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光催化膜反应器应用于废水处理的研究进展

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张青青, 曾婷, 张磊, 王春英. 光催化膜反应器应用于废水处理的研究进展[J]. 环境化学, 2020, (5): 1297-1306. doi: 10.7524/j.issn.0254-6108.2019081305
引用本文: 张青青, 曾婷, 张磊, 王春英. 光催化膜反应器应用于废水处理的研究进展[J]. 环境化学, 2020, (5): 1297-1306. doi: 10.7524/j.issn.0254-6108.2019081305
shu
ZHANG Qingqing, ZENG Ting, ZHANG Lei, WANG Chunying. Review of photocatalytic membrane reactors in water treatment[J]. Environmental Chemistry, 2020, (5): 1297-1306. doi: 10.7524/j.issn.0254-6108.2019081305
Citation: ZHANG Qingqing, ZENG Ting, ZHANG Lei, WANG Chunying. Review of photocatalytic membrane reactors in water treatment[J]. Environmental Chemistry, 2020, (5): 1297-1306. doi: 10.7524/j.issn.0254-6108.2019081305
shu

光催化膜反应器应用于废水处理的研究进展

  • 1. 江西理工大学资源与环境工程学院, 赣州, 341000;

  • 2. 江西省矿冶环境污染控制重点实验室, 赣州, 341000

    • 通讯作者: 王春英, E-mail: beyond_life@163.com
  • 基金项目:

    国家自然科学基金（51408277）和江西理工大学"清江青年英才支持计划"（JXUSTQJYX2016003）资助.

Review of photocatalytic membrane reactors in water treatment

  • 1. School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou, 341000, China;

  • 2. Jiangxi Key Laboratory of Mining & Metallurgy Environmental Pollution Control, Ganzhou, 341000, China

    • Corresponding author: WANG Chunying, beyond_life@163.com
  • Fund Project: Supported by the National Natural Science Foundation of China (51408277)and Qingjiang Excellent Young Talents Jiangxi University of Science and Technology(JXUSTQJYX2016003).

