新型有机污染物氯代多环芳烃分析方法及其污染现状研究进展

高占啟, 杨雪, 彭英. 新型有机污染物氯代多环芳烃分析方法及其污染现状研究进展[J]. 环境化学, 2016, 35(2): 287-296. doi: 10.7524/j.issn.0254-6108.2016.02.2015080301
引用本文: 高占啟, 杨雪, 彭英. 新型有机污染物氯代多环芳烃分析方法及其污染现状研究进展[J]. 环境化学, 2016, 35(2): 287-296. doi: 10.7524/j.issn.0254-6108.2016.02.2015080301
GAO Zhanqi, YANG Xue, PENG Ying. Analytical methods and pollution status of a new class of organic contaminants-chlorinated polycyclic aromatic hydrocarbons[J]. Environmental Chemistry, 2016, 35(2): 287-296. doi: 10.7524/j.issn.0254-6108.2016.02.2015080301
Citation: GAO Zhanqi, YANG Xue, PENG Ying. Analytical methods and pollution status of a new class of organic contaminants-chlorinated polycyclic aromatic hydrocarbons[J]. Environmental Chemistry, 2016, 35(2): 287-296. doi: 10.7524/j.issn.0254-6108.2016.02.2015080301

新型有机污染物氯代多环芳烃分析方法及其污染现状研究进展

  • 基金项目:

    江苏省环境监测基金(1413)资助.

Analytical methods and pollution status of a new class of organic contaminants-chlorinated polycyclic aromatic hydrocarbons

  • Fund Project: Supported by the Environmental Monitoring Fund of Jiangsu Province(1413).
  • 摘要: 氯代多环芳烃(Chlorinated polycyclic aromatic hydrocarbons,Cl-PAHs)作为多环芳烃的氯代衍生物,具有类似二英的致癌、致畸、致突变毒性,并且广泛存在于环境介质中,对生态环境和人类健康具有一定的潜在威胁.本文介绍了Cl-PAHs在不同环境介质中的分析方法、污染现状、迁移转化及其毒性效应,最后对其未来研究方向进行了展望.在今后,应该加强污泥和沉积物等复杂环境基质中Cl-PAHs的分析方法研究;系统研究Cl-PAHs在环境介质中的污染现状和迁移转化行为,并开展Cl-PAHs的环境风险和人体健康风险研究.
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  • [1] OHURA T, AMAGAI T, MAKINO M. Behavior and prediction of photochemical degradation of chlorinated polycyclic aromatic hydrocarbons in cyclohexane[J]. Chemosphere, 2008, 70(11):2110-2117.
    [2] HORIL Y, KHIM J S, HIGLEY E B, et al. Relative potencies of individual chlorinated and brominated polycyclic aromatic hydrocarbons for induction of aryl hydrocarbon receptor-mediated responses[J]. Environmental Science & Technology, 2009, 43(6):2159-2165.
    [3] KUCKLICK J R, HELM P A. Advances in the environmental analysis of polychlorinated naphthalenes and toxaphene[J]. Analytical and Bioanalytical Chemistry, 2006, 386(4):819-836.
    [4] MAHMOODA, MALIK R N, LI J, et al. Congener specific analysis, spatial distribution and screening-level risk assessment of polychlorinated naphthalenes in water and sediments from two tributaries of the River Chenab, Pakistan[J]. Science of The Total Environment, 2014, 485-486:693-700.
    [5] KANNAN K, HILSCHEROVA K, IMAGAWA T, et al. Polychlorinated naphthalenes,-biphenyls,-dibenzo-p-dioxins, and-dibenzofurans in double-crested cormorants and herring gulls from Michigan waters of the Great Lakes[J]. Environmental Science & Technology, 2001, 35(3):441-447.
    [6] FALANDYSZ J. Polychlorinated naphthalenes:An environmental update[J]. Environment Pollution, 1998, 101(1):77-90.
    [7] 杨永亮,潘静,朱晓华,等. 四川省卧龙地区土壤中二英类化合物和多氯萘的海拔梯度分布及对牦牛的毒性风险评价[J]. 环境化学, 2009, 28(2):276-283.

    YANG Y L, PAN J, ZHU X H, LIU X D. Altitude gradient distributions of dioxin-like compounds and PCNs in soils from Wolong area and human health risk assessment for yak consumption[J]. Environmental Chemistry, 2009, 28(2):276-283(in Chinese).

