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微孔-P25复合二氧化钛矿化挥发性有机物的性能

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张旻, 高俊贤, 王艳红, 王硕, 李激, 吕金泽. 微孔-P25复合二氧化钛矿化挥发性有机物的性能[J]. 环境工程学报, 2017, 11(10): 5523-5528. doi: 10.12030/j.cjee.201612088
引用本文: 张旻, 高俊贤, 王艳红, 王硕, 李激, 吕金泽. 微孔-P25复合二氧化钛矿化挥发性有机物的性能[J]. 环境工程学报, 2017, 11(10): 5523-5528. doi: 10.12030/j.cjee.201612088
shu
ZHANG Min, GAO Junxian, WANG Yanhong, WANG Shuo, LI Ji, LYU Jinze. Performance of microporous-P25 composite TiO2 for volatile organic compounds mineralization[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5523-5528. doi: 10.12030/j.cjee.201612088
Citation: ZHANG Min, GAO Junxian, WANG Yanhong, WANG Shuo, LI Ji, LYU Jinze. Performance of microporous-P25 composite TiO2 for volatile organic compounds mineralization[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5523-5528. doi: 10.12030/j.cjee.201612088
shu

微孔-P25复合二氧化钛矿化挥发性有机物的性能

  • 1.

    江南大学环境与土木工程学院, 无锡 214122

  • 2.

    江苏省厌氧生物技术重点实验室, 无锡 214122

  • 3.

    江苏高校水处理技术与材料协同创新中心, 苏州 215009

  • 基金项目:

    江苏省青年科学基金资助项目（BK20150126）

    绿色催化四川省高校重点实验室开放基金资助项目（LZJ14203）

    中央高校基本科研业务费专项（JUSRP11522）

  • 中图分类号: X51

Performance of microporous-P25 composite TiO2 for volatile organic compounds mineralization

  • 1.

    School of Environment and Civil Engineering, Jiangnan University, Wuxi 214122, China

  • 2.

    Jiangsu Key Laboratory of Anaerobic Biotechnology, Jiangnan University, Wuxi 214122, China

  • 3.

    Jiangsu College of Water Treatment Technology and Material Collaborative Innovation Center, Suzhou 215009, China

  • Fund Project:

  • 摘要: 矿化效率不足是光催化净化VOCs技术应用的主要瓶颈之一。为提升矿化效率，以十二胺为模板剂，在P25表面构建微孔二氧化钛同质吸附层。利用表面光电压谱、氮气等温吸附-脱附、X射线衍射等研究其结构特性和对甲苯的光催化降解，并探讨微孔TiO2和P25复合比例对催化剂性能的影响。结果发现，随着微孔复合比例增加，比表面积和甲苯平衡吸附量均显著提高。微孔复合比例小导致吸附对甲苯矿化的强化作用不明显，而微孔复合比例过高则造成材料光生载流子分离效率下降。微孔TiO2和P25复合比例为8∶5时，催化剂对甲苯的矿化效率最高，分别是P25和微孔TiO2的3.14和1.85倍。
    Abstract: Mineralization efficiency is one of the main bottlenecks in the application of VOCs photocatalytic degradation. In order to improve mineralization efficiency, microporous titanium layer was constructed on the surface of P25 using 12-amino-dodecylamine as the template. The structural characteristics and photocatalytic degradation of toluene were studied by surface photovoltage measurement system, nitrogen isothermal adsorption-desorption and X-ray diffraction. The results showed that the surface area and the equilibrium adsorption amount of toluene increased with the mole ratio of microporous composite to P25.The relatively low ratio limited the adsorption amount of toluene, whereas the separation efficiency of charge carriers decreased when the coated microporous TiO2 too thick. The microporous-P25 composite with mole ratio of 8:5 showed the highest mineralization efficiency of toluene, 3.14 and 1.85 times higher than those of P25 and microporous TiO2, respectively.
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  • 收稿日期:  2017-02-15
  • 刊出日期:  2017-10-12
张旻, 高俊贤, 王艳红, 王硕, 李激, 吕金泽. 微孔-P25复合二氧化钛矿化挥发性有机物的性能[J]. 环境工程学报, 2017, 11(10): 5523-5528. doi: 10.12030/j.cjee.201612088
引用本文: 张旻, 高俊贤, 王艳红, 王硕, 李激, 吕金泽. 微孔-P25复合二氧化钛矿化挥发性有机物的性能[J]. 环境工程学报, 2017, 11(10): 5523-5528. doi: 10.12030/j.cjee.201612088
shu
ZHANG Min, GAO Junxian, WANG Yanhong, WANG Shuo, LI Ji, LYU Jinze. Performance of microporous-P25 composite TiO2 for volatile organic compounds mineralization[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5523-5528. doi: 10.12030/j.cjee.201612088
Citation: ZHANG Min, GAO Junxian, WANG Yanhong, WANG Shuo, LI Ji, LYU Jinze. Performance of microporous-P25 composite TiO2 for volatile organic compounds mineralization[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5523-5528. doi: 10.12030/j.cjee.201612088
shu

微孔-P25复合二氧化钛矿化挥发性有机物的性能

  • 1.  江南大学环境与土木工程学院, 无锡 214122
  • 2.  江苏省厌氧生物技术重点实验室, 无锡 214122
  • 3.  江苏高校水处理技术与材料协同创新中心, 苏州 215009
  • 收稿日期:  2017-02-15
基金项目:

江苏省青年科学基金资助项目（BK20150126）

绿色催化四川省高校重点实验室开放基金资助项目（LZJ14203）

中央高校基本科研业务费专项（JUSRP11522）

摘要: 矿化效率不足是光催化净化VOCs技术应用的主要瓶颈之一。为提升矿化效率，以十二胺为模板剂，在P25表面构建微孔二氧化钛同质吸附层。利用表面光电压谱、氮气等温吸附-脱附、X射线衍射等研究其结构特性和对甲苯的光催化降解，并探讨微孔TiO2和P25复合比例对催化剂性能的影响。结果发现，随着微孔复合比例增加，比表面积和甲苯平衡吸附量均显著提高。微孔复合比例小导致吸附对甲苯矿化的强化作用不明显，而微孔复合比例过高则造成材料光生载流子分离效率下降。微孔TiO2和P25复合比例为8∶5时，催化剂对甲苯的矿化效率最高，分别是P25和微孔TiO2的3.14和1.85倍。

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