环境中有机磷酸酯阻燃剂分析方法的研究进展

胡晓辉, 仇雁翎, 朱志良, 赵建夫. 环境中有机磷酸酯阻燃剂分析方法的研究进展[J]. 环境化学, 2014, 33(12): 2076-2086. doi: 10.7524/j.issn.0254-6108.2014.12.013
引用本文: 胡晓辉, 仇雁翎, 朱志良, 赵建夫. 环境中有机磷酸酯阻燃剂分析方法的研究进展[J]. 环境化学, 2014, 33(12): 2076-2086. doi: 10.7524/j.issn.0254-6108.2014.12.013
HU Xiaohui, QIU Yanling, ZHU Zhiliang, ZHAO Jianfu. Research progress on analytical methods of organophosphate ester flame retardants in the environment[J]. Environmental Chemistry, 2014, 33(12): 2076-2086. doi: 10.7524/j.issn.0254-6108.2014.12.013
Citation: HU Xiaohui, QIU Yanling, ZHU Zhiliang, ZHAO Jianfu. Research progress on analytical methods of organophosphate ester flame retardants in the environment[J]. Environmental Chemistry, 2014, 33(12): 2076-2086. doi: 10.7524/j.issn.0254-6108.2014.12.013

环境中有机磷酸酯阻燃剂分析方法的研究进展

  • 基金项目:

    "十二五"规划水体污染控制与治理重大专项(2011ZX07103-004-03)资助.

Research progress on analytical methods of organophosphate ester flame retardants in the environment