    [8]
    [9] LOFROTH G, NILSSON L, AGURELL E, et al. Salmonella/microsome mutagenicity of monochloro derivatives of some di-, tri-and tetracyclic aromatic hydrocarbons[J]. Mutation research, 1985, 155(3):91-94.
    [10] COLMSJO A, RANNUG A, RANNUG U. Some chloro derivatives of polynuclear aromatic hydrocarbons are potent mutagens in Salmonella typhimurium[J]. Mutation research, 1984, 135(1):21-29.
    [11] SHIRAISHI H, PILKING N H, OTSUKI A, et al. Occurrence of chlorinated polynuclear aromatic hydrocarbons in tap water[J]. Environ Sci Technol, 1985, 19(7):585-590.
    [12] OYIER A R, LIUKKONEN R J, LUKASEWYCZ M T, et al. Chlorine "Disinfection" chemistry of aromatic compounds. Polynuclear aromatic hydrocarbons:Rates, products, and mechanisms[J]. Environmental Science & Technology, 1983, 17:334-342.
    [13] MA J, HORⅡ Y, CHENG J, et al. Chlorinated and parent polycyclic aromatic hydrocarbons in environmental samples from an electronic waste recycling facility and a chemical industrial complex in China[J]. Environmental Science & Technology, 2009, 43(3):643-649.
    [14] IEDA T, OCHIAI N, MIYAWAKI T, et al. Environmental analysis of chlorinated and brominated polycyclic aromatic hydrocarbons by comprehensive two-dimensional gas chromatography coupled to high-resolution time-of-flight mass spectrometry[J]. Journal of Chromatography A, 2011, 1218(21):3224-3232.
    [15] 孙建林,倪宏刚,丁超,等. 深圳茅洲河表层沉积物卤代多环芳烃污染研究[J]. 环境科学, 2012, 33(9):3089-3096.

    SUN J L, NI H G, DING C, et al. Halogenated polycyclic aromatic hydrocarbons in surface sediments of Maozhou River, Shenzhen[J]. Environmental Science, 2012, 33(09):3089-3096(in Chinese).

    [16] KITAZAWA A, AMAGAI T, OHURA T. Temporal trends and relationships of particulate chlorinated polycyclic aromatic hydrocarbons and their parent compounds in urban air[J]. Environmental Science & Technology, 2006, 40(15):4592-4598.
    [17] KAKIMOTO K, NAGAYOSHI H, KONISHI Y, et al. Atmospheric chlorinated polycyclic aromatic hydrocarbons in East Asia[J]. Chemosphere, 2014, 111:40-46.
    [18] 王丽,金芬,李敏洁,等. 分散固相萃取-气相色谱-串联质谱法测定蔬菜中多环芳烃及卤代多环芳烃[J]. 分析化学, 2013,41(6):869-875.

    WANG L, JIN F, LI M J, et al. Determination of polycyclic aromatic hydrocarbons and halogenated polycyclic hydrocarbons in vegetable by gas chromatography-tandem mass spectrometry[J]. Chinese Journal of Analytical Chemistry, 2013,41(6):869-875(in Chinese).

    [19] MA J, CHEN Z, WU M, et al. Airborne PM2.5/PM10-associated chlorinated polycyclic aromatic hydrocarbons and their parent compounds in a suburban area in Shanghai, China[J]. Environmental Science & Technology, 2013, 47(14):7615-7623.
    [20] FERNANDO S, JOBST K J, TAGUCHI V Y, et al. Identification of the halogenated compounds resulting from the 1997 Plastimet Inc. Fire in Hamilton, Ontario, using comprehensive two-dimensional gas chromatography and(ultra)high resolution mass spectrometry[J]. Environmental Science & Technology, 2014, 48(18):10656-10663.
    [21] HORⅡ Y, OK G, OHURA T, et al. Occurrence and profiles of chlorinated and brominated polycyclic aromatic hydrocarbons in waste incinerators[J]. Environmental Science & Technology, 2008, 42(6):1904-1909.
    [22] 莫李桂,马盛韬,李会茹,等. 气相色谱/三重四极杆串联质谱法检测土壤中氯代多环芳烃和溴代多环芳烃[J]. 分析化学, 2013, 41(12):1825-1830.

    MO L G, MA S T, LI H R, et al. Determination of chlorinated-and brominated-polycyclic aromatic hydrocarbons in soil samples by gas chromatography coupled with triple quadrupole mass spectrometry[J]. Chinese Journal of Analytical Chemistry, 2013, 41(12):1825-1830(in Chinese).

    [23] SANKODA K, KURIBAYASHI T, NOMIYAMA K, et al. Occurrence and source of chlorinated polycyclic aromatic hydrocarbons(Cl-PAHs) in tidal flats of the Ariake Bay, Japan[J]. Environmental Science & Technology, 2013, 47:7037-7044.
    [24] FUJIMA S, OHURA T, AMAGAI T. Simultaneous determination of gaseous and particulate chlorinated polycyclic aromatic hydrocarbons in emissions from the scorching of polyvinylidene chloride film[J]. Chemosphere, 2006, 65(11):1983-1989.
    [25] 郑继三,马静,Horii Yuichi,等. 固相萃取/气相色谱质谱法测定灰尘中的氯代多环芳烃[J]. 环境化学, 2012, 31(7):1101-1107.

    ZHENG J, MA J, YUICHI H, et al. Determination of chlorinated polycyclic aromatic hydrocarbons in dust by solid-phase extract(SPE) and gas chromatofraphy-mass spectrometry[J]. Environmental Chemistry, 2012, 31(7):1101-1107(in Chinese).

