矿区炼金废渣的固化/稳定化处理

赵述华, 张太平, 陈志良, 潘伟斌. 矿区炼金废渣的固化/稳定化处理[J]. 环境工程学报, 2013, 7(12): 4951-4957.
引用本文: 赵述华, 张太平, 陈志良, 潘伟斌. 矿区炼金废渣的固化/稳定化处理[J]. 环境工程学报, 2013, 7(12): 4951-4957.
Zhao Shuhua, Zhang Taiping, Chen Zhiliang, Pan Weibin. Solidification/stabilization treatment of gold mining waste residue[J]. Chinese Journal of Environmental Engineering, 2013, 7(12): 4951-4957.
Citation: Zhao Shuhua, Zhang Taiping, Chen Zhiliang, Pan Weibin. Solidification/stabilization treatment of gold mining waste residue[J]. Chinese Journal of Environmental Engineering, 2013, 7(12): 4951-4957.

矿区炼金废渣的固化/稳定化处理

  • 基金项目:

    国家环保公益项目(201109024,201309003)

    国家高技术研究发展计划(863)项目(2009AA063102)

  • 中图分类号: X753;X53

Solidification/stabilization treatment of gold mining waste residue

  • Fund Project:
  • 摘要: 通过对金矿矿区炼金废渣的酸中和能力、净产酸量及浸出毒性实验,测定了废渣的产酸潜力及重金属砷、镉、铅、锌的总量和它们的浸出量。为了合理处置矿区炼金废渣,并为矿区重金属污染土壤的修复提供技术支持,采用石灰、粉煤灰、堆肥化污泥作为添加剂对废渣进行固化/稳定化处理;通过浸出毒性实验对固化/稳定化处理效果进行综合分析,试图寻求一种最佳的稳定剂。结果表明,无论是单独添加石灰、粉煤灰或者堆肥化污泥还是两两组合混合添加,样品浸出液的pH都有升高,As、Cd的浸出浓度都有明显下降,而且两两组合添加比单独添加的固化/稳定化处理效果更好。在两两组合添加中,粉煤灰混合堆肥化污泥的处理效果最好,浸出液的pH值达到7.82,As、Cd的浸出率分别下降72.0%和72.2%。说明粉煤灰混合堆肥化污泥处理炼金废渣效果最佳,同时具有以废治污的资源化生态效能。
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  • [1] 陈桥, 胡克, 王建国, 等. 矿山土地污染危害及污染源探讨. 国土资源科技管理, 2004, 21(4): 51-53 Chen Q., Hu K., Wang J. G., et al. A discussion on hazard of polluted land at mining areas and sources of pollution. Management Geological Science and Technology, 2004, 21(4): 51-53(in Chinese)
    [2] 王学刚, 王光辉, 刘金生. 矿区重金属污染土壤的修复技术研究现状. 工业安全与环保, 2010, 36(4): 29-31 Wang X. G., Wang G. H., Liu J. S. Study on mining Area's heavy metal soil pollution remediation technology. Industrial Safety and Environmental Protection, 2010, 36(4): 29-31(in Chinese)
    [3] 胡振琪, 凌海明. 金属矿山污染土地修复技术及实例研究. 金属矿山, 2003, (6):53-56 Hu Z. Q., Ling H. M. Investigation of remediation technology of contaminated land in metal mine. Metal Mine, 2003, (6):53-56(in Chinese)
    [4] Suman R. D. S., Aparna C., Rekha P., et al. Stabilization and solidification technologies for the remediation of contaminated soils and sediments: An overview. Land Contamination and Reclamation, 2005, 13(1): 23-48
    [5] Bone B. D., Barnard L. H., Hills C. D. Guidance on the Use of Stabilization/Solidification for the Treatment of Contaminated Soil. Bristol: UK Environment Agency, 2004.1-103
    [6] 周启星, 宋玉芳. 污染土壤修复原理与方法. 北京: 科学出版社, 2004
    [7] 李柏林, 李晔, 王海涛, 等. 含砷废渣的固化处理. 化工环保, 2008, 28(2): 153-157 Li B. L., Li Y., Wang H. T., et al. Solidification treatment of arsenic-containing waste residue. Environmental Protection of Chemical Industry, 2008, 28(2): 153-157(in Chinese)
    [8] 韩怀芬, 黄玉柱, 金漫彤. 铬渣的固化/稳定化研究. 环境污染与防治, 2002, 24(4): 199-200 Han H. F., Huang Y. Z., Jin M. T. Research of solidification chromium residue with cement binders.Environmental Pollution & Control, 2002, 24(4): 199-200(in Chinese)
    [9] 周剑波, 宁寻安, 刘敬勇, 等. 印染污泥固化及稳定化处理技术研究. 环境工程学报, 2011, 5(2): 457-461 Zhou J. B., Ning X. A., Liu J. Y., et al. Study on solidification/stabilization treatment of textile dyeing sludge. Chinese Journal of Environmental Engineering, 2011, 5(2): 457-461(in Chinese)
    [10] 赵萌, 郑发鸿, 王平艳. 含砷污泥的粉煤灰固化研究. 环境工程学报, 2007, 1(10): 112-115 Zhao M., Zheng F. M., Wang P. Y. A study on solidification of sludge with arsenic using fly ash. Chinese Journal of Environmental Engineering, 2007, 1(10): 112-115(in Chinese)
    [11] Dimitris D., Xiao G. M. Utilization of fly ash for stabilization/solidification of heavy metal contaminated soils. Engineering Geology, 2003, 70(3-4): 377-394
    [12] 鲁如坤. 土壤农业化学分析法. 北京: 农业科技出版社, 1999
    [13] Miller S. D., Jeffery J. J., Wong J. W. C. In-pit identification and management of acid forming waste rock at the Golden Cross Gold Mine, New Zealand. Proceedings of the Second International Conference on the Abatement of Acidic Drainage. Montreal, 1991.137-151
