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共存钙离子对镧铝改性稻壳生物炭除磷性能的影响

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阮华珍, 高章龙, 陈玉婷, 魏小婷, 熊瑞涵, 石稳民, 刘冬啟, 康建雄, 李道圣, 任拥政. 共存钙离子对镧铝改性稻壳生物炭除磷性能的影响[J]. 环境化学, 2020, (5): 1279-1289. doi: 10.7524/j.issn.0254-6108.2019070802
引用本文: 阮华珍, 高章龙, 陈玉婷, 魏小婷, 熊瑞涵, 石稳民, 刘冬啟, 康建雄, 李道圣, 任拥政. 共存钙离子对镧铝改性稻壳生物炭除磷性能的影响[J]. 环境化学, 2020, (5): 1279-1289. doi: 10.7524/j.issn.0254-6108.2019070802
shu
RUAN Huazhen, GAO Zhanglong, CHEN Yuting, WEI Xiaoting, XIONG Ruihan, SHI Wenmin, LIU Dongqi, KANG Jianxiong, LI Daosheng, REN Yongzheng. Effect of coexisting calcium ions on phosphate removal performance of lanthanum and aluminum modified rice husk biochar[J]. Environmental Chemistry, 2020, (5): 1279-1289. doi: 10.7524/j.issn.0254-6108.2019070802
Citation: RUAN Huazhen, GAO Zhanglong, CHEN Yuting, WEI Xiaoting, XIONG Ruihan, SHI Wenmin, LIU Dongqi, KANG Jianxiong, LI Daosheng, REN Yongzheng. Effect of coexisting calcium ions on phosphate removal performance of lanthanum and aluminum modified rice husk biochar[J]. Environmental Chemistry, 2020, (5): 1279-1289. doi: 10.7524/j.issn.0254-6108.2019070802
shu

共存钙离子对镧铝改性稻壳生物炭除磷性能的影响

  • 1. 华中科技大学环境科学与工程学院, 武汉, 430074;

  • 2. 中国城市建设研究院有限公司, 北京, 100120;

  • 3. 中国市政工程中南设计研究总院有限公司, 武汉, 430000;

  • 4. 中建三局绿色产业投资有限公司, 武汉, 430056

    • 通讯作者: 刘冬啟, E-mail: liudongqi@hust.edu.cn ; 
  • 基金项目:

    国家自然科学基金（51409108）和国家重点研发计划（2018YFD1100600）资助.

Effect of coexisting calcium ions on phosphate removal performance of lanthanum and aluminum modified rice husk biochar

  • 1. School of Environmental Science & Engineering, Huazhong University Science and Technology, Wuhan, 430074, China;

  • 2. China Urban Construction Design & Research Institute Co. Ltd, Beijing, 100120, China;

  • 3. Central and Southern China Municipal Engineering Design & Research Institute Co., Ltd, Wuhan, 430000, China;

  • 4. China Construction Third Bureau Green Industry Investment Co., Ltd., Wuhan, 430056, China

    • Corresponding author: LIU Dongqi, liudongqi@hust.edu.cn ; 
  • Fund Project: Supported by the National Natural Science Foundation of China(51409108) and National Key Research and Development Program(2018YFD1100600).

  • 摘要: 本研究利用稻壳制备高介孔率生物炭，然后用共沉淀法负载金属La、Al，制得镧铝改性稻壳基生物炭吸附剂.通过控制反应时间、磷浓度、共存阴离子、初始pH等条件，研究共存钙离子时对吸附剂除磷性能的影响.结果表明，La、Al在稻壳基生物炭上负载后呈无定型态；吸附剂的除磷过程符合伪二阶动力学模型和Langmuir模型，且Ca2+的加入有利于提高磷的去除率，含Ca2+体系的最终除磷效果是无Ca2+时的2.6倍；含竞争阴离子时，Ca2+的加入会使F-对磷吸附的抑制作用减弱，使HCO3-对磷吸附的抑制作用略微增强；在pH值为2.0—8.0时，Ca2+能提高改性生物炭的吸附容量，而pH>8.0时主要是钙离子与磷酸盐的沉淀作用使体系中磷大量被去除.
    Abstract: In the present work, the modified adsorbents were obtained by co-precipitation La and Al to the high mesoporous biochar which was prepared from rice husks. The effects of reaction time, phosphate concentration, coexisting anions, initial pH and other conditions on the phosphate removal properties of the adsorbents were characterized with the existence of calcium ions. The results showed that La, Al was amorphous on rice husk biochar, the phosphate removal process was in accordance with the pseudo second-order kinetic model and Langmuir model, and the addition of calcium ions improved the phosphate removal rate, the phosphorus removal performance of Ca2+ system was 2.6 times higher that of Ca2+ free. In the presence of competitive anions, the addition of calcium ions would weaken the inhibition of F- on phosphate adsorption, and slightly enhance the inhibition of HCO3-. At pH 2.0-8.0, Ca2+ could increase the adsorption capacity of the modified biochar, while the higher phosphate removal was achieved by the precipitation of calcium ions and phosphate when pH>8.0.
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  • [1] 邵青. EM除磷效果初探[J]. 工业水处理,2001,21(2):16-18.