    [26] OHURA T, KITAZAWA A, AMAGAI T, et al. Occurrence, profiles, and photostabilities of chlorinated polycyclic aromatic hydrocarbons associated with particulates in urban air[J]. Environmental Science & Technology, 2005, 39(1):85-91.
    [27] HORⅡ Y, OHURA T, YAMASHITA N, et al. Chlorinated polycyclic aromatic hydrocarbons in sediments from industrial areas in Japan and the United States[J]. Archives of Environmental Contamination and Toxicology, 2009, 57(4):651-660.
    [28] MANZANO C, HOH E, SIMONICH S L M. Improved separation of complex polycyclic aromatic hydrocarbon mixtures using novel column combinations in GC×GC/ToF-MS[J]. Environmental Science & Technology, 2012, 46(14):7677-7684.
    [29] OHURA T, HORⅡ Y, KOJIMA M, et al. Diurnal variability of chlorinated polycyclic aromatic hydrocarbons in urban air, Japan[J]. Atmospheric Environment, 2013, 81:84-91.
    [30] OHURA T, SAWADA K, AMAGAI T, et al. Discovery of novel halogenated polycyclic aromatic hydrocarbons in urban particulate matters:Occurrence, photostability, and AhR activity[J]. Environmental Science & Technology, 2009, 43(7):2269-2275.
    [31] OHURA T, KITAZAWA A, AMAGAI T. Seasonal variability of 1-chloropyrene on atmospheric particles and photostability in toluene[J]. Chemosphere, 2004, 57(8):831-837.
    [32] 孙建林,常文静,陈正侠,等. 深圳大气颗粒物中卤代多环芳烃污染研究[J]. 环境科学, 2015, 36(5):1513-1522.

    SUN J L, CHANG W J, CHEN Z X, et al. Pollution of halogenated polycyclic aromatic hydrocarbons in atmospheric particulate matters of Shenzhen[J]. Environment Science, 2015, 36(5):1513-1522(in Chinese).

    [33] SANKODA K, NOMIYAMA K, YONHARA T, et al. Evidence for in situ production of chlorinated polycyclic aromatic hydrocarbons on tidal flats:Environmental monitoring and laboratory scale experiment[J]. Chemosphere, 2012, 88(5):542-547.
    [34] NI H, ZENG E Y. Environmental and human exposure to soil chlorinated and brominated polycyclic aromatic hydrocarbons in an urbanized region[J]. Environmental Toxicology and Chemistry, 2012, 31(7):1494-1500.
    [35] OHURA T, FUJIMA S, AMAGAIT, et al. Chlorinated polycyclic aromatic hydrocarbons in the atmosphere:Seasonal levels, gas-particle partitioning, and origin[J]. Environmental Science & Technology, 2008, 42(9):3296-3302.
    [36] NILSSON U L, OESTMAN C E. Chlorinated polycyclic aromatic hydrocarbons:Method of analysis and their occurrence in urban air[J]. Environmental Science & Technology, 1993, 27(9):1826-1831.
    [37] ISHAQ R, NAF C, ZEBUHR Y, et al. PCBs, PCNs, PCDD/Fs, PAHs and Cl-PAHs in air and water particulate samples——patterns and variations[J]. Chemosphere, 2003, 50(9):1131-1150.
    [38] OHURA T. Environmental behavior, sources, and effects of chlorinated polycyclic aromatic hydrocarbons[J]. The Scientific World Journal, 2007, 7:372-380.
    [39] FU P, Von TUNGELN L, CHIU L, et al. Halogenated-polycyclic aromatic hydrocarbons:A class of genotoxic environmental pollutants[J]. Environmental Carcinogenesis & Ecotoxicology Reviews-Part C of Journal of Environmental Science and Health, 1999, 17(2):71-109.
    [40] OHURA T, MORITAM, MAKINO M, et al. Aryl Hydrocarbon receptor-mediated effects of chlorinated polycyclic aromatic hydrocarbons[J]. Chemical Research in Toxicology, 2007, 20(9):1237-1241.
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出版历程
  • 收稿日期:  2015-08-03
  • 刊出日期:  2016-02-15

新型有机污染物氯代多环芳烃分析方法及其污染现状研究进展

  • 1. 国家环境保护地表水环境有机污染物监测分析重点实验室, 江苏省环境监测中心, 南京, 210036
基金项目:

江苏省环境监测基金(1413)资助.

摘要: 氯代多环芳烃(Chlorinated polycyclic aromatic hydrocarbons,Cl-PAHs)作为多环芳烃的氯代衍生物,具有类似二英的致癌、致畸、致突变毒性,并且广泛存在于环境介质中,对生态环境和人类健康具有一定的潜在威胁.本文介绍了Cl-PAHs在不同环境介质中的分析方法、污染现状、迁移转化及其毒性效应,最后对其未来研究方向进行了展望.在今后,应该加强污泥和沉积物等复杂环境基质中Cl-PAHs的分析方法研究;系统研究Cl-PAHs在环境介质中的污染现状和迁移转化行为,并开展Cl-PAHs的环境风险和人体健康风险研究.

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