    [14] Porter S. K., Schecke K. G., Impellitter C. A., et al. Toxic metals in the environment: Thermodynamic considerations for possible immobilization strategies for Pb, Cd, As, and Hg. Critical Reviews in Environmental Science and Technology, 2004, 34(6): 495-604
    [15] William H., Edwards R., Lepp N. W. Arsenic and heavy metal mobility in iron oxide-amended contaminated soil as evaluated by short-and long-term leaching tests. Environmental Pollution, 2004, 131(3): 495-504
    [16] Mench M., Bussiere S., Boisson J., et al. Progress in remediation and revegetation of the barren Jales gold mine spoil after in situ treatment. Plant and Soil, 2003, 249(1): 187-202
    [17] 蒋成爱, 吴启堂, 陈杖榴. 土壤中砷污染研究进展. 土壤, 2004, 36(3): 264-270 Jiang C. A., Wu Q. T., Chen Z. L. Arsenic contaminate in the soil. Soils, 2004, 36(3): 264-270(in Chinese)
    [18] 廖敏, 黄昌勇, 谢正苗. pH对镉在土水系统中的迁移和形态的影响. 环境科学学报, 1999, 19(1): 81-86 Liao M., Huang C. Y., Xie Z. M. Effect of pH on transport and transformation of cadmium in soil-water system. Acta Scientiae Circumstantiae, 1999, 19(1): 81-86 (in Chinese)
    [19] 张晓熹, 罗泉达, 郑瑞生, 等. 石灰对重金属污染土壤上镉形态及芥菜镉吸收的影响.福建农业学报, 2003, 15(3): 151-154 Zhang X. X., Luo Q. D., Zheng R. S., et al. Effects of liming on soil Cd fractionation and Cd uptake by vegetable in heavy metal contaminated soil. Fujian Journal of Agriculture Sciences, 2003, 18(3): 151-154(in Chinese)
    [20] 郝双龙, 丁园, 余小芬, 等. 粉煤灰和石灰对突发性污染土壤中重金属化学形态的影响. 广东农业科学, 2012, (3):55-57 Hao S. L., Ding Y., Yu X. F., et al. Effect of lime and fly ash on chemical forms of heavy metal in sudden polluted soils. Guangdong Agricultural Sciences, 2012, (3):55-57(in Chinese)
    [21] Alamm G. M., Tokunaga S., Maekawa T. Extraction of arsenic in a synthetic arsenic-contaminated soil using phosphate. Chemosphere, 2011, 43(8):1035-1041
    [22] 魏显有, 王秀敏, 刘云惠, 等.土壤中砷的吸附行为及其形态分布研究. 河北农业大学学报, 1999, 22(3): 28-30 Wei X. Y., Wang X. M., Liu Y. H., et al. The study of the adsorptive behavior of arsenic in soil and its form distribution. Journal of Agricultural University of Hebei, 1999, 22(3): 28-30(in Chinese)
    [23] 陈世宝, 华珞, 白玲玉, 等. 有机质在土壤重金属污染治理中的应用. 农业环境与发展, 1997, 14(3): 27-29 Chen S. B., Hua L., Bai L. Y., et al. Application of organic matters in the improvement of soil polluted by heavy metals. Agro-Environment and Development, 1997, 14(3): 27-29(in Chinese)
    [24] 华珞, 白玲玉. 镉锌复合污染对小麦籽粒镉累积的影响和有机肥调控作用. 农业环境保护, 2002, 21(5): 393-398 Hua L., Bai L. Y. Combination of pollutants cadmium and zinc and its effects on Cd accumulationin wheat grain and adjustment by organic manure. Agro-Environmental Protection, 2002, 21(5): 393-398(in Chinese)
    [25] 郝汉舟, 陈同斌, 靳孟贵, 等. 重金属污染土壤稳定/固化修复技术研究进展. 应用生态学报, 2011, 22(3): 816-824 Hao H. Z., Chen T. B., Jin M. G., et al. Recent advance in solidification/stabilization technology for the remediation of heavy metals contaminated soil. Chinese Journal of Applied Ecology, 2011, 22(3): 816-824(in Chinese)
    [26] 陈同斌, 高定, 李新波. 城市污泥堆肥对栽培基质保水能力和有效养分的影响. 生态学报, 2002, 22(6): 802-807 Chen T. B., Gao D., Li X. B. Effects of sewage sludge compost on available nutrient s and water retention ability of planting substrate. Acta Ecologica Sinica, 2002, 22(6):802-807(in Chinese)
    [27] 莫测辉, 蔡全英, 王江海, 等. 城市污泥在矿山废弃地复垦的应用研究. 生态学杂志, 2011, 20(2): 44-47 Mo C. H., Cai Q. Y., Wang J. H., et al. Application of sewage sludge to the abandoned mining land reclamation. Chinese Journal of Ecology, 2011, 20(2): 44-47(in Chinese)
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出版历程
  • 收稿日期:  2012-12-19
  • 刊出日期:  2013-12-08
赵述华, 张太平, 陈志良, 潘伟斌. 矿区炼金废渣的固化/稳定化处理[J]. 环境工程学报, 2013, 7(12): 4951-4957.
引用本文: 赵述华, 张太平, 陈志良, 潘伟斌. 矿区炼金废渣的固化/稳定化处理[J]. 环境工程学报, 2013, 7(12): 4951-4957.
Zhao Shuhua, Zhang Taiping, Chen Zhiliang, Pan Weibin. Solidification/stabilization treatment of gold mining waste residue[J]. Chinese Journal of Environmental Engineering, 2013, 7(12): 4951-4957.
Citation: Zhao Shuhua, Zhang Taiping, Chen Zhiliang, Pan Weibin. Solidification/stabilization treatment of gold mining waste residue[J]. Chinese Journal of Environmental Engineering, 2013, 7(12): 4951-4957.