  • 摘要: 多相光催化技术是目前最具有发展前景的水处理技术之一，其原理是光催化剂在光辐照下产生羟基自由基、超氧自由基等具有强氧化性的活性物种，从而降解各种有机污染物、灭活病原微生物、处理药剂废水等.但是该技术存在催化剂回收难、后续处理困难等问题.通过光催化技术与膜技术耦合而发展起的光催化膜反应器（photocatalytic membrane reactors，PMRs）将有效解决上述问题：相对于单独光催化处理，PMRs具有工艺简化、催化剂易于回收等优点；相对于单独膜处理，其又具有矿化完全、不易产生膜污染等优点.光催化剂种类（TiO2、g-C3N4、CeO2、MOFs材料、铋系光催化剂等），膜基材（有机膜、无机膜、陶瓷膜、聚合膜等），以及结合光催化剂与膜基的复合膜均对光催化膜反应器的性能有重要影响.目前，根据不同的水质及处理要求，国内外的光催化膜反应器类型主要分悬浮型和固定型，文章对不同种类光催化膜反应器构造、处理对象及其优缺点进行了详细论述；深入讨论了PMRs在实际应用中尚存在的技术、经济成本等限制问题.
    Abstract: Heterogeneous photocatalysis technology is one of the most promising water treatment technologies. The principle is that the photocatalysts are excited by photons and generate various reactive oxygen species (ROSs) including hydroxyl radicals and superoxide radicals. These generated ROSs with strong oxidizing properties could degrade organic pollutants, inactivate various pathogenic microorganisms, and treat pharmaceutical wastewater. However, photocatalysis has difficulty in recycling photocatalyst and subsequent treatment. Photocatalytic membrane reactors (PMRs) developed by coupling photocatalysis with membrane process could solve these problems. Compared with single photocatalysis, PMRs have the advantages of simplified process and easy recovery of catalyst. Compared with single membrane process, PMRs have the advantages of complete mineralization and less membrane fouling. These three parameters have important influences on the performance of the PMRs, which are types of photocatalyst (TiO2, g-C3N4, CeO2, MOFs material and Bi-based photocatalysts, etc.), membrane substrate (organic membrane, inorganic membrane, ceramic membrane, polymer membrane, etc.) and composite membranes composed of photocatalyst materials and membrane substrate. According to different water quality and processing requirements, the configurations of PMRs can be divided into two types due to the immobilized photocatalyst and suspended photocatalyst. The reactor structures, treatment objects, advantages and disadvantages of different kinds of photocatalytic membrane reactors were discussed in detail. There still exist limitations of technical and economic costs in practical applications for PMRs.
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  • [1] BRASLAVSKY S E, BRAUN A M, CASSANO A E, et al. Glossary of terms used in photocatalysis and radiation catalysis (IUPAC Recommendations 2011)[J]. Pure and Applied Chemistry,2011,83(5):931-1014.
    [2] HOFFMANN M R, MARTIN S T, CHOI W. Environmental applications of semiconductor photocatalysis[J]. Chemical Reviews,1995,95:69-96.
    [3] LINSEBIGLER A L, LU G, YATES J T. Photocatalysis on TiO2 surfaces principles, mechanisms, and selected results[J]. Chemical Reviews,1995,95:735-758.
    [4] ZHENG X, SHEN Z P, SHI L, et al. Photocatalytic membrane reactors (PMRs) in water treatment:Configurations and influencing factors[J]. Catalysts,2017,7(8):224.
    [5] MOLINARI R, LAVORATO C, ARGURIO P. Recent progress of photocatalytic membrane reactors in water treatment and in synthesis of organic compounds. A review[J]. Catalysis Today,2017,281:144-164.
    [6] ZHANG W, DING L, LUO J, et al. Membrane fouling in photocatalytic membrane reactors (PMRs) for water and wastewater treatment:A critical review[J]. Chemical Engineering Journal,2016,302:446-458.
    [7] JANSSENS R, MANDAL M K, DUBEY K K, et al. Slurry photocatalytic membrane reactor technology for removal of pharmaceutical compounds from wastewater:Towards cytostatic drug elimination[J]. Science of the Total Environment,2017,599-600:612-626.
    [8] MENG F, LIU Y, WANG J, et al. Temperature dependent photocatalysis of g-C3N4, TiO2 and ZnO:Differences in photoactive mechanism[J]. Journal of Colloid Interface Science,2018,532:321-330.
    [9] GAYA U I, ABDULLAH A H. Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide:A review of fundamentals, progress and problems[J]. Journal of Photochemistry and Photobiology C:Photochemistry Reviews,2008,9(1):1-12.
    [10] HERRMANN J M. Heterogeneous photocatalysis fundamentals and applications to the removal of various types of aqueous pollutants[J]. Catalysis Today,1999,53:115-129.
    [11] BYRNE C, SUBRAMANIAN G, PILLAI S C. Recent advances in photocatalysis for environmental applications[J]. Journal of Environmental Chemical Engineering,2018,6(3):3531-3555.
    [12] EI-SHAFAI N M, EI-KHOULY M E, EI-KEMARY M, et al. Fabrication and characterization of graphene oxide-titanium dioxide nanocomposite for degradation of some toxic insecticides[J]. Journal of Industrial and Engineering Chemistry,2019,69:315-323.
    [13] HAIDER A J, JAMEEL Z N, AI-HUSSAININ I H M. Review on:Titanium dioxide applications[J]. Energy Procedia,2019,157:17-29.
    [14] DETTE C, PEREZ-OSORIO M A, KLEY C S, et al. TiO2 anatase with a bandgap in the visible region[J]. Nano Letters,2014,14(11):6533-6538.
    [15] CHEN X, BURDA C. The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials[J]. Journal of the American Chemical Society,2008,130:5018-5019.
    [16] LI J. Preparation of highly photocatalytic active nano-size TiO2-Cu2O particle composites with a novel electrochemical method[J]. Electrochemistry Communications,2004,6(9):940-943.
    [17] LI F, LI H, GUAN L X, et al. Nanocrystalline Co2+/F- codoped TiO2-SiO2 composite films for environmental applications[J]. Chemical Engineering Journal,2014,252:1-10.
    [18] RONG'AN HE, SHAOWEN CAO, PENG ZHOU, et al. Recent advances in visible light Bi-based photocatalysts[J]. Chinese Journal of Catalysis,2014,35:989-1007.
    [19] MOREIRA N F F, SAMPAIO M J, RIBEIRO A R, et al. Metal-free g-C3N4 photocatalysis of organic micropollutants in urban wastewater under visible light[J]. Applied Catalysis B:Environmental,2019,248:184-192.
    [20] XING S, LI T, GAO Y, et al. Insight into the mechanism for photocatalytic degradation of ciprofloxacin with CeO2[J]. Optik,2019,183:266-272.
    [21] PI Y, LI X, XIA Q, et al. Adsorptive and photocatalytic removal of persistent organic pollutants (POPs) in water by metal-organic frameworks (MOFs)[J]. Chemical Engineering Journal,2018,337:351-371.
    [22] 濮倩敏, 李泽胜, 李德豪. 钨酸铋纳米片光催化剂的制备以及四环素类抗生素降解性能研究[J]. 合成材料老化与应用,2018,47(4):72-75.

