境科学与技术, 2009(B06):438-441. TONG X C, HU J X, LIU J G, et al. Environment exposure analysis and screening risk assessment of short chain chlorinated paraffins in China[J]. Environmental Science & Technology, 2009

    (B06):438-441(in Chinese).

    [15] 袁博, 王亚韡, 傅建捷, 等. 氯化石蜡分析方法的研究及土壤样品中氯化石蜡的测定[J]. 科学通报, 2010, 55(19):1879-1885.

    YUAN B, WANG Y W, FU J J, et al. Study on the analytical method of chlorinated paraffins and the determination of chlorinated paraffins in soil samples[J]. Chinese Science Bulletin, 2010, 55(19):1879-1885(in Chinese).

    [16] UNECE. Study contract on "support related to the international work on Persistent Organic Pollutants (POPs)" management option dossier for Short Chain Chlorinated Paraffins (SCCPs)[C]. Updated version on the basis of the outcome of the Sixth Meeting of the Task Force on POPs, 2007, 261(4):1335-1345.
    [17] CHEN M Y, LUO X J, ZHANG X L, et al. Chlorinated paraffins in sediments from the Pearl River Delta, South China:Spatial and temporal distributions and implication for processes[J]. Environ Sci Technol, 2011, 45(23):9936-9943.
    [18] 王亚韡, 傅建捷, 江桂斌. 短链氯化石蜡及其环境污染现状与毒性效应研究[J]. 科学通报, 2009, 28(1):1-9.

    WANG Y W, FU J J, JIANG G B. The research of environmentai pollutions and toxic effect of short chain chlorinated paraffins[J]. Chinese Science Bulletin, 2009, 28(1):1-9(in Chinese).