  • Fund Project:
  • 摘要: 有机磷酸酯广泛应用于塑料、纺织品、电子设备、建筑材料中作为阻燃剂或塑化剂,其使用量逐渐增长,已经导致可以在多种环境介质中检测到.本文综述了近几年国内外对有机磷酸酯的分析方法的研究进展,介绍了从空气、沉积物、生物、水等环境介质中提取、净化和检测有机磷酸酯的多种方法和技术手段,讨论了实验过程中替代标、内标的选择及空白污染控制措施.最后,对未来相关分析方法的发展趋势进行了展望.
  • 加载中
  • [1] Schindler B K, Foerster K, Angerer J. Determination of human urinary organophosphate flame retardant metabolites by solid-phase extraction and gas chromatography-tandem mass spectrometry[J]. J Chromatogr B, 2009, 877(4): 375-381
    [2] Campone L, Piccinelli A L, Ostman C, et al. Determination of organophosphorous flame retardants in fish tissues by matrix solid-phase dispersion and gas chromatography[J]. Anal Bioanal Chem, 2010, 397(2): 799-806
    [3] Weil E D, Levchik S V. Flame retardants in commercial use or development for textiles[J]. J Fire Sci, 2008, 26(3): 243-281
    [4] Cristale J, Quintana J, Chaler R, et al. Gas chromatography/mass spectrometry comprehensive analysis of organophosphorus, brominated flame retardants, by-products and formulation intermediates in water[J]. J Chromatogr A, 2012, 1241: 1-12
    [5] Bacaloni A, Cavaliere C, Foglia P, et al. Liquid chromatography/tandem mass spectrometry determination of organophosphorus flame retardants and plasticizers in drinking and surface waters[J]. Rapid Commun Mass Sp, 2007, 21(7): 1123-1130
    [6] Marklund A, Andersson B, Haglund P. Screening of organophosphorus compounds and their distribution in various indoor environments[J]. Chemosphere, 2003, 53(9): 1137-1146
    [7] 赵劲松,王宇,王海燕,等. 有机磷酸酯类化合物的定量结构-活性关系及稳健性分析[J]. 环境化学, 2005,24(5): 573-577
    [8] Ma Y Q, Cui K Y, Zeng F, et al. Microwave-assisted extraction combined with gel permeation chromatography and silica gel cleanup followed by gas chromatography-mass spectrometry for the determination of organophosphorus flame retardants and plasticizers in biological samples[J]. Anal Chim Acta, 2013, 786: 47-53
    [9] Sundkvist A M, Olofsson U, Haglund P. Organophosphorus flame retardants and plasticizers in marine and fresh water biota and in human milk[J]. J Environ Monitor, 2010, 12(4): 943-951
    [10] Yan X J, He H, Peng Y, et al. Determination of organophosphorus flame retardants in surface water by solid phase extraction coupled with gas Chromatography-Mass spectrometry[J]. Chinese J Anal Chem, 2012, 40(11): 1693-1696
    [11] Garcia-López M, Rodriguez I, Cela R. Development of a dispersive liquid-liquid microextraction method for organophosphorus flame retardants and plastizicers determination in water samples[J]. J Chromatogr A, 2007, 1166(1/2): 9-15
    [12] Tollback J, Tamburro D, Crescenzi C, et al. Air sampling with Empore solid phase extraction membranes and online single-channel desorption/liquid chromatography/mass spectrometry analysis: Determination of volatile and semi-volatile organophosphate esters[J]. J Chromatogr A, 2006, 1129(1): 1-8
    [13] Moller A, Sturm R, Xie Z Y, et al. Organophosphorus flame retardants and plasticizers in airborne particles over the northern pacific and indian ocean toward the polar regions: Evidence for global occurrence[J]. Environ Sci Technol, 2012, 46(6): 3127-3134
    [14] Carlsson H, Nilsson U, Becker G, et al. Organophosphate ester flame retardants and plasticizers in the indoor environment: Analytical methodology and occurrence[J]. Environ Sci Technol, 1997, 31(10): 2931-2936
    [15] Bacaloni A, Cavaliere C, Foglia P, et al. Liquid chromatography/tandem mass spectrometry determination of organophosphorus flame retardants and plasticizers in drinking and surface waters[J]. Rapid Commun Mass Sp, 2007, 21(7): 1123-1130
    [16] European Commission. Regulation (EC) No. 2268/95 of 27 September 1995 concerning the second listof priority substances as foreseen under Council Regulation (EEC) No, 793/3[R]. Off J Europ Union L, 1995, 231: 18-19
    [17] European Commission. Regulation (EC) No. 2364/2000 of 25 October 2000 concerning the fourth list of priority substances as foreseen under Council Regulation (EEC) No, 793/939[R]. Off J Europ Union L, 2000, 273, 5-7
    [18] Moller A, Xie Z Y, Caba A, et al. Organophosphorus flame retardants and plasticizers in the atmosphere of the North Sea[J]. Environ Pollut, 2011, 159(12): 3660-3665
