活性炭和沸石对氨氮的吸附特性及生物再生

田琳, 孔强, 任宗明, 付荣恕, 苗明升. 活性炭和沸石对氨氮的吸附特性及生物再生[J]. 环境工程学报, 2012, 6(10): 3424-3428.
引用本文: 田琳, 孔强, 任宗明, 付荣恕, 苗明升. 活性炭和沸石对氨氮的吸附特性及生物再生[J]. 环境工程学报, 2012, 6(10): 3424-3428.
Tian Lin, Kong Qiang, Ren Zongming, Fu Rongshu, Miao Mingsheng. Adsorption characteristics of activated carbon and zeolite and their biological regeneration[J]. Chinese Journal of Environmental Engineering, 2012, 6(10): 3424-3428.
Citation: Tian Lin, Kong Qiang, Ren Zongming, Fu Rongshu, Miao Mingsheng. Adsorption characteristics of activated carbon and zeolite and their biological regeneration[J]. Chinese Journal of Environmental Engineering, 2012, 6(10): 3424-3428.

活性炭和沸石对氨氮的吸附特性及生物再生

  • 基金项目:

    国家水体污染控制与治理科技重大专项(2008ZX07209-006,2009ZX07210-009)

  • 中图分类号: X703.1

Adsorption characteristics of activated carbon and zeolite and their biological regeneration

