混凝工艺去除合流污水中有机物及营养元素
Organics and nutrients removal in combined wastewater by coagulation and flocculation process
-
摘要: 通过系列杯罐试验混凝处理合流污水,采用硫酸铝(Al2(SO4)3)、硫酸铁(Fe2(SO4)3)、聚合氯化铝(PAC)和聚合氯化铝铁(PAFC)4种混凝剂均能有效去除污水中的 TP、PO3-4-P、SS和COD。聚合金属盐(PAC和PAFC)混凝处理效果优于金属盐(Al2(SO4)3和Fe2(SO4)3),达到相同的处理效果的投加量明显低于后者。助凝剂采用聚丙烯酰胺(PAM)、聚乙烯醇(PVA)、自制的高分子聚合物(AN)和活化硅酸(AS),在保持较低混凝剂投加量的条件下可明显提高污水处理效果;添加助凝剂对强化PO3-4-P的去除作用不明显,PO3-4-P的去除仅与混凝剂的投加量相关。混凝剂和助凝剂对污水中NH3-N的去除作用相对不显著。SS去除率随混凝剂投加量的变化趋势说明混凝的机理较为复杂,可能存在多种混凝机理共同作用。Abstract: The removal efficiency of inorganics, organics and nutrients of a combined sewage were studied by the coagulationflocculation process in jar tests. Suspended solid (SS), chemical oxygen demand (COD), total phosphorus (TP) and orthophosphate (PO3-4-P) in the combined wastewater could be effectively removed using flocculants, such as aluminum sulfate (Al2(SO4)3), ferric sulfate (Fe2(SO4)3), polyaluminium chloride (PAC) and polyaluminiumferric chloride (PAFC). Polymetal salt flocculants (PAC and PAFC) had more effective removal efficiency of pollutants than metal salt ones (Al2(SO4)3 and Fe2(SO4)3), which means that the former dosage is less than the later with the same removal efficiency of pollutants. Flocculant aids, such as cationic polyacrylamide (PAM), polyvinyl alcohol (PVA), a new polyelectrolyte made in laboratory (AN) and activated silica (AS), dramatically enhanced the coagulationflocculation process at relatively low coagulant dosage. The removal of PO3-4-P only depended on the coagulant dosage; and the flocculant aids had marginal effect on the process. The flocculants and flocculant aids didn’t significantly improve NH3-N removal efficiency. The trend of SS removal efficiencies indicated that the flocculation mechanism is considerably complex and could present synergic flocculation mechanisms in the process.
-
Key words:
- combined sewage /
- coagulation /
- flocculation /
- flocculant /
- flocculant aids /
- organics /
- nutrients
-
-

计量
- 文章访问数: 1404
- HTML全文浏览数: 778
- PDF下载数: 809
- 施引文献: 0