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改良剂对土壤Sb赋存形态和生物可给性的影响

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李季, 黄益宗, 胡莹, 金姝兰, 保琼莉, 王斐, 向猛, 李晓敏. 改良剂对土壤Sb赋存形态和生物可给性的影响[J]. 环境化学, 2015, 34(6): 1043-1048. doi: 10.7524/j.issn.0254-6108.2015.06.2014111301
引用本文: 李季, 黄益宗, 胡莹, 金姝兰, 保琼莉, 王斐, 向猛, 李晓敏. 改良剂对土壤Sb赋存形态和生物可给性的影响[J]. 环境化学, 2015, 34(6): 1043-1048. doi: 10.7524/j.issn.0254-6108.2015.06.2014111301
shu
LI Ji, HUANG Yizong, HU Ying, JIN Shulan, BAO Qiongli, WANG Fei, XIANG Meng, LI Xiaomin. Effect of several amendments on fractionation and bio-accessibility of antimony in contaminated soil[J]. Environmental Chemistry, 2015, 34(6): 1043-1048. doi: 10.7524/j.issn.0254-6108.2015.06.2014111301
Citation: LI Ji, HUANG Yizong, HU Ying, JIN Shulan, BAO Qiongli, WANG Fei, XIANG Meng, LI Xiaomin. Effect of several amendments on fractionation and bio-accessibility of antimony in contaminated soil[J]. Environmental Chemistry, 2015, 34(6): 1043-1048. doi: 10.7524/j.issn.0254-6108.2015.06.2014111301
shu

改良剂对土壤Sb赋存形态和生物可给性的影响

  • 1.

    中国科学院生态环境研究中心, 北京, 100085;

  • 2.

    农业部环境保护科研监测所, 天津, 300191;

  • 3.

    上饶师范学院, 上饶, 334000

  • 基金项目:

    国家科技支撑计划项目(2015BAD05B02)

    国家自然科学基金面上项目(21377152)

    中央级公益性科研院所基本科研业务费专项资金(农业部环境保护科研监测所)资助项目资助.

Effect of several amendments on fractionation and bio-accessibility of antimony in contaminated soil

  • 1.

    Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China;

  • 2.

    Agro-Environmental Protection Institute, Ministry of Agriculture, Tianjin, 300191, China;

  • 3.

    Shangrao Normal University, Shangrao, 334000, China

  • Fund Project:

  • 摘要: 采用室内土壤培养法研究不同改良剂(骨炭、生物调理剂、沸石、石灰、油菜秸秆、生物炭、堆肥和赤泥)对土壤Sb化学形态转化和生物可给性的影响.结果表明,除堆肥处理外,添加5%的其他7种改良剂均显著地提高了土壤的pH值,其中石灰处理pH最为明显.BCR分级提取表明,土壤Sb主要以残渣态形式存在.添加生石灰、骨炭和生物调理剂显著地提高了土壤Sb的移动性,而添加赤泥、生物炭和堆肥却显著地降低了土壤Sb的移动性.添加不同的改良剂对土壤Sb的生物可给性也有影响,但是受不同培养时间影响较大.培养2个月后,添加5%的堆肥、5%赤泥和5%生物炭处理导致土壤Sb的生物可给性含量分别比对照降低38%、23%和20%;而添加5%的石灰、5%油菜秸秆和5%的生物调理剂处理导致土壤Sb的生物可给性含量分别比对照提高1.07倍、1.06倍和1.11倍.堆肥、赤泥和生物炭是钝化Sb污染土壤的潜力材料.
    Abstract: Effects of bone char, modifying agent, zeolite, limestone, rape straw, biochar, compost and red mud on the fractionation and bio-accessibility of Sb in soil were investigated by batch soil column incubation experiment in laboratory. All 5% amendments increased the soil pH except compost, and the most effective one was limestone. BCR sequential extraction showed that Sb was mainly in the residual fraction form. The treatment with 5% limestone, 5% bone char and 5% modifying agent significantly (PP<0.05). Different amendments had different effects on the bio-accessibility of Sb, and the key influencing factor was incubation time. Compared with the control, the contents of bio-accessible Sb decreased by 38%, 23% and 20%, respectively, in 5% compost, 5% red mud and 5% biochar amended soils after 2 months incubation. Contents of bio-accessible Sb increased by 1.07, 1.06 and 1.11-fold with 5% limestone, 5% rape straw and 5% modifying agent addition after 2 months incubation. The results highlighted the potential of red mud, biochar and compost in reducing the bioavailability of Sb in contaminated soil.
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  • 收稿日期:  2014-11-13
  • 刊出日期:  2015-06-15
李季, 黄益宗, 胡莹, 金姝兰, 保琼莉, 王斐, 向猛, 李晓敏. 改良剂对土壤Sb赋存形态和生物可给性的影响[J]. 环境化学, 2015, 34(6): 1043-1048. doi: 10.7524/j.issn.0254-6108.2015.06.2014111301
引用本文: 李季, 黄益宗, 胡莹, 金姝兰, 保琼莉, 王斐, 向猛, 李晓敏. 改良剂对土壤Sb赋存形态和生物可给性的影响[J]. 环境化学, 2015, 34(6): 1043-1048. doi: 10.7524/j.issn.0254-6108.2015.06.2014111301
shu
LI Ji, HUANG Yizong, HU Ying, JIN Shulan, BAO Qiongli, WANG Fei, XIANG Meng, LI Xiaomin. Effect of several amendments on fractionation and bio-accessibility of antimony in contaminated soil[J]. Environmental Chemistry, 2015, 34(6): 1043-1048. doi: 10.7524/j.issn.0254-6108.2015.06.2014111301
Citation: LI Ji, HUANG Yizong, HU Ying, JIN Shulan, BAO Qiongli, WANG Fei, XIANG Meng, LI Xiaomin. Effect of several amendments on fractionation and bio-accessibility of antimony in contaminated soil[J]. Environmental Chemistry, 2015, 34(6): 1043-1048. doi: 10.7524/j.issn.0254-6108.2015.06.2014111301
shu

改良剂对土壤Sb赋存形态和生物可给性的影响

  • 1.  中国科学院生态环境研究中心, 北京, 100085;
  • 2.  农业部环境保护科研监测所, 天津, 300191;
  • 3.  上饶师范学院, 上饶, 334000
  • 收稿日期:  2014-11-13
基金项目:

国家科技支撑计划项目(2015BAD05B02)

国家自然科学基金面上项目(21377152)

中央级公益性科研院所基本科研业务费专项资金(农业部环境保护科研监测所)资助项目资助.

摘要: 采用室内土壤培养法研究不同改良剂(骨炭、生物调理剂、沸石、石灰、油菜秸秆、生物炭、堆肥和赤泥)对土壤Sb化学形态转化和生物可给性的影响.结果表明,除堆肥处理外,添加5%的其他7种改良剂均显著地提高了土壤的pH值,其中石灰处理pH最为明显.BCR分级提取表明,土壤Sb主要以残渣态形式存在.添加生石灰、骨炭和生物调理剂显著地提高了土壤Sb的移动性,而添加赤泥、生物炭和堆肥却显著地降低了土壤Sb的移动性.添加不同的改良剂对土壤Sb的生物可给性也有影响,但是受不同培养时间影响较大.培养2个月后,添加5%的堆肥、5%赤泥和5%生物炭处理导致土壤Sb的生物可给性含量分别比对照降低38%、23%和20%;而添加5%的石灰、5%油菜秸秆和5%的生物调理剂处理导致土壤Sb的生物可给性含量分别比对照提高1.07倍、1.06倍和1.11倍.堆肥、赤泥和生物炭是钝化Sb污染土壤的潜力材料.

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