  • Fund Project:
  • 摘要: 采用活性炭和沸石作为吸附材料,分别考察了这两种吸附材料对水体中氨氮的吸附特性及其生物再生性能。实验结果表明,活性炭和沸石对水体中氨氮的等温吸附符合Freundlich等温式,其拟合度分别为0.9783和0.9303;静态吸附结果表明活性炭和沸石均具有较好的氨氮吸附性能,24 h内沸石对氨氮的吸附能力为1.27 mg/g,高于活性炭的0.53 mg/g;动态吸附中沸石达到吸附饱和的时间为96 h,较活性炭达到吸附饱和的时间长,沸石显示出作为氨氮吸附剂的优越性;活性炭和沸石经过96 h的生物再生后吸附性能获得一定程度的再生,出水中氨氮浓度比未进行生物再生前分别降低17.31 mg/L和8.32 mg/L,且都在表面形成了稳定的生物膜。
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  • [1] 刘娜娜,伍钧,郑丹,等.人工湿地基质的筛选及其对猪场废水厌氧消化液中氨氮吸附性能研究.环境工程学报,2011,5(4):783-788 Liu N.,Wu J.,Zheng D.,et al.Study on constructed wetlands packings selection and its adsorption properties for ammonia nitrogen in digested piggery wastewater.Chinese Journal of Environmental Engineering,2011,5(4):783-788(in Chinese)
    [2] Gabriela Vaccaa H.W.,Marcell Nikolausz.,et al.Effect of plants and filter materials on bacteria removal in pilot-scale constracted wetlands.Water Research,2005,39(7):1361-1371
    [3] 张建,陈素红,张成禄,等.水枝锦活性炭对孔雀石绿的吸附性能研究.环境污染与防治,2009,31(3):1-5,20 Zhang J.,Chen S.H.,Zhang C.L.,et al.The preparation and adsorptive removal of malachite green from aqueous solution onto activated carbon prepared from lythrum salicaria pedicel.Environmental Pollution and Control,2009,31(3):1-5,20(in Chinese)
    [4] 成官文,吴志超,章非娟,等.沸石在水污染控制中的研究与应用进展.环境科学与技术,2006,29(3):111-114 Cheng G..W.,Wu Z.C.,Zhang F.J.,et al.Progress in application of zeolite to wastewater treatment.Environmental Science & Technology,2006,29(3):111-114(in Chinese)
    [5] 张婷,李望良,唐煌,等.生物再生-吸附剂再生新方法.化工学报,2009,60(9):2145-2152 Zhang T.,Li W.L.,Tang H.,et al.Bioregeneration:A novel regeneration method for adsorbents.Journal of Chemical Industry and Engineering,2009,60(9):2145-2152(in Chinese)
    [6] Michal Green,A.M.,Ori Lahav.Biological-ion exchange process for ammonium removal from secondary effluent.Wat.Sci.Technol.,1996,34(1-2):449-458
    [7] Ori Lahav M.G.Ammonium removal using ion exchange and biological regeneration.Water Research,1998,32(7):2019-2028
    [8] Tsuno Hiroshi N.F.,Somiya Isao.Removal of ammonium nitrogen in bio-zeolite reactor.Doboku Gakkai Ronbunshu,1994,503(29):159-166
    [9] 孔强.富营养化水体生态修复中高效微生物的研究.济南:山东师范大学硕士学位论文,2010 Kong Q..Study on efficient microorganisms in eutrophic water ecological restoration.Jinan:Master's Dagree Thesis of Shandong Normal University,2010(in Chinese)
    [10] 国家环境保护总局,水和废水监测分析方法(第4版).北京:中国环境科学出版社,2002
    [11] 肖文胜,徐文国,杨桔才.曝气生物滤池中生物膜的活性研究.北京理工大学学报,2003,23(5):654-657,664 Xiao W.S.,Xu W.G.,Yang J.C.Activity of biomembranes and biofloccules in biological aerated filters.Journal of Beijing Institute of Technology,2003,23(5):654-657,664(in Chinese)
    [12] M Roi,.Cerjan-Stefanovi.,S.Kurajica.,et al.Ammoniacal nitrogen removal from water by treatment with clays and zeolites.Water Research,2000,34(14):3675-3681
    [13] 王龙,高旭,郭劲松,等.Mg/Al水滑石对水中痕量邻苯二甲酸酯的吸附动力学和热力学.环境工程学报,2011,5(11):2537-2541 Wang L.,Gao X.,Guo J.S.,et al.Adsorption kinetics and thermodynamics of trace phthalate esters on Mg/Al hydrotalcite.Chinese Journal of Environmental Engineering,2011,5(11):2537-2541(in Chinese)
    [14] Keane M.A.The removal of copper and nickel from aqueous solution using Y zeolite ion exchangers.Colloids and Surface,1998,138(1):11-20
    [15] Chung Y.C.,Son D.H.,Anh D.H.Nitrogen and organics removal from industrial wastewater using natural zeolite media.Water Science and Technology,2000,42(5-6):127-134
    [16] Ozgur A.F.C.Bioregeneration of activated carbon:A review.International Biodeterioration and Biodegradation,2007,59(4):257-272
    [17] 张曦,吴为中,温东辉,等.氨氮在天然沸石上的吸附及解吸.环境化学,2003,22(2):166-171 Zhang X.,Wu W.Z.,Wen D.H.,et al.Adsorption and desorption of ammonia-nitrogen onto natural zeolite.Environmental Chemistry,2003,22(2):166-171(in Chinese)
    [18] 陶婷婷,张玉先,汪胜.沸石滤料生物滤池用于生活污水脱氮处理研究.给水排水,2005,31(10):36-39 Tao T.T.,Zhang Y.X.,Wang S.Application of zeolite biological filter for domestic wastewater treatment.Water & Wastewater Engineering,2005,31(10):36-39(in Chinese)
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出版历程
  • 收稿日期:  2012-04-12
  • 刊出日期:  2012-10-16
田琳, 孔强, 任宗明, 付荣恕, 苗明升. 活性炭和沸石对氨氮的吸附特性及生物再生[J]. 环境工程学报, 2012, 6(10): 3424-3428.
引用本文: 田琳, 孔强, 任宗明, 付荣恕, 苗明升. 活性炭和沸石对氨氮的吸附特性及生物再生[J]. 环境工程学报, 2012, 6(10): 3424-3428.
Tian Lin, Kong Qiang, Ren Zongming, Fu Rongshu, Miao Mingsheng. Adsorption characteristics of activated carbon and zeolite and their biological regeneration[J]. Chinese Journal of Environmental Engineering, 2012, 6(10): 3424-3428.
Citation: Tian Lin, Kong Qiang, Ren Zongming, Fu Rongshu, Miao Mingsheng. Adsorption characteristics of activated carbon and zeolite and their biological regeneration[J]. Chinese Journal of Environmental Engineering, 2012, 6(10): 3424-3428.

活性炭和沸石对氨氮的吸附特性及生物再生

  • 1. 山东师范大学生命科学学院, 济南 250014
  • 2. 中国科学院烟台海岸带研究所, 烟台 264000
基金项目:

国家水体污染控制与治理科技重大专项(2008ZX07209-006,2009ZX07210-009)

摘要: 采用活性炭和沸石作为吸附材料,分别考察了这两种吸附材料对水体中氨氮的吸附特性及其生物再生性能。实验结果表明,活性炭和沸石对水体中氨氮的等温吸附符合Freundlich等温式,其拟合度分别为0.9783和0.9303;静态吸附结果表明活性炭和沸石均具有较好的氨氮吸附性能,24 h内沸石对氨氮的吸附能力为1.27 mg/g,高于活性炭的0.53 mg/g;动态吸附中沸石达到吸附饱和的时间为96 h,较活性炭达到吸附饱和的时间长,沸石显示出作为氨氮吸附剂的优越性;活性炭和沸石经过96 h的生物再生后吸附性能获得一定程度的再生,出水中氨氮浓度比未进行生物再生前分别降低17.31 mg/L和8.32 mg/L,且都在表面形成了稳定的生物膜。

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