    [19] VAN MOURIK L M, LEONARDS P E G, GAUS C, et al. Recent developments in capabilities for analysing chlorinated paraffins in environmental matrices:A review[J]. Chemosphere, 2015, 136:259-272.
    [20] BAYEN S, OBBARD J P, THOMAS G O. Chlorinated paraffins:A review of analysis and environmental occurrence[J]. Environ Int, 2006, 32(7):915-929.
    [21] Li Q L, LI J, WANG Y, et al. Atmospheric short-chain chlorinated paraffins in China, Japan, and South Korea[J]. Environ Sci Technol, 2012, 46(21):11948-11954.
    [22] WANG Y, LI J, CHENG Z N, et al. Short-and medium-chain chlorinated paraffins in air and soil of subtropical terrestrial environment in the Pearl River Delta, South China:Distribution, composition, atmospheric deposition fluxes, and environmental fate[J]. Environ Sci Technol, 2013, 47(6):2679-2687.
    [23] CHAEMFA C, XU Y, LI J, et al. Screening of atmospheric short-and medium-chain chlorinated paraffins in india and Pakistan using polyurethane foam based passive air sampler[J]. Environ Sci Technol, 2014, 48(9):4799-4808.
    [24] PETERS A J, TOMY G T, JONES K C, et al. Occurrence of C-10-C-13 polychlorinated n-alkanes in the atmosphere of the United Kingdom[J]. Atmos Environ, 2000, 34(19):3085-3090.
    [25] STEVENSON G, YATES A, GILLETT R, et al.Interlaboratory comparison of short chain chlorinated paraffins analysismethods applied to indoor air samples from Melbourne[J]. Australia.Organohalogen Compd, 2011,73:1367-1369.
    [26] FRIDéN U E, MCLACHLAN M S, BERGER U. Chlorinated paraffins in indoor air and dust:Concentrations, congener patterns, and human exposure[J]. Environ Int, 2011, 37(7):1169-1174.
    [27] MA X D, ZHANG H J, ZHOU H Q, et al. Occurrence and gas/particle partitioning of short-and medium-chain chlorinated paraffins in the atmosphere of Fildes Peninsula of Antarctica[J]. Atmos Environ, 2014, 90(1):10-15.
    [28] GEIß S, EINAX J W, SCOTT S P. Determination of the sum of short chain polychlorinated n-alkanes with a chlorine content of between 49 and 67% in water by GC-ECNI-MS and quantification by multiple linear regression[J]. Clean, 2010, 38(1):57-76.
    [29] NICHOLLS C R, ALLCHIN C R, LAW R J. Levels of short and medium chain length polychlorinated n-alkanes in environmental samples from selected industrial areas in England and Wales[J]. Environ Pollut, 2001, 114(3):415-430.
    [30] CASTELLS P, SANTOS F J, GALCERAN M T. Solid-phase extraction versus solid-phase microextraction for the determination of chlorinated paraffins in water using gas chromatography-negative chemical ionisation mass spectrometry[J]. Journal of Chromatography A, 2004, 1025(2):157-162.
    [31] CASTELLS P, SANTOS F J, GALCERAN M T. Solid-phase microextraction for the analysis of short-chain chlorinated paraffins in water samples[J]. Journal of Chromatography A, 2003, 984(1):1-8.
    [32] GANDOLF I F, MALLERET L, SERGENT M, et al. Parameters optimization using experimental design for headspace solid phase micro-extraction analysis of short-chain chlorinated paraffins in waters under the European water framework directive[J]. Journal of Chromatography A, 2015, 1406:59-67.
    [33] GEIß S, LöFFLER D, KöRNER B, et al. Determination of the sum of short chain chlorinated n-alkanes with a chlorine content between 50% and 67% in sediment samples by GC-ECNI-MS and quantification by multiple linear regression[J]. Microchemical Journal, 2015, 119:30-39.
    [34] HüTTIG J, OEHME M. Presence of chlorinated paraffins in sediments from the North and Baltic Seas[J]. Archives of Environmental Contamination and Toxicology, 2005, 49(4):449-456.
    [35] ⅡNO F, TAKASUGA T, SENTHILKUMAR K, et al. Risk assessment of short-chain chlorinated paraffins in Japan based on the first market basket study and species sensitivity distributions[J]. Environ Sci Technol, 2005, 39(3):859-866.
    [36] CASTELLS P, PARERA J, SANTOS F J, et al. Occurrence of polychlorinated naphthalenes, polychlorinated biphenyls and short-chain chlorinated paraffins in marine sediments from Barcelona (Spain)[J]. Chemosphere, 2008, 70(9):1552-1562.