    [19] Staaf T, Ostman C. Indoor air sampling of organophosphate triesters using solid phase extraction (SPE) adsorbents[J]. J Environ Monitor, 2005, 7(4): 344-348
    [20] Marklund A, Andersson B, Haglund P. Organophosphorus flame retardants and plasticizers in air from various indoor environments[J]. J Environ Monitor, 2005, 7(8): 814-819
    [21] Bjorklund J, Isetun S, Nilsson U. Selective determination of organophosphate flame retardants and plasticizers in indoor air by gas chromatography, positive-ion chemical ionization and collision-induced dissociation mass spectrometry[J]. Rapid Commun Mass Sp, 2004, 18(24): 3079-3083
    [22] Ericsson M, Colmsjo A. Dynamic microwave-assisted extraction coupled on-line with solid-phase extraction and large-volume injection gas chromatography: Determination of organophosphate esters in air samples[J]. Anal Chem, 2003, 75(7): 1713-1719
    [23] Ingerowski G, Friedle A, Thumulla J. Chlorinated ethyl and isopropyl phosphoric acid triesters in the indoor environment-an inter-laboratory exposure study[J]. Indoor Air-International Journal of Indoor Air Quality and Climate, 2001, 11(3): 145-149
    [24] van der Veen I, de Boer J. Phosphorus flame retardants: Properties, production, environmental occurrence, toxicity and analysis[J]. Chemosphere, 2012, 88(10): 1119-1153
    [25] Garcia M, Rodriguez I, Cela R. Microwave-assisted extraction of organophosphate flame retardants and plasticizers from indoor dust samples[J]. J Chromatogr A, 2007, 1152(1/2): 280-286
    [26] Cristale J, Lacorte S. Development and validation of a multiresidue method for the analysis of polybrominated diphenyl ethers, new brominated and organophosphorus flame retardants in sediment, sludge and dust[J]. J Chromatogr A, 2013, 1305: 267-275
    [27] Stapleton H M, Klosterhaus S, Eagle S, et al. Detection of organophosphate flame retardants in furniture foam and US house dust[J]. Environ Sci Technol, 2009, 43(19): 7490-7495
    [28] van den Eede N, Dirtu A C, Neels H, et al. Analytical developments and preliminary assessment of human exposure to organophosphate flame retardants from indoor dust[J]. Environ Int, 2011, 37(2): 454-461
    [29] Isetun S, Nilsson U, Colmsjo A, et al. Air sampling of organophosphate triesters using SPME under non-equilibrium conditions[J]. Anal Bioanal Chem, 2004, 378(7): 1847-1853
    [30] Van den Eede N, Dirtu A C, Ali N, et al. Multi-residue method for the determination of brominated and organophosphate flame retardants in indoor dust[J]. Talanta, 2012, 89: 292-300
    [31] Garcia-López M, Rodriguez I, Cela R, et al. Determination of organophosphate flame retardants and plasticizers in sediment samples using microwave-assisted extraction and gas chromatography with inductively coupled plasma mass spectrometry[J]. Talanta, 2009, 79(3): 824-829
    [32] Garcia-López M, Rodriguez I, Cela R. Pressurized liquid extraction of organophosphate triesters from sediment samples using aqueous solutions[J]. J Chromatogr A, 2009, 1216(42): 6986-6993
    [33] Martinez-Carballo E, Gonzalez-Barreiro C, Sitka A, et al. Determination of selected organophosphate esters in the aquatic environment of Austria[J]. Sci Total Environ, 2007, 388(1/3): 290-299
    [34] Green N, Schlabach M, Bakke T, et al. Screening of selected metals and new organic contaminants 2007[R]. NIVA Report 5569-2008,SPFO-Report 1014/2008. TA-2367/2008. ISBN:978-82-577-5304-7.2008, ISBN:978-82-577-5304-7
    [35] Fries E, Mihajlovic I. Pollution of soils with organophosphorus flame retardants and plasticizers[J]. J Environ Monitor, 2011, 13(10): 2692-2694
    [36] 温家欣. 有机磷酸酯阻燃剂的分离分析技术及其应用研究[D]. 中山大学硕士学位论文, 2010
    [37] Kim J W, Isobe T, Chang K H, et al. Levels and distribution of organophosphorus flame retardants and plasticizers in fishes from Manila Bay, the Philippines[J]. Environ Pollut, 2011, 159(12): 3653-3659
    [38] Marklund A, Andersson B, Haglund P. Organophosphorus flame retardants and plasticizers in Swedish sewage treatment plants[J]. Environ Sci Technol, 2005, 39(19): 7423-7429
    [39] Martinez-Carballo E, Gonzalez-Barreiro C, Sitka A, et al. Determination of selected organophosphate esters in the aquatic environment of Austria[J]. Sci Total Environ, 2007, 388(1/3): 290-299
