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臭氧和基于臭氧的高级氧化工艺降解农药的研究进展

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刘超, 强志民, 张涛, 张忠国. 臭氧和基于臭氧的高级氧化工艺降解农药的研究进展[J]. 环境化学, 2011, 30(7): 1225-1235.
引用本文: 刘超, 强志民, 张涛, 张忠国. 臭氧和基于臭氧的高级氧化工艺降解农药的研究进展[J]. 环境化学, 2011, 30(7): 1225-1235.
shu
LIU Chao, QIANG Zhimin, ZHANG Tao, ZHANG Zhongguo. DEGRADATION OF PESTICIDES BY OZONE AND OZONE-BASED ADVANCED OXIDATION PROCESSES: STATE-OF-THE-ART[J]. Environmental Chemistry, 2011, 30(7): 1225-1235.
Citation: LIU Chao, QIANG Zhimin, ZHANG Tao, ZHANG Zhongguo. DEGRADATION OF PESTICIDES BY OZONE AND OZONE-BASED ADVANCED OXIDATION PROCESSES: STATE-OF-THE-ART[J]. Environmental Chemistry, 2011, 30(7): 1225-1235.
shu

臭氧和基于臭氧的高级氧化工艺降解农药的研究进展

  • 1.

    中国科学院生态环境研究中心环境水质学国家重点实验室, 北京, 100085;

  • 2.

    轻工业环境保护研究所, 北京, 100089

  • 基金项目:

    国家科技支撑项目(2006BAJ08B02)

    国家863项目(2008AA06A414)

    环境水质学国家重点实验室开放基金项目(10K07ESPCR)资助.

DEGRADATION OF PESTICIDES BY OZONE AND OZONE-BASED ADVANCED OXIDATION PROCESSES: STATE-OF-THE-ART

  • 1.

    State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;

  • 2.

    Environmental Protection Research Institute of Light Industry, Beijing 100089, China

  • Fund Project:

  • 摘要: 由于农药的环境持久性以及毒性,饮用水源中的农药微污染日益受到水处理行业的关注.在众多水处理工艺中,由于其高效氧化去除有机污染物及控制嗅味等特点,臭氧及其相关高级氧化技术的应用已日趋广泛.本文综述了这些氧化技术对多类代表性农药(包括有机氯、有机磷、氨基甲酸酯、氯乙酰胺和三嗪等)的降解效能,详细讨论了农药的降解效率、反应动力学、降解副产物的分析鉴定及可能的反应途径,并评估了降解副产物的毒性,以期为饮用水源遭受农药微污染时的处理工艺选择与优化提供有益参考.
    Abstract: The micro-pollution of drinking water sources by pesticides has raised great concern in recent years due to their environmental persistence and health risk. Ozone and ozone-based advanced oxidation processes, among various water treatment technologies, have been increasingly practiced in water plants due to their effectiveness in organic pollutants removal as well as taste and odor control. In this paper, the degradation of several typical classes of pesticides, namely organochlorines, organphosphates, carbamates, chloroacetamides and triazines, by these oxidation processes is comprehensively reviewed. The degree of pesticide removal, reaction kinetics, identification of degradation byproducts, possible reaction pathways, and toxicity of degradation byproducts are all addressed and discussed. This work is expected to provide a valuable reference to water plants for the selection and/or optimization of treatment processes when the source water encounters micro-pollution by pesticides.
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  • 收稿日期:  2010-08-29
刘超, 强志民, 张涛, 张忠国. 臭氧和基于臭氧的高级氧化工艺降解农药的研究进展[J]. 环境化学, 2011, 30(7): 1225-1235.
引用本文: 刘超, 强志民, 张涛, 张忠国. 臭氧和基于臭氧的高级氧化工艺降解农药的研究进展[J]. 环境化学, 2011, 30(7): 1225-1235.
shu
LIU Chao, QIANG Zhimin, ZHANG Tao, ZHANG Zhongguo. DEGRADATION OF PESTICIDES BY OZONE AND OZONE-BASED ADVANCED OXIDATION PROCESSES: STATE-OF-THE-ART[J]. Environmental Chemistry, 2011, 30(7): 1225-1235.
Citation: LIU Chao, QIANG Zhimin, ZHANG Tao, ZHANG Zhongguo. DEGRADATION OF PESTICIDES BY OZONE AND OZONE-BASED ADVANCED OXIDATION PROCESSES: STATE-OF-THE-ART[J]. Environmental Chemistry, 2011, 30(7): 1225-1235.
shu

臭氧和基于臭氧的高级氧化工艺降解农药的研究进展

  • 1.  中国科学院生态环境研究中心环境水质学国家重点实验室, 北京, 100085;
  • 2.  轻工业环境保护研究所, 北京, 100089
  • 收稿日期:  2010-08-29
基金项目:

国家科技支撑项目(2006BAJ08B02)

国家863项目(2008AA06A414)

环境水质学国家重点实验室开放基金项目(10K07ESPCR)资助.

摘要: 由于农药的环境持久性以及毒性,饮用水源中的农药微污染日益受到水处理行业的关注.在众多水处理工艺中,由于其高效氧化去除有机污染物及控制嗅味等特点,臭氧及其相关高级氧化技术的应用已日趋广泛.本文综述了这些氧化技术对多类代表性农药(包括有机氯、有机磷、氨基甲酸酯、氯乙酰胺和三嗪等)的降解效能,详细讨论了农药的降解效率、反应动力学、降解副产物的分析鉴定及可能的反应途径,并评估了降解副产物的毒性,以期为饮用水源遭受农药微污染时的处理工艺选择与优化提供有益参考.

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