矿区炼金废渣的固化/稳定化处理

  • 1.  华南理工大学环境与能源学院, 广州 510006
  • 2.  环境保护部华南环境科学研究所, 广州 510655
基金项目:

国家环保公益项目(201109024,201309003)

国家高技术研究发展计划(863)项目(2009AA063102)

摘要: 通过对金矿矿区炼金废渣的酸中和能力、净产酸量及浸出毒性实验,测定了废渣的产酸潜力及重金属砷、镉、铅、锌的总量和它们的浸出量。为了合理处置矿区炼金废渣,并为矿区重金属污染土壤的修复提供技术支持,采用石灰、粉煤灰、堆肥化污泥作为添加剂对废渣进行固化/稳定化处理;通过浸出毒性实验对固化/稳定化处理效果进行综合分析,试图寻求一种最佳的稳定剂。结果表明,无论是单独添加石灰、粉煤灰或者堆肥化污泥还是两两组合混合添加,样品浸出液的pH都有升高,As、Cd的浸出浓度都有明显下降,而且两两组合添加比单独添加的固化/稳定化处理效果更好。在两两组合添加中,粉煤灰混合堆肥化污泥的处理效果最好,浸出液的pH值达到7.82,As、Cd的浸出率分别下降72.0%和72.2%。说明粉煤灰混合堆肥化污泥处理炼金废渣效果最佳,同时具有以废治污的资源化生态效能。

English Abstract

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