    PU Q M, LI Z S, LI D H. Preparation of bismuth tungstate nanoscale photocatalyst and the study on degradation performance of tetracycline antibiotics[J]. Synthetic Materials Aging and Application, 2018,47(4):72-75(in Chinese).

    [23] 张中杰, 关卫省, 孙绍芳, 等. Pt/BiVO4光催化剂的制备及其光催化降解性能[J]. 环境化学,2014,33(6):1003-1009.

    ZHANG Z J, GUAN W S, SUN S F, et al. Preparation of and its photocatalytic activity for the degradation of tetracycline[J]. Environmental Chemistry,2014, 33(6):1003-1009(in Chinese).

    [24] 张聪, 米屹东, 马东, 等. CeO2/g-C3N4光催化剂的制备及性能[J]. 环境化学,2017,36(1):147-152.

    ZHANG C, MI Y D, MA D, et al. Preparation and photocatalytic performance of CeO2/g-C3N4 photocatalysts[J]. Environmental Chemistry,2017, 36(1):147-152(in Chinese).

    [25] SHI L, WANG T, ZHANG H, et al. An amine-functionalized iron(Ⅲ) metal-organic framework as efficient visible-light photocatalyst for Cr(Ⅵ) reduction[J]. Advanced Science,2015,2(3):1500006.
    [26] 黄涛, 蒋华兵, 张国亮, 等. 悬浮态光催化超滤膜反应器处理4BS染料废水[J]. 水处理技术,2009,35(2):72-75.

    HUANG T, JIANG H B, ZHANG G L, et al. Degradation of 4BS in dying wastewater by photocatalyst suspended ultrafiltration membrane reactor[J]. Technology of Water Treatment,2009,35(2):72-75(in Chinese).