    [37] GAO Y, ZHANG H J, CHEN J P, et al. Optimized cleanup method for the determination of short chain polychlorinated n-alkanes in sediments by high resolution gas chromatography/electron capture negative ion-low resolution mass spectrometry[J]. Anal Chim Acta, 2011, 703(2):187-193.
    [38] GAO Y, ZHANG H J, SU F, et al. Environmental occurrence and distribution of short chain chlorinated paraffins in sediments and soils from the Liaohe River Basin, P. R. China[J]. Environ Sci Technol, 2012, 46(7):3771-3778.
    [39] WANG X T, WANG X K, ZHANG Y, et al. Short-and medium-chain chlorinated paraffins in urban soils of Shanghai:Spatial distribution, homologue group patterns and ecological risk assessment[J]. Sci Total Environ, 2014, 490C:144-152.
    [40] CHEN L G, HUANG Y M, HAN S, et al. Sample pretreatment optimization for the analysis of short chain chlorinated paraffins in soil with gas chromatography-electron capture negative ion-mass spectrometry[J]. Journal of Chromatography A, 2013, 1274(2):36-43.
    [41] BOGDAL C, ALSBERG T, Diefenbacher P S, et al. Fast quantification of chlorinated paraffins in environmental samples by direct injection high-resolution mass spectrometry with pattern deconvolution[J]. Anal Chem, 2015, 87(5):2852-2860.
    [42] ZENG L, LI H, WANG T, et al. Behavior, fate, and mass loading of short chain chlorinated paraffins in an advanced municipal sewage treatment plant[J]. Environ Sci Technol, 2013, 47(2):732-740.
    [43] ZENG L, WANG T, WANG P, et al. Distribution and trophic transfer of short-chain chlorinated paraffins in an aquatic ecosystem receiving effluents from a sewage treatment plant[J]. Environ Sci Technol, 2011, 45(13):5529-5535.
    [44] ZENG L X, CHEN R, ZHAO Z S, et al. Spatial distributions and deposition chronology of short chain chlorinated paraffins in marine sediments across the Chinese Bohai and Yellow Seas[J]. Environ Sci Technol, 2013, 47(20):11449-11456.
    [45] ZENG L X, ZHAO Z S, LI H J, et al. Distribution of short chain chlorinated paraffins in marine sediments of the East China Sea:Influencing factors, transport and implications[J]. Environ Sci Technol, 2012, 46(18):9898-9906.
    [46] ZENG L, WANG T, RUAN T, et al. Levels and distribution patterns of short chain chlorinated paraffins in sewage sludge of wastewater treatment plants in China[J]. Environmental Pollution, 2012, 160(1):88-94.
    [47] ZENG L X, WANG T, HAN W Y, et al. Spatial and vertical distribution of short chain chlorinated paraffins in soils from wastewater irrigated farmlands[J]. Environ Sci Technol, 2011, 45(6):2100-2106.
    [48] HUSSY I, WEBSTER L, RUSSELL M, et al. Determination of chlorinated paraffins in sediments from the Firth of Clyde by gas chromatography with electron capture negative ionisation mass spectrometry and carbon skeleton analysis by gas chromatography with flame ionisation detection[J]. Chemosphere, 2012, 88(3):292-299.
    [49] PARERA J, SANTOS F J, GALCERAN M T. Microwave-assisted extraction versus Soxhlet extraction for the analysis of short-chain chlorinated alkanes in sediments[J]. Journal of Chromatography A, 2004, 1046(1-2):19-26.
    [50] ZENG L X, LAM J C W, WANG Y W, et al. Temporal trends and pattern changes of short-and medium-chain chlorinated paraffins in marine mammals from the South China Sea over the past decade[J]. Environ Sci Technol, 2015, 49(19):11348-11355.
    [51] YUAN B, WANG T, ZHU N, et al. Short chain chlorinated paraffins in mollusks from coastal waters in the Chinese Bohai Sea[J]. Environ Sci Technol, 2012, 46(12):6489-6496.
    [52] PARERA J, ABALOS M, SANTOS F J, et al. Polychlorinated dibenzo-p-dioxins, dibenzofurans, biphenyls, paraffins and polybrominated diphenyl ethers in marine fish species from Ebro River Delta (Spain)[J]. Chemosphere, 2013, 93(3):499-505.
    [53] STRID A, BRUHN C, SVERKO E, et al. Brominated and chlorinated flame retardants in liver of Greenland shark (Somniosus microcephalus)[J]. Chemosphere, 2013, 91(2):222-228.
    [54] JENSEN S, HäGGBERG L, JöRUNDSDóTTIR H, et al. A quantitative lipid extraction method for residue analysis of fish involving nonhalogenated solvents[J]. Journal of Agricultural and Food Chemistry, 2003, 51(19):5607-5611.
    [55] BENDIG P, HAGELE F, VETTER W. Widespread occurrence of polyhalogenated compounds in fat from kitchen hoods[J]. Analytical and Bioanalytical Chemistry, 2013, 405(23):7485-7496.