    [40] 刘艺凯,唐建辉,潘晓辉,等. 环境中多溴联苯醚分析方法的研究进展[J]. 环境化学, 2012,31(12): 1908-1915.
    [41] Quintana J B, Rodil R, Reemtsma T, et al. Organophosphorus flame retardants and plasticizers in water and air II. Analytical methodology[J]. Trac-Trend Anal Chem, 2008, 27(10SI): 904-915
    [42] Garcia-Lopez M, Rodriguez I, Cela R. Pressurized liquid extraction of organophosphate triesters from sediment samples using aqueous solutions[J]. J Chromatogr A, 2009, 1216(42): 6986-6993
    [43] Garcia A, Rodriguez I, Cela R. Optimisation of a matrix solid-phase dispersion method for the determination of organophosphate compounds in dust samples[J]. Anal Chim Acta, 2007, 590(1): 17-25
    [44] Cristale J, Katsoyiannis A, Chen C E, et al. Assessment of flame retardants in river water using a ceramic dosimeter passive sampler[J]. Environ Pollut, 2013, 172: 163-169
    [45] Ellis J, Shah M, Kubachka K M, et al. Determination of organophosphorus fire retardants and plasticizers in wastewater samples using MAE-SPME with GC-ICPMS and GC-TOFMS detection[J]. J Environ Monitor, 2007, 9(12): 1329-1336
    [46] Wang X W, Liu J F, Yin Y G. Development of an ultra-high-performance liquid chromatography-tandem mass spectrometry method for high throughput determination of organophosphorus flame retardants in environmental water[J]. J Chromatogr A, 2011, 1218(38): 6705-6711
    [47] Bollmann U E, Moler A, Xie Z Y, et al. Occurrence and fate of organophosphorus flame retardants and plasticizers in coastal and marine surface waters[J]. Water Res, 2012, 46(2): 531-538
    [48] Rodil R, Quintana J B, Lopez-Mahia P, et al. Multi-residue analytical method for the determination of emerging pollutants in water by solid-phase extraction and liquid chromatography-tandem mass spectrometry[J]. J Chromatogr A, 2009, 1216(14): 2958-2969
    [49] Regnery J, Puttmann W, Merz C, et al. Occurrence and distribution of organophosphorus flame retardants and plasticizers in anthropogenically affected groundwater[J]. J Environ Monitor, 2011, 13(2): 347-354
    [50] Garcia-Lopez M, Rodriguez I, Cela R. Mixed-mode solid-phase extraction followed by liquid chromatography-tandem mass spectrometry for the determination of tri- and di-substituted organophosphorus species in water samples[J]. J Chromatogr A, 2010, 1217(9): 1476-1484
    [51] Rodriguez I, Calvo F, Quintana J B, et al. Suitability of solid-phase microextraction for the determination of organophosphate flame retardants and plasticizers in water samples[J]. J Chromatogr A, 2006, 1108(2): 158-165
    [52] Rodil R, Quintana J B, Reemtsma T. Liquid chromatography-tandem mass spectrometry determination of nonionic organophosphorus flame retardants and plasticizers in wastewater samples[J]. Anal Chem, 2005, 77(10): 3083-3089
    [53] Meyer J, Bester K. Organophosphate flame retardants and plasticisers in wastewater treatment plants[J]. J Environ Monitor, 2004, 6(7): 599-605
    [54] Gorga M, Petrovic M, Barcelo D. Multi-residue analytical method for the determination of endocrine disruptors and related compounds in river and waste water using dual column liquid chromatography switching system coupled to mass spectrometry[J]. J Chromatogr A, 2013, 1295: 57-66
    [55] Andresen J A, Grundmann A, Bester K. Organophosphorus flame retardants and plasticisers in surface waters[J]. Sci Total Environ, 2004, 332(1/3): 155-166
    [56] Marklund A, Andersson B, Haglund P. Traffic as a source of organophosphorus flame retardants and plasticizers in snow[J]. Environ Sci Technol, 2005, 39(10): 3555-3562
    [57] Mahugo-Santana C, Sosa-Ferrera Z, Torres-Padron M E, et al. Application of new approaches to liquid-phase microextraction for the determination of emerging pollutants[J]. Trac-Trend Anal Chem, 2011, 30(5): 731-748
    [58] Garcia-Lopez M, Rodriguez I, Cela R. Evaluation of liquid-liquid microextraction using polypropylene microporous membranes for the determination of organophosphorus flame retardants and plasticizers in water samples[J]. Anal Chim Acta, 2008, 625(2): 145-153
