氧化铁红生产中氨的回收及循环利用
Recovery and recycling of ammonia in iron oxide red preparing processes
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摘要: 利用吹脱工艺处理水热法制备氧化铁红产生的高浓度氨氮废水。经试验所得最佳的吹脱工艺参数为pH=12、CaO浓度30%、吹脱温度100℃和负压吹脱30 min。在此条件下,氨的回收利用率可达97.40%。用硫酸铁溶液吸收吹脱后氨水,使得氨得到了循环利用。水热实验证明回收的氨水并不影响氧化铁红产品的质量。Abstract: Blow-off method was employed to study the treatment of high concentration ammonianitrogen wastewater from iron oxide red prepared by hydrothermal method. The optimal process parameters achieved in the experiment included a pH value of 12, CaO concentration of 30%, blow-off temperature of 100℃ and blowoff time with negative pressure of 3 h. Under these conditions, an ammonianitrogen recovery rate of 97.40% could be obtained. Ammonia of blowoff reacted with ferric sulfate solution and was recycled completely. It is verified in a lab experiment that the reused ammonia doesn’t lower the quality of the iron oxide red prepared by hydrothermal method.
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Key words:
- blow-off method /
- ammonianitrogen /
- recovery and recycling
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