    [56] GAO W, WU J, WANG Y W, et al. Distribution and congener profiles of short-chain chlorinated paraffins in indoor/outdoor glass window surface films and their film-air partitioning in Beijing, China[J]. Chemosphere, 2016, 144:1327-1333.
    [57] WANG T, YU J, HAN S, et al. Levels of short chain chlorinated paraffins in pine needles and bark and their vegetation-air partitioning in urban areas[J]. Environ Pollut, 2015, 196:309-312.
    [58] COELHAN M. Determination of short chain polychlorinated paraffins in fish samples by short column GC/ECNI-MS[J]. Anal Chem, 1999, 71(20):4498-4505.
    [59] RIEGER R, BALLSCHMITER K. Semivolatile organic compounds-polychlorinated dibenzo-p-dioxins (PCDD), dibenzofurans (PCDF), biphenyls (PCB), hexachlorobenzene (HCB), 4,4'-DDE and chlorinated paraffins (CP)-as markers in sewer films[J]. Fresenius' Journal of Analytical Chemistry, 1995, 352(7):715-724.
    [60] ŠTEJNAROVá P, COELHAN M, KOSTRHOUNOVá R, et al. Analysis of short chain chlorinated paraffins in sediment samples from the Czech Republic by short-column GC/ECNI-MS[J]. Chemosphere, 2005, 58(3):253-262.
    [61] KORYTáR P, LEONARDS P E G, DE BOER J, et al. Group separation of organohalogenated compounds by means of comprehensive two-dimensional gas chromatography[J]. Journal of Chromatography A, 2005, 1086(1-2):29-44.
    [62] XIA D, GAO L, ZHU S, et al. Separation and screening of short-chain chlorinated paraffins in environmental samples using comprehensive two-dimensional gas chromatography with micro electron capture detection[J]. Analytical and Bioanalytical Chemistry, 2014, 406(29):7561-7570.
    [63] XIA D, GAO L R, ZHENG M H, et al. A novel method for profiling and quantifying short-and medium-chain chlorinated paraffins in environmental samples using comprehensive two-dimensional gas chromatography-electron capture negative ionization high-resolution time-of-flight mass spectrometry[J]. Environ Sci Technol, 2016, 50(14):7601-7609.
    [64] RANDEGGER-VOLLRATH A. Determination of chlorinated paraffins in cutting fluids and lubricants[J]. Fresenius' Journal of Analytical Chemistry, 1998, 360(1):62-68.
    [65] FRIDéN U, JANSSON B, PARLAR H. Photolytic clean-up of biological samples for gas chromatographic analysis of chlorinated paraffins[J]. Chemosphere, 2004, 54(8):1079-1083.
    [66] TOMY G T, TITTLEMIER S A, STERN G A, et al. Effects of temperature and sample amount on the electron capture negative ion mass spectra of polychloro-n-alkanes[J]. Chemosphere, 1998, 37(7):1395-1410.
    [67] ZENCAK Z, OEHME M. Recent developments in the analysis of chlorinated paraffins[J]. TrAC Trends in Analytical Chemistry, 2006, 25(4):310-317.
    [68] TOMY G T, STERN G A, MUIR D C G, et al. Quantifying C-10-C-13 polychloroalkanes in environmental samples by high-resolution gas chromatography electron capture negative ion high resolution mass spectrometry[J]. Anal Chem, 1997, 69(14):2762-2771.
    [69] RETH M, OEHME M. Limitations of low resolution mass spectrometry in the electron capture negative ionization mode for the analysis of short-and medium-chain chlorinated paraffins[J]. Analytical and Bioanalytical Chemistry, 2004, 378(7):1741-1747.
    [70] ELJARRAT E, BARCELó D. Quantitative analysis of polychlorinated n-alkanes in environmental samples[J]. TrAC Trends in Analytical Chemistry, 2006, 25(4):421-434.
    [71] ZENCAK Z, OEHME M. Chloride-enhanced atmospheric pressure chemical ionization mass spectrometry of polychlorinated n-alkanes[J]. Rapid Commun Mass Sp, 2004, 18(19):2235-2240.
    [72] ZENCAK Z, RETH M, OEHME M. Determination of total polychlorinated n-alkane concentration in biota by electron ionization-MS/MS[J]. Anal Chem, 2004, 76(7):1957-1962.
    [73] GAO W, WU J, WANG Y W, et al. Quantification of short-and medium-chain chlorinated paraffins in environmental samples by gas chromatography quadrupole time-of-flight mass spectrometry[J]. Journal of Chromatography A, 2016, 1452:98-106.
    [74] KOH I-O, ROTARD W, THIEMANN W H P. Analysis of chlorinated paraffins in cutting fluids and sealing materials by carbon skeleton reaction gas chromatography[J]. Chemosphere, 2002, 47(2):219-227.