    [27] JIANG H, ZHANG G, HUANG T, et al. Photocatalytic membrane reactor for degradation of acid red B wastewater[J]. Chemical Engineering Journal,2010,156(3):571-577.
    [28] MOZIA S, TOYODA M, INAGAKI M, et al. Application of carbon-coated TiO2 for decomposition of methylene blue in a photocatalytic membrane reactor[J]. Journal of Hazardous Materials,2007,140(1-2):369-375.
    [29] MOLINARI R, PALMISANO L, DRIOLI E, et al. Studies on various reactor configurations for coupling photocatalysis and membrane processes in water purification[J]. Journal of Membrane Science,2002,206:399-415.
    [30] SUNG HO KIM, SEUNG-YEOP KWAK, BYEONG-HYEOK SOHN, et al. Design of TiO2 nanoparticle self-assembled aromatic polyamide thin-film-composite (TFC) membrane as an approach to solve biofouling problem[J]. Journal of Membrane Science,2003,211:157-165.
    [31] HE Z, LYU Z, GU Q, et al. Ceramic-based membranes for water and wastewater treatment[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2019,578:123513.
    [32] CARO J, NOACK M, KOLSCH P, et al. Zeolite membranes-state of their development and perspective[J]. Microporous and Mesoporous Materials,2000,38(1):3-24.
    [33] ZHAO H, LI H, YU H, et al. CNTs-TiO2/Al2O3 composite membrane with a photocatalytic function:Fabrication and energetic performance in water treatment[J]. Separation and Purification Technology,2013,116:360-365.
    [34] LIU X, CONG R, CAO L, et al. The structure, morphology and photocatalytic activity of graphene-TiO2 multilayer films and charge transfer at the interface[J]. New Journal of Chemistry,2014,38(6):2362-2367.
    [35] GRZECHULSKA J, MORAWSKI A W. Photocatalytic labyrinth flow reactor with immobilized P25 TiO2 bed for removal of phenol from water[J]. Applied Catalysis B:Environmental,2003,46(2):415-419.
    [36] BALASUBRAMANIAN G, DIONYSIOU D, SUIDAN M, et al. Evaluating the activities of immobilized TiO2 powder films for the photocatalytic degradation of organic contaminants in water[J]. Applied Catalysis B:Environmental,2004,47(2):73-84.
    [37] SONG YANG, GU J S,YU H Y, et al. Polypropylene membrane surface modification by RAFT grafting polymerization and TiO2 photocatalysts immobilization for phenol decomposition in a photocatalytic membrane reactor[J]. Separation and Purification Technology,2011,83:157-165.
    [38] YU S, WANG Y, SUN F, et al. Novel mpg-C3N4/TiO2 nanocomposite photocatalytic membrane reactor for sulfamethoxazole photodegradation[J]. Chemical Engineering Journal,2018,337:183-192.
    [39] HUANG C, DING Y, CHEN Y, et al. Highly efficient Zr doped-TiO2/glass fiber photocatalyst and its performance in formaldehyde removal under visible light[J]. Journal of Environmental Sciences,2017,60:61-69.
    [40] SIRIRERKRATANA K, KEMACHEEVAKUL P, CHUANGCHOTE S. Color removal from wastewater by photocatalytic process using titanium dioxide-coated glass, ceramic tile, and stainless steel sheets[J]. Journal of Cleaner Production,2019,215:123-130.
    [41] DE OLIVEIRA PEREIRA L, MARQUES SALES I, PEREIRA ZAMPIERE L, et al. Preparation of magnetic photocatalysts from TiO2, activated carbon and iron nitrate for environmental remediation[J]. Journal of Photochemistry and Photobiology A:Chemistry,2019,382:111907.
    [42] LAVORATO C, ARGURIO P, MASTROPIETRO T F, et al. Pd/TiO2 doped faujasite photocatalysts for acetophenone transfer hydrogenation in a photocatalytic membrane reactor[J]. Journal of Catalysis,2017,353:152-161.
    [43] LIU L, LIU Z, BAI H, et al. Concurrent filtration and solar photocatalytic disinfection/degradation using high-performance Ag/TiO2 nanofiber membrane[J]. Water Research,2012,46(4):1101-1112.
    [44] LIAO J, LIN S, PAN N, et al. Fabrication and photocatalytic properties of free-standing TiO2 nanotube membranes with through-hole morphology[J]. Materials Characterization,2012,66:24-29.
    [45] LEONG S, RAZMJOU A, WANG K, et al. TiO2 based photocatalytic membranes:A review[J]. Journal of Membrane Science,2014,472:167-184.
    [46] XIAO Y, XU S, LI Z, et al. Progress of applied research on TiO2 photocatalysis-membrane separation coupling technology in water and wastewater treatments[J]. Chinese Science Bulletin,2010,55(14):1345-1353.
    [47] LEE S A, CHOO K H, LEE C H. Use of ultrafiltration membranes for the separation of TiO2 photocatalysts in drinking water treatment[J]. Industrial & Engineering Chemistry Research,2001,40:1712-1719.
    [48] OLLIS D F. Integrating photocatalysis and membrane technologies for water treatment[J]. Annals of the New York Academy of Sciences,2003,984:65-84.
    [49] DESA A L, HAIROM N H H, SIDIK D A B, et al. A comparative study of ZnO-PVP and ZnO-PEG nanoparticles activity in membrane photocatalytic reactor (MPR) for industrial dye wastewater treatment under different membranes[J]. Journal of Environmental Chemical Engineering,2019,7(3):103143.
    [50] FU J, JI M, WANG Z, et al. A new submerged membrane photocatalysis reactor (SMPR) for fulvic acid removal using a nano-structured photocatalyst[J]. Journal of Hazardous Materials,2006,131(1-3):238-242.
    [51] ERDIM E, SOYER E, TASIYICI S, et al. Hybrid photocatalysis/submerged microfi ltration membrane system for drinking water treatment[J]. Desalination and Water Treatment,2012,9(1-3):165-174.
    [52] BRUNETTI A, POMILLA F R, MARC G, et al. CO2 reduction by C3N4-TiO2 Nafion photocatalytic membrane reactor as a promising environmental pathway to solar fuels[J]. Applied Catalysis B:Environmental,2019,255:117779.
    [53] ESP NDOLA J C, CRIST V O R O, MENDES A, et al. Photocatalytic membrane reactor performance towards oxytetracycline removal from synthetic and real matrices:Suspended vs immobilized TiO2-P25[J]. Chemical Engineering Journal,2019,378:122114.
    [54] GAO B, CHEN W, LIU J, et al. Continuous removal of tetracycline in a photocatalytic membrane reactor (PMR) with ZnIn2S4 as adsorption and photocatalytic coating layer on PVDF membrane[J]. Journal of Photochemistry and Photobiology A:Chemistry,2018,364:732-739.
    [55] HU C, WANG M S, CHEN C H, et al. Phosphorus-doped g-C3N4 integrated photocatalytic membrane reactor for wastewater treatment[J]. Journal of Membrane Science,2019,580:1-11.
    [56] MOZIA S, DAROWNA D, SZYMAN' SKI K, et al. Performance of two photocatalytic membrane reactors for treatment of primary and secondary effluents[J]. Catalysis Today,2014,236:135-145.
    [57] PLAKAS K V, SARASIDIS V C, PATSIOS S I, et al. Novel pilot scale continuous photocatalytic membrane reactor for removal of organic micropollutants from water[J]. Chemical Engineering Journal,2016,304:335-343.
    [58] SZYMAN'SKI K, MORAWSKI A W, MOZIA S. Humic acids removal in a photocatalytic membrane reactor with a ceramic UF membrane[J]. Chemical Engineering Journal,2016,305:19-27.
    [59] LI Q, JIA R, SHAO J, et al. Photocatalytic degradation of amoxicillin via TiO2 nanoparticle coupling with a novel submerged porous ceramic membrane reactor[J]. Journal of Cleaner Production,2019,209:755-761.
    [60] DEVECI E V, DIZGE N, YATMAZ H C, et al. Integrated process of fungal membrane bioreactor and photocatalytic membrane reactor for the treatment of industrial textile wastewater[J]. Biochemical Engineering Journal,2016,105:420-427.
    [61] HO D P, VIGNESWARAN S, NGO H H. Photocatalysis-membrane hybrid system for organic removal from biologically treated sewage effluent[J]. Separation and Purification Technology,2009,68(2):145-152.
    [62] 解立平, 王能亮, 黄伟. 一体式光催化氧化-膜分离流化床反应器性能的研究[J]. 环境工程学报,2007,1(9):20-24.

