基于响应曲面法优化生物质污泥活性炭的制备方法

刘宇程; 刘骞; 陈菊; 吕忠祥; 汤历平; 石艳

doi:10.12030/j.cjee.201701034

环境工程学报

基于响应曲面法优化生物质污泥活性炭的制备方法

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刘宇程, 刘骞, 陈菊, 吕忠祥, 汤历平, 石艳. 基于响应曲面法优化生物质污泥活性炭的制备方法[J]. 环境工程学报, 2017, 11(11): 6041-6049. doi: 10.12030/j.cjee.201701034

引用本文:

LIU Yucheng, LIU Qian, CHEN Ju, LYU Zhongxiang, TANG Liping, SHI Yan. Preparation method of biological sludge activated carbon based on response surface methodology[J]. Chinese Journal of Environmental Engineering, 2017, 11(11): 6041-6049. doi: 10.12030/j.cjee.201701034

Citation:

LIU Yucheng, LIU Qian, CHEN Ju, LYU Zhongxiang, TANG Liping, SHI Yan. Preparation method of biological sludge activated carbon based on response surface methodology[J]. Chinese Journal of Environmental Engineering, 2017, 11(11): 6041-6049. doi: 10.12030/j.cjee.201701034

基于响应曲面法优化生物质污泥活性炭的制备方法

1.
西南石油大学化学化工学院, 成都 610500
2.
富顺县水务局, 富顺 643200
3.
过程装备与控制工程四川省高校重点实验室, 自贡 643000
4.
西南石油大学机电工程学院, 成都 6105000
基金项目:
西南石油大学油气田污染治理青年科研创新团队项目（2013XJZT003）

过程装备与控制工程四川省高校重点实验室开放基金资助项目（GK201616）
中图分类号: X705

Preparation method of biological sludge activated carbon based on response surface methodology

1.
College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China
2.
Water Conservancy Bureau, Fushun 643200, China
3.
Sichuan Provincial Key Lab of Process Equipment and Control, Sichuan University of Science and Engineering, Zigong 643000, China
4.
School of mechatronic Engineering, Southwest Petroleum University, Chengdu 610500, China
Fund Project:

摘要: 针对传统技术制备污泥活性炭的比表面积不高、吸附值低等不足，通过在污泥中添加核桃壳以改善污泥原料缺陷，研究了活化剂种类、核桃壳加量、活化温度、活化时间、活化剂浓度及浸渍比等影响活性炭吸附能力的制备条件。在优化后的条件下制备出了高吸附性能的生物质污泥复合活性炭。结果表明：选择氯化锌作为活化剂，核桃壳加量20%、活化温度500℃、活化时间60 min、活化剂浓度2.5 mol·L-1、浸渍比1：2.5为最优化制备条件。制备出的生物质污泥复合活性炭碘吸附值为574.11 mg·g-1，产率为43.93%。
- 生物质污泥活性炭 /
- 污泥 /
- 碘值 /
- 产率
Abstract: According to the deficiencies of traditional technology of sludge activated carbon preparation such as low specific surface area and low adsorption, the research focus on improving the defects of raw sludge material by adding walnut shell in sludge, studying the experiment condition such as the species of activator, the mass fraction of walnut shell, activation temperature, activation time, activator concentration and dipping ratio, etc. It can provide high adsorption performance biological sludge activated carbon under the optimum experimental conditions. The optimization condition is choosing Zinc chloride as activator, 20%walnut shell, activation temperature 500℃, activation time 60 min, activation concentration 2.5 mol·L-1, dipping ratio 1:2.5.The biological sludge activated carbon is prepared that the iodine index is 574.11 mg·g-1 and the yield is 43.93%.
- biological sludge activated carbon /
- sludge /
- iodine index /
- yield

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[3]	张练, 魏海浪, 张惠芳, 等. 城市污泥堆肥土地修复利用研究进展[J]. 环境卫生工程, 2013, 21(6):7-9
[4]	BOUALEM T, DEBABB A, YUSO A M D. Activated carbons obtained from sewage sludge by chemical activation:Gas-phase environmental applications[J]. Joural of Environment Management, 2014,140:145-151
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Citation:

基于响应曲面法优化生物质污泥活性炭的制备方法

1. 西南石油大学化学化工学院, 成都 610500
2. 富顺县水务局, 富顺 643200
3. 过程装备与控制工程四川省高校重点实验室, 自贡 643000
4. 西南石油大学机电工程学院, 成都 6105000

收稿日期: 2017-03-07

基金项目:

西南石油大学油气田污染治理青年科研创新团队项目（2013XJZT003）

过程装备与控制工程四川省高校重点实验室开放基金资助项目（GK201616）

关键词:

摘要: 针对传统技术制备污泥活性炭的比表面积不高、吸附值低等不足，通过在污泥中添加核桃壳以改善污泥原料缺陷，研究了活化剂种类、核桃壳加量、活化温度、活化时间、活化剂浓度及浸渍比等影响活性炭吸附能力的制备条件。在优化后的条件下制备出了高吸附性能的生物质污泥复合活性炭。结果表明：选择氯化锌作为活化剂，核桃壳加量20%、活化温度500℃、活化时间60 min、活化剂浓度2.5 mol·L-1、浸渍比1：2.5为最优化制备条件。制备出的生物质污泥复合活性炭碘吸附值为574.11 mg·g-1，产率为43.93%。

English Abstract

Preparation method of biological sludge activated carbon based on response surface methodology

1. College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China
2. Water Conservancy Bureau, Fushun 643200, China
3. Sichuan Provincial Key Lab of Process Equipment and Control, Sichuan University of Science and Engineering, Zigong 643000, China
4. School of mechatronic Engineering, Southwest Petroleum University, Chengdu 610500, China

Received Date: 2017-03-07

Fund Project:

Keywords:

Abstract: According to the deficiencies of traditional technology of sludge activated carbon preparation such as low specific surface area and low adsorption, the research focus on improving the defects of raw sludge material by adding walnut shell in sludge, studying the experiment condition such as the species of activator, the mass fraction of walnut shell, activation temperature, activation time, activator concentration and dipping ratio, etc. It can provide high adsorption performance biological sludge activated carbon under the optimum experimental conditions. The optimization condition is choosing Zinc chloride as activator, 20%walnut shell, activation temperature 500℃, activation time 60 min, activation concentration 2.5 mol·L-1, dipping ratio 1:2.5.The biological sludge activated carbon is prepared that the iodine index is 574.11 mg·g-1 and the yield is 43.93%.

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基于响应曲面法优化生物质污泥活性炭的制备方法

Preparation method of biological sludge activated carbon based on response surface methodology

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基于响应曲面法优化生物质污泥活性炭的制备方法

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Preparation method of biological sludge activated carbon based on response surface methodology

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