    [75] MOORE S, VROMET L, RONDEAU B. Comparison of metastable atom bombardment and electron capture negative ionization for the analysis of polychloroalkanes[J]. Chemosphere, 2004, 54(4):453-459.
    [76] RETH M, ZENCAK Z, OEHME M. New quantification procedure for the analysis of chlorinated paraffins using electron capture negative ionization mass spectrometry[J]. Journal of Chromatography A, 2005, 1081(2):225-231.
    [77] GAO Y, ZHANG H, ZOU L,et al. Quantification of short-chain chlorinated paraffins by deuterodechlorination combined with gas chromatography-mass spectrometry[J]. Environ Sci Technol, 2016, 50(7):3746-3753.
    [78] BARBER J L, SWEETMAN A J, THOMAS G O, et al. Spatial and temporal variability in air concentrations of short-chain (C-10-C-13) and medium-chain (C-14-C-17) chlorinated n-alkanes measured in the UK atmosphere[J]. Environ Sci Technol, 2005, 39(12):4407-4415.
    [79] COELHAN M. Levels of Chlorinated Paraffins in Water[J]. Clean-Soil Air Water, 2010, 38(5-6):452-456.
    [80] MA X D, ZHANG H J, WANG Z, et al. Bioaccumulation and trophic transfer of short chain chlorinated paraffins in a marine food web from Liaodong Bay, North China[J]. Environ Sci Technol, 2014, 48(10):5964-5971.
    [81] PřIBYLOVá P, KLáNOVáJ, HOLOUBEK I. Screening of short-and medium-chain chlorinated paraffins in selected riverine sediments and sludge from the Czech Republic[J]. Environ Pollut, 2006, 144(1):248-254.
    [82] MA X D, CHEN C, ZHANG H J, et al. Congener-specific distribution and bioaccumulation of short-chain chlorinated paraffins in sediments and bivalves of the Bohai Sea, China[J]. Mar Pollut Bull, 2014, 79(1-2):299-304.
    [83] WANG X T, ZHANG Y, MIAO Y, et al. Short-chain chlorinated paraffins (SCCPs) in surface soil from a background area in China:Occurrence, distribution, and congener profiles[J]. Environmental Science and Pollution Research, 2013, 20(7):4742-4749.
    [84] HALSE A K, SCHLABACH M, SCHUSTER J K, et al. Endosulfan, pentachlorobenzene and short-chain chlorinated paraffins in background soils from Western Europe[J]. Environ Pollut, 2015, 196:21-28.
    [85] ZHAO Z S, LI H J, WANG Y W, et al. Source and migration of short-chain chlorinated paraffins in the Coastal East China Sea using multiproxies of marine organic geochemistry[J]. Environ Sci Technol, 2013, 47(10):5013-5022.
    [86] MORALES L, MARTRAT M G, OLMOS J, et al. Persistent organic pollutants in gull eggs of two species (Larus michahellis and Larus audouinii) from the Ebro delta Natural Park[J]. Chemosphere, 2012, 88(11):1306-1316.
    [87] RUSINA T P, KORYTáR P, DE BOER J. Comparison of quantification methods for the analysis of polychlorinated alkanes using electron capture negative ionisation mass spectrometry[J]. International Journal of Environmental Analytical Chemistry, 2011, 91(4):319-332.
    [88] HARADA K H, TAKASUGA T, HITOMI T, et al. Dietary exposure to short-chain chlorinated paraffins has increased in Beijing, China[J]. Environ Sci Technol, 2011, 45(16):7019-7027.
    [89] HILGER B, FROMME H, VOLKEL W, et al. Occurrence of chlorinated paraffins in house dust samples from Bavaria, Germany[J]. Environ Pollut, 2013, 175C:16-21.
    [90] NILSSON M L, BENGTSSON S, KYLIN H. Identification and determination of chlorinated paraffins using multivariate evaluation of gas chromatographic data[J]. Environ Pollut, 2012, 163(163):142-148.
    [91] RETH M, ZENCAK Z, OEHME M. First study of congener group patterns and concentrations of short-and medium-chain chlorinated paraffins in fish from the North and Baltic Sea[J]. Chemosphere, 2005, 58(7):847-854.
  • 加载中
计量
  • 文章访问数:  1464
  • HTML全文浏览数:  1380
  • PDF下载数:  571
  • 施引文献:  0
出版历程
  • 收稿日期:  2016-12-12
  • 刊出日期:  2017-08-15

短链氯化石蜡环境分析方法新进展

  • 1.  中国科学院大学化学与化学工程学院, 北京, 100049;
  • 2.  中国科学院生态环境研究中心, 环境化学与生态毒理学国家重点实验室, 北京, 100085;
  • 3.  暨南大学环境学院, 广州市环境暴露与健康重点实验室, 广东省环境污染与健康重点实验室, 广州, 510632
基金项目:

国家自然科学基金(21377001,21577142,41522304)和北京市自然科学基金(8152029)资助.

摘要: 短链氯化石蜡(SCCPs)是链长10-13个碳原子的复杂直链烷烃工业产品,具有持久性、远距离迁移性、生物毒性、生物蓄积性等持久性有机污染物(POPs)特性.目前,国际上对SCCPs的环境行为和归趋的研究相对有限,主要的原因之一是SCCPs分析方法的局限.本文对近几年SCCPs的分析方法的发展,包括提取、净化、分离、检测、定量,进行详细的综述,为我国在此方面的研究提供参考.

English Abstract

参考文献 (91)

目录

/

返回文章
返回