正辛醇萃取苯酚稀溶液的特性研究
EXTRACTION BEHAVIORS OF PHENOL IN DILUTE SOLUTION BY 1-OCTANOL
-
摘要: 为探索工业含酚废水处理的适宜萃取剂, 进行了正辛醇萃取苯酚稀溶液的实验研究.测定了不同pH值和苯酚初始浓度条件下的萃取平衡数据、萃残液CODCr值, 分析了萃残液中CODCr值的来源.综合考虑萃取剂的萃取能力和产生的CODCr值, 提出了酸性和中性溶液为正辛醇处理苯酚废水的适宜操作条件.以正辛醇为萃取剂对工业含酚废水进行了错流萃取实验, 论证了其应用的可行性.Abstract: In this paper,the extraction experiments have been carried out for phenolextracted with 1-octanolin dilute solution.The distribution coefficient and the CO2DCrvalue in residualphase were measured under a wide pH range and various initialphenolconcentrations in the aqueous phase,and the relationship between CO2DCr value and the solute in the residualphase was analyzed.Based on the extractability and the CO2DCr value,the solution with and acidic or neutralpH values was proposed as a suitable condition for phenolextracted by 1-octanol.Finally,the removalphenolwas successfully achieved from industrialeffluent by the extraction with 1-octanol.
-
Key words:
- phenol /
- 1-octanol /
- extraction /
- CO2DCr
-
-

计量
- 文章访问数: 767
- HTML全文浏览数: 767
- PDF下载数: 437
- 施引文献: 0