猪场废水的厌氧消化除磷机制
Mechanisms of phosphorus removal from piggery wastewater under anaerobic condition
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摘要: 采用批式厌氧消化实验,研究了猪场废水厌氧消化过程中生物、物理和化学作用对磷去除的贡献。结果表明,厌氧消化6 d,灭菌的混合液几乎没有磷被去除;未灭菌的混合液,上清液总磷去除率为57.3%,且随着混合液总磷的减少,吸收液的磷逐渐增多,说明废水中的部分磷被转化成气态磷化合物并释放。将原水在4℃、厌氧条件下静置6 d,废水TP去除率为70.7%,说明物理沉降的除磷作用显著。对厌氧消化前后的污泥进行浸提,发现没有灭菌、灭菌混合液的污泥的Ca、Mg-RP(HCl-RP)含量分别增加93.4%和50.5%。由于没有灭菌的混合液的pH不断升高,灭菌的混合液的pH不断下降,说明生物的新陈代谢活动使得环境条件改变(pH增加)而有利于磷化合物沉淀的形成。实验表明,猪场废水厌氧消化过程中磷的去除是物理、化学及生物过程共同作用的结果。Abstract: Batch experiments were carried out to research the contribution of biological, physical and chemical process to phosphrus removal from piggery wastewater under anaerobic condition. The results indicated that through 6 days’ anaerobic digestion, phosphrus was hardly removed from the mixed liquor which was sterilized, and the total phosphorus removal rate of supernatant of the mixed liquor without sterilization was 57.3%. Along with the decreasing total phosphorus content in mixed liquor, phosphrus in absorption solution increased, which revealed that a part of phosphate in the wastewater was released out by changing into gaseous phosphate. While the bottles contained original wastewater were sealed anaerobically and layed up for 6 days at 4℃, the total phosphorus removal rate of supernatant of the mixed liquor was 70.7%. It indicated that phosphrus removed by physical sedimentation was obvious. Detected matrix-bound phosphine in the sludge before and after anaerobic process, it was found that the content of Ca,Mg-RP(HCl-RP)in the sludge without and with sterilization increased by 93.4% and 50.5% respectively. The pH value of mixed liquor without sterilization increased, and of mixed liquor with sterilization decreased. It showed that the environment change (pH value increase) resulted from the metabolization of microbe facilitated chemical precipitation of phosphorus compound. Which means that biology has the accessorial function of inducing chemic depositing. The experiments indicated that phosphrus removal from piggery wastewater during anaerobic digestion was the coaction of physical, chemic and biological process.
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