    XIE L P, WANG N L, HUANG W. Study on the performance of integrative reactor coupling with photocatalysis oxidation and organic membrane separation[J]. Chinese Journal of Environmental Engineering,2007,1(9):20-24(in Chinese).

    [63] RAHIMPOUR A, MADAENI S S, TAHERI A H, et al. Coupling TiO2 nanoparticles with UV irradiation for modification of polyethersulfone ultrafiltration membranes[J]. Journal of Membrane Science,2008,313(1-2):158-169.
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  • 收稿日期:  2019-08-13
张青青, 曾婷, 张磊, 王春英. 光催化膜反应器应用于废水处理的研究进展[J]. 环境化学, 2020, (5): 1297-1306. doi: 10.7524/j.issn.0254-6108.2019081305
引用本文: 张青青, 曾婷, 张磊, 王春英. 光催化膜反应器应用于废水处理的研究进展[J]. 环境化学, 2020, (5): 1297-1306. doi: 10.7524/j.issn.0254-6108.2019081305
shu
ZHANG Qingqing, ZENG Ting, ZHANG Lei, WANG Chunying. Review of photocatalytic membrane reactors in water treatment[J]. Environmental Chemistry, 2020, (5): 1297-1306. doi: 10.7524/j.issn.0254-6108.2019081305
Citation: ZHANG Qingqing, ZENG Ting, ZHANG Lei, WANG Chunying. Review of photocatalytic membrane reactors in water treatment[J]. Environmental Chemistry, 2020, (5): 1297-1306. doi: 10.7524/j.issn.0254-6108.2019081305
shu

光催化膜反应器应用于废水处理的研究进展

    通讯作者: 王春英, E-mail: beyond_life@163.com
  • 1. 江西理工大学资源与环境工程学院, 赣州, 341000;
  • 2. 江西省矿冶环境污染控制重点实验室, 赣州, 341000
  • 收稿日期:  2019-08-13
基金项目:

国家自然科学基金（51408277）和江西理工大学"清江青年英才支持计划"（JXUSTQJYX2016003）资助.

摘要: 多相光催化技术是目前最具有发展前景的水处理技术之一，其原理是光催化剂在光辐照下产生羟基自由基、超氧自由基等具有强氧化性的活性物种，从而降解各种有机污染物、灭活病原微生物、处理药剂废水等.但是该技术存在催化剂回收难、后续处理困难等问题.通过光催化技术与膜技术耦合而发展起的光催化膜反应器（photocatalytic membrane reactors，PMRs）将有效解决上述问题：相对于单独光催化处理，PMRs具有工艺简化、催化剂易于回收等优点；相对于单独膜处理，其又具有矿化完全、不易产生膜污染等优点.光催化剂种类（TiO2、g-C3N4、CeO2、MOFs材料、铋系光催化剂等），膜基材（有机膜、无机膜、陶瓷膜、聚合膜等），以及结合光催化剂与膜基的复合膜均对光催化膜反应器的性能有重要影响.目前，根据不同的水质及处理要求，国内外的光催化膜反应器类型主要分悬浮型和固定型，文章对不同种类光催化膜反应器构造、处理对象及其优缺点进行了详细论述；深入讨论了PMRs在实际应用中尚存在的技术、经济成本等限制问题.

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