    SHAO Q. Study on removing phosphate of domestic wastes with EM[J]. Industrial Water Treatment, 2001, 21(2):16-18(in Chinese).

    [2] SUNIL K R, LOREN G, GUNAWAN G, et al. A comprehensive review of phosphate removal technologies and processes[J]. Journal of Macromolecular Science, 2014,51:538-545.
    [3] VIKRANT K, KIM K, OK Y S, et al. Engineered/designer biochar for the removal of phosphate in water and wastewater[J]. Science of the Total Environment, 2018, 616-617:1242-1260.
    [4] LIMA I M, MARSHALL W E. Adsorption of selected environmentally important metals by poultry manure-based granular activated carbons[J]. Journal of Chemical Technology & Biotechnology, 2005, 80(9):1054-1061.
    [5] SIZMUR T, FRESNO T, AKGVL G, et al. Biochar modification to enhance sorption of inorganics from water[J]. Bioresource Technology, 2017, 246:34-47.
    [6] QIU H, LIANG C, YU J, et al. Preferable phosphate sequestration by nano-La(Ⅲ) (hydr)oxides modified wheat straw with excellent properties in regeneration[J]. Chemical Engineering Journal, 2017, 315:345-354.
    [7] XIE J, WANG Z, LU S, et al. Removal and recovery of phosphate from water by lanthanum hydroxide materials[J]. Chemical Engineering Journal, 2014, 254:163-170.
    [8] 石稳民, 付有为, 许智, 等. 镧负载多孔陶粒用于低浓度含磷废水的处理[J]. 环境科学与技术,2018,41(11):110-114.

    SHI W M, FU Y W, XU Z, et al. Treatment of wastewater containing low concentration of phosphate by lanthanum doped porous ceramics[J]. Environmental Science & Technology, 2018, 41(11):110-114(in Chinese).

    [9] TANG Q, SHI C, SHI W, et al. Preferable phosphate removal by nano-La(Ⅲ) hydroxides modified mesoporous rice husk biochars:Role of the host pore structure and point of zero charge[J]. Science of the Total Environment, 2019, 662:511-520.
    [10] SHI W, FU Y, JIANG W, et al. Enhanced phosphate removal by zeolite loaded with Mg-Al-La ternary (hydr)oxides from aqueous solutions:Performance and mechanism[J]. Chemical Engineering Journal, 2019, 357:33-44.
    [11] YIN Q, REN H, WANG R, et al. Evaluation of nitrate and phosphate adsorption on Al-modified biochar:Influence of Al content[J]. Science of the Total Environment, 2018, 631-632:895-903.
    [12] 徐凌云, 奚军军, 陈贵杰, 等. 酒糟生物炭负载铝对饮用水中氟的去除[J]. 环境工程学报,2016,10(10):5624-5630.

    XU L Y, XI J J, CHEN G J, et al. Removal of fluoride from drinking water using distiller's grains biochars coated by aluminum hydroxide[J]. Chinese Journal of Environmental Engineering, 2016, 10(10):5624-5630(in Chinese).

    [13] YAN L, XU Y, YU H, et al. Adsorption of phosphate from aqueous solution by hydroxy-aluminum, hydroxy-iron and hydroxy-iron-aluminum pillared bentonites[J]. Journal of Hazardous Materials, 2010, 179(1-3):244-250.
    [14] ZHANG S, LU Y, LIN X, et al. Removal of fluoride from groundwater by adsorption onto La(Ⅲ)-Al(Ⅲ) loaded scoria adsorbent[J]. Applied Surface Science, 2014, 303:1-5.
    [15] HUANG W, CHEN J, HE F, et al. Effective phosphate adsorption by Zr/Al-pillared montmorillonite:insight into equilibrium, kinetics and thermodynamics[J]. Applied Clay Science, 2015, 104:252-260.
    [16] MITROGIANNIS D, PSYCHOYOU M, BAZIOTIS I, et al. Removal of phosphate from aqueous solutions by adsorption onto Ca(OH)2 treated natural clinoptilolite[J]. Chemical Engineering Journal, 2017, 320:510-522.
    [17] ANTELO J, ARCE F, FIOL S. Arsenate and phosphate adsorption on ferrihydrite nanoparticles. Synergetic interaction with calcium ions[J]. Chemical Geology, 2015, 410:53-62.
    [18] RIETRA R P J J, HIEMSTRA T, van RIEMSDIJK W H. Interaction between Calcium and Phosphate Adsorption on Goethite[J]. Environmental Science & Technology, 2001, 35(16):3369-3374.
    [19] 李大伟. 热解稻壳炭基多孔材料的制备、表征及应用基础[D]. 合肥:中国科学技术大学, 2011. LI D W. Preparation,characterization and application of porous materials deriverd from pyrolyzed rice husk[D]. Hefei:University of Science and Technology of China, 2011(in Chinese).
    [20] 石程好. 镧负载稻壳基生物炭除磷性能研究[D]. 武汉:华中科技大学, 2018. SHI C H. Study on the phosphate removal by La-modified rice husk biochars[D]. Wuhan:Huazhong University of Science and Technology, 2018(in Chinese).
    [21] SEN GUPTA S, BHATTACHARYYA K G. Kinetics of adsorption of metal ions on inorganic materials:A review[J]. Advances in Colloid and Interface Science, 2011, 162(1-2):39-58.
    [22] CHEN L, ZHAO X, PAN B, et al. Preferable removal of phosphate from water using hydrous zirconium oxide-based nanocomposite of high stability[J]. Journal of Hazardous Materials, 2015, 284:35-42.
    [23] LIN J, ZHAN Y, WANG H, et al. Effect of calcium ion on phosphate adsorption onto hydrous zirconium oxide[J]. Chemical Engineering Journal, 2017, 309:118-129.
    [24] YAO W, MILLERO F J. Adsorption of phosphate on manganese dioxide in seawater[J]. Environmental Science and Technology, 1996, 30(2):536-541.
    [25] 许润, 石程好, 唐倩, 等. 氢氧化镧改性介孔稻壳生物炭除磷性能[J]. 环境科学,2019,40(4):1834-1841.

