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Fenton-超声联合处理金刚烷胺制药废水

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樊杰, 曾萍, 张盼月, 宋永会, 李东一. Fenton-超声联合处理金刚烷胺制药废水[J]. 环境工程学报, 2014, 8(5): 1744-1748.
引用本文: 樊杰, 曾萍, 张盼月, 宋永会, 李东一. Fenton-超声联合处理金刚烷胺制药废水[J]. 环境工程学报, 2014, 8(5): 1744-1748.
shu
Fan Jie, Zeng Ping, Zhang Panyue, Song Yonghui, Li Dongyi. Treatment of wastewater from amantadine production by Fenton-ultrasound process[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1744-1748.
Citation: Fan Jie, Zeng Ping, Zhang Panyue, Song Yonghui, Li Dongyi. Treatment of wastewater from amantadine production by Fenton-ultrasound process[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1744-1748.
shu

Fenton-超声联合处理金刚烷胺制药废水

  • 1.

    北京林业大学环境科学与工程学院, 北京 100083

  • 2.

    中国环境科学研究院城市水环境科技创新基地, 北京 100012

  • 基金项目:

    科技部中国-以色列科学与战略研究开发专项资金合作研究项目

    国家“水体污染控制与治理”科技重大专项（2012ZX07202-002，2012ZX07202-005）

    中法国际科技合作项目石化和制药行业节水减排技术合作研究（2010DFB90590）

  • 中图分类号: X703

Treatment of wastewater from amantadine production by Fenton-ultrasound process

  • 1.

    College of Environmental Science and Engineering, Beijing Forestry University, Beijing 100083, China

  • 2.

    Deparment of Urban Water Environmental Research, Chinese Research Academy of Environmental Science, Beijing 100012, China

  • Fund Project:

  • 摘要: 近年来，流感常用药盐酸金刚烷胺的产量不断增大，然而，其生产过程中产生的废水由于得不到有效处理，引起较大污染。以盐酸金刚烷胺生产过程中产生的胺化废水和溴化废水为原水，利用Fenton-超声联合工艺进行处理，主要研究反应时间、初始pH、H2O2投加量和H2O2/Fe2+的投加比和声能密度等操作条件对于金刚烷胺制药废水处理效果的影响。实验结果表明，优化处理条件下，Fenton-超声联合工艺对金刚烷胺制药废水中TOC去除效果最高达到65.6%。超声和Fenton的联合产生了良好的协同效果，Fenton-超声联合工艺对金刚烷胺制药废水的处理效果比单独超声和单独Fenton处理效果之和高18%，大大提高了废水中有机物的去除效果。
    Abstract: As one kind of frequently-used flu medicines, amantadine has been increasingly produced these years, however, the wastewater from amantadine production can't be effectively treated, leading to serious pollution. This study aims at the treatment of wastewater from amantadine production with Fenton-ultrasound combined process. Effects of reaction time, initial pH, H2O2dosage, H2O2/Fe2+ molar ratio and ultrasound power density on the wastewater treatment effectiveness were investigated. Results showed that the TOC removal can reach 65.6% under the optimum reaction conditions. Ultrasound and Fenton treatment showed a good synergy effect that the TOC removal of the combined treatment was 18% higher than the sum of single ultrasound and single Fenton treatment, which greatly promoted the organic removal from the wastewater from amantadine production.
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    [7] 莫立焕, 周志明, 王玉峰.超声波强化Fenton试剂深度处理制浆中段废水.中国造纸, 2012, 31(1):23-27 Mo L. H., Zhou Z. M., Wang Y. F. Advanced treatment of pulping effluent by ultrasonic strengthened Fenton process. China Pulp. & Paper, 2012, 31(1): 23-27 (in Chinese)
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出版历程
  • 收稿日期:  2013-05-06
  • 刊出日期:  2014-05-06
樊杰, 曾萍, 张盼月, 宋永会, 李东一. Fenton-超声联合处理金刚烷胺制药废水[J]. 环境工程学报, 2014, 8(5): 1744-1748.
引用本文: 樊杰, 曾萍, 张盼月, 宋永会, 李东一. Fenton-超声联合处理金刚烷胺制药废水[J]. 环境工程学报, 2014, 8(5): 1744-1748.
shu
Fan Jie, Zeng Ping, Zhang Panyue, Song Yonghui, Li Dongyi. Treatment of wastewater from amantadine production by Fenton-ultrasound process[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1744-1748.
Citation: Fan Jie, Zeng Ping, Zhang Panyue, Song Yonghui, Li Dongyi. Treatment of wastewater from amantadine production by Fenton-ultrasound process[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1744-1748.
shu

Fenton-超声联合处理金刚烷胺制药废水

  • 1.  北京林业大学环境科学与工程学院, 北京 100083
  • 2.  中国环境科学研究院城市水环境科技创新基地, 北京 100012
  • 收稿日期:  2013-05-06
基金项目:

科技部中国-以色列科学与战略研究开发专项资金合作研究项目

国家“水体污染控制与治理”科技重大专项（2012ZX07202-002，2012ZX07202-005）

中法国际科技合作项目石化和制药行业节水减排技术合作研究（2010DFB90590）

摘要: 近年来，流感常用药盐酸金刚烷胺的产量不断增大，然而，其生产过程中产生的废水由于得不到有效处理，引起较大污染。以盐酸金刚烷胺生产过程中产生的胺化废水和溴化废水为原水，利用Fenton-超声联合工艺进行处理，主要研究反应时间、初始pH、H2O2投加量和H2O2/Fe2+的投加比和声能密度等操作条件对于金刚烷胺制药废水处理效果的影响。实验结果表明，优化处理条件下，Fenton-超声联合工艺对金刚烷胺制药废水中TOC去除效果最高达到65.6%。超声和Fenton的联合产生了良好的协同效果，Fenton-超声联合工艺对金刚烷胺制药废水的处理效果比单独超声和单独Fenton处理效果之和高18%，大大提高了废水中有机物的去除效果。

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