    [59] Quintana J B, Rodil R, Lopez-Mahia P, et al. Optimisation of a selective method for the determination of organophosphorous triesters in outdoor particulate samples by pressurised liquid extraction and large-volume injection gas chromatography-positive chemical ionisation-tandem mass spectrometry[J]. Anal Bioanal Chem, 2007, 388(5/6): 1283-1293
    [60] Kawagoshi Y, Nakamura S, Fukunaga I. Degradation of organophosphoric esters in leachate from a sea-based solid waste disposal site[J]. Chemosphere, 2002, 48(2): 219-225
    [61] Otake T, Yoshinaga J, Yanagisawa Y. Analysis of organic esters of plasticizer in indoor air by GC-MS and GC-FPD[J]. Environ Sci Technol, 2001, 35(15): 3099-3102
    [62] Nagase M, Toba M, Kondo H, et al. Estimation of organophosphoric acid triesters in soft polyurethane foam using a concentrated sulfuric acid dissolution technique and gas chromatography with flame photometric detection[J]. Anal Sci, 2003, 19(12): 1617-1620
    [63] John H, Worek F, Thiermann H. LC-MS-based procedures for monitoring of toxic organophosphorus compounds and verification of pesticide and nerve agent poisoning[J]. Anal Bioanal Chem, 2008, 391(1): 97-116
    [64] Nagase M, Toba M, Kondo H, et al. Estimation of organophosphoric acid triesters in soft polyurethane foam using a concentrated sulfuric acid dissolution technique and gas chromatography with flame photometric detection[J]. Anal Sci, 2003, 19(12):1617-1620
    [65] 王晓伟,刘景富,阴永光. 有机磷酸酯阻燃剂污染现状与研究进展[J]. 化学进展, 2010(10): 1983-1992.
    [66] Quintana J B, Reemtsma T. Potential of membrane-assisted solvent extraction for the determination of phosphoric acid triesters in wastewater samples by liquid chromatography-tandem mass spectrometry[J]. J Chromatogr A, 2006, 1124(1/2): 22-28
    [67] Amini N, Crescenzi C. Feasibility of an on-line restricted access material/liquid chromatography/tandem mass spectrometry method in the rapid and sensitive determination of organophosphorus triesters in human blood plasma[J]. J Chromatogr B, 2003, 795(2): 245-256
    [68] Moller K, Nilsson U, Crescenzi C. Synthesis and evaluation of molecularly imprinted polymers for extracting hydrolysis products of organophosphate flame retardants[J]. J Chromatogr A, 2001, 938(1/2): 121-130
    [69] Quintana J B, Rodil R, Reemtsma T. Determination of phosphoric acid mono- and diesters in municipal wastewater by solid-phase extraction and ion-pair liquid chromatography-Tandem mass spectrometry[J]. Anal Chem, 2006, 78(5): 1644-1650
    [70] Kim J W, Isobe T, Sudaryanto A, et al. Organophosphorus flame retardants in house dust from the Philippines: Occurrence and assessment of human exposure[J]. Environ Sci Pollut R, 2013, 20(2): 812-822
    [71] Brandsma S H, de Boer J, Cofino W P, et al. Organophosphorus flame-retardant and plasticizer analysis, including recommendations from the first worldwide interlaboratory study[J]. Trac-Trend Anal Chem, 2013, 43(SI): 217-228
    [72] Zhang X K, Dutky R C, Fales H M. Rubber stoppers as sources of contaminants in electrospray analysis of peptides and proteins[J]. Anal Chem, 1996, 68(18): 3288-3289
  • 加载中
计量
  • 文章访问数:  1760
  • HTML全文浏览数:  1588
  • PDF下载数:  1940
  • 施引文献:  0
出版历程
  • 收稿日期:  2014-03-11
胡晓辉, 仇雁翎, 朱志良, 赵建夫. 环境中有机磷酸酯阻燃剂分析方法的研究进展[J]. 环境化学, 2014, 33(12): 2076-2086. doi: 10.7524/j.issn.0254-6108.2014.12.013
引用本文: 胡晓辉, 仇雁翎, 朱志良, 赵建夫. 环境中有机磷酸酯阻燃剂分析方法的研究进展[J]. 环境化学, 2014, 33(12): 2076-2086. doi: 10.7524/j.issn.0254-6108.2014.12.013
HU Xiaohui, QIU Yanling, ZHU Zhiliang, ZHAO Jianfu. Research progress on analytical methods of organophosphate ester flame retardants in the environment[J]. Environmental Chemistry, 2014, 33(12): 2076-2086. doi: 10.7524/j.issn.0254-6108.2014.12.013
Citation: HU Xiaohui, QIU Yanling, ZHU Zhiliang, ZHAO Jianfu. Research progress on analytical methods of organophosphate ester flame retardants in the environment[J]. Environmental Chemistry, 2014, 33(12): 2076-2086. doi: 10.7524/j.issn.0254-6108.2014.12.013

环境中有机磷酸酯阻燃剂分析方法的研究进展

  • 1.  同济大学环境科学与工程学院长江水环境教育部重点实验室, 上海, 200092;
  • 2.  同济大学环境科学与工程学院污染控制与资源化研究国家重点实验室, 上海, 200092
基金项目:

"十二五"规划水体污染控制与治理重大专项(2011ZX07103-004-03)资助.

摘要: 有机磷酸酯广泛应用于塑料、纺织品、电子设备、建筑材料中作为阻燃剂或塑化剂,其使用量逐渐增长,已经导致可以在多种环境介质中检测到.本文综述了近几年国内外对有机磷酸酯的分析方法的研究进展,介绍了从空气、沉积物、生物、水等环境介质中提取、净化和检测有机磷酸酯的多种方法和技术手段,讨论了实验过程中替代标、内标的选择及空白污染控制措施.最后,对未来相关分析方法的发展趋势进行了展望.

English Abstract

参考文献 (72)

返回顶部

目录

/

返回文章
返回