    XU R, SHI C H, TANG Q, et al. Phosphate removal using rice husk biochars modified with lanthanum hydroxide[J]. Environmental Science, 2019, 40(4):1834-1841(in Chinese).

    [26] KOILRAJ P, SASAKI K. Selective removal of phosphate using La-porous carbon composites from aqueous solutions:Batch and column studies[J]. Chemical Engineering Journal, 2017, 317:1059-1068.
    [27] XU R, ZHANG M, MORTIMER R J G, et al. Enhanced phosphate locking by novel lanthanum/aluminum-hydroxide composite:Implications for eutrophication control[J]. Environmental Science & Technology, 2017, 51(6):3418-3425.
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  • 收稿日期:  2019-07-08
阮华珍, 高章龙, 陈玉婷, 魏小婷, 熊瑞涵, 石稳民, 刘冬啟, 康建雄, 李道圣, 任拥政. 共存钙离子对镧铝改性稻壳生物炭除磷性能的影响[J]. 环境化学, 2020, (5): 1279-1289. doi: 10.7524/j.issn.0254-6108.2019070802
引用本文: 阮华珍, 高章龙, 陈玉婷, 魏小婷, 熊瑞涵, 石稳民, 刘冬啟, 康建雄, 李道圣, 任拥政. 共存钙离子对镧铝改性稻壳生物炭除磷性能的影响[J]. 环境化学, 2020, (5): 1279-1289. doi: 10.7524/j.issn.0254-6108.2019070802
shu
RUAN Huazhen, GAO Zhanglong, CHEN Yuting, WEI Xiaoting, XIONG Ruihan, SHI Wenmin, LIU Dongqi, KANG Jianxiong, LI Daosheng, REN Yongzheng. Effect of coexisting calcium ions on phosphate removal performance of lanthanum and aluminum modified rice husk biochar[J]. Environmental Chemistry, 2020, (5): 1279-1289. doi: 10.7524/j.issn.0254-6108.2019070802
Citation: RUAN Huazhen, GAO Zhanglong, CHEN Yuting, WEI Xiaoting, XIONG Ruihan, SHI Wenmin, LIU Dongqi, KANG Jianxiong, LI Daosheng, REN Yongzheng. Effect of coexisting calcium ions on phosphate removal performance of lanthanum and aluminum modified rice husk biochar[J]. Environmental Chemistry, 2020, (5): 1279-1289. doi: 10.7524/j.issn.0254-6108.2019070802
shu

共存钙离子对镧铝改性稻壳生物炭除磷性能的影响

    通讯作者: 刘冬啟, E-mail: liudongqi@hust.edu.cn ; 
  • 1. 华中科技大学环境科学与工程学院, 武汉, 430074;
  • 2. 中国城市建设研究院有限公司, 北京, 100120;
  • 3. 中国市政工程中南设计研究总院有限公司, 武汉, 430000;
  • 4. 中建三局绿色产业投资有限公司, 武汉, 430056
  • 收稿日期:  2019-07-08
基金项目:

国家自然科学基金（51409108）和国家重点研发计划（2018YFD1100600）资助.

摘要: 本研究利用稻壳制备高介孔率生物炭，然后用共沉淀法负载金属La、Al，制得镧铝改性稻壳基生物炭吸附剂.通过控制反应时间、磷浓度、共存阴离子、初始pH等条件，研究共存钙离子时对吸附剂除磷性能的影响.结果表明，La、Al在稻壳基生物炭上负载后呈无定型态；吸附剂的除磷过程符合伪二阶动力学模型和Langmuir模型，且Ca2+的加入有利于提高磷的去除率，含Ca2+体系的最终除磷效果是无Ca2+时的2.6倍；含竞争阴离子时，Ca2+的加入会使F-对磷吸附的抑制作用减弱，使HCO3-对磷吸附的抑制作用略微增强；在pH值为2.0—8.0时，Ca2+能提高改性生物炭的吸附容量，而pH>8.0时主要是钙离子与磷酸盐的沉淀作用使体系中磷大量被去除.

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