圆球型电石渣反应料处理煤矿酸性废水

邵保钧, 瞿丽雅, 康媞, 马博强, 许璟. 圆球型电石渣反应料处理煤矿酸性废水[J]. 环境工程学报, 2015, 9(8): 3889-3894. doi: 10.12030/j.cjee.20150849
引用本文: 邵保钧, 瞿丽雅, 康媞, 马博强, 许璟. 圆球型电石渣反应料处理煤矿酸性废水[J]. 环境工程学报, 2015, 9(8): 3889-3894. doi: 10.12030/j.cjee.20150849
Shao Baojun, Qu Liya, Kang Ti, Ma Boqiang, Xu Jing. Treatment of acid mine drainager using ball-type carbide slag reaction material[J]. Chinese Journal of Environmental Engineering, 2015, 9(8): 3889-3894. doi: 10.12030/j.cjee.20150849
Citation: Shao Baojun, Qu Liya, Kang Ti, Ma Boqiang, Xu Jing. Treatment of acid mine drainager using ball-type carbide slag reaction material[J]. Chinese Journal of Environmental Engineering, 2015, 9(8): 3889-3894. doi: 10.12030/j.cjee.20150849

圆球型电石渣反应料处理煤矿酸性废水

  • 基金项目:

    贵州省环境保护厅环境科技项目(黔环科[2013]2号)

  • 中图分类号: X703

Treatment of acid mine drainager using ball-type carbide slag reaction material

  • Fund Project:
  • 摘要: 采用电石渣制备成圆球型反应料,通过多级处理式实验装置对煤矿酸性废水进行处理。研究了在不曝气和曝气2组实验情况下处理出水的pH变化特征和反应料去除铁、锰的效果。结果表明,在不曝气组, 当水力停留时间(HRT)为17.6 h,总出水pH值由进水2.84~2.95提高到4.17~11.88,总出水铁平均浓度80.43 mg/L,平均去除率为72.87%,锰平均浓度6.16 mg/L,平均去除率48.21%。在曝气组,当HRT为17.6 h,曝气量为10.50 L/min,总出水pH值由进水2.84~3.00提高到9.10~11.87,总出水铁平均浓度0.03 mg/L,平均去除率为99.99%,锰平均浓度0.14 mg/L,平均去除率为98.72%。因此,利用圆球型电石渣反应料去除煤矿酸性废水中的铁、锰以及提高pH有很好的效果。
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  • [1] 孟君.煤矿酸性废水处理研究进展.贵州化工,2009,34(2):50-51 Meng Jun.A progression on governingof acid coal mine drainage.Gui Zhou Chemical Industry,2009,34(2):50-51(in Chinese)
    [2] 张翔.贵州煤炭的未来什么样?中国煤炭报,2014-8-11(3)
    [3] 丛志远,赵峰华,郑晓燕.煤矿酸性矿井水研究进展.煤矿环境保护,2002,16(5):8-12 Cong Zhiyuan,Zhao Fenghua,Zheng Xiaoyan.Progress in the research of acid mine drainage.Coal Mine Environmental Protection,2002,16(5):8-12(in Chinese)
    [4] Pratt A.R.,Nesbitt H.W.,Muir I. J.Generation of acids from mine waste:Oxidation leaching of pyrrhotite in dilute H2SO4 solutions at pH 3.0. Ge-ochimica et Cosmochimica Acta, 1994,58(23):5147-5159
    [5] Ata Akcil,Soner Koldas.Acid mine drainage(AMD):Causes,treatment and case studies.Journal of Cleaner Production,2006,14:1139-1145
    [6] 张瑞雪,吴攀,杨艳,等.贵州煤矿酸性废水"被动处理"技术的新方法探讨.地球与环境,2010,38(2):250-254 Zhang Ruixue,Wu Pan,Yang Yan,et al.Study new mthods for treating acid mine drainage with passive treatment technology.Earth and Environment,2010,38(2):250-254 (in Chinese)
    [7] 康媞,胡文,陈守应.煤矿酸性废水处理技术的应用研究.环境工程,2012,30(4):46-47 Kang Ti,Hu Wen,Chen Shouying.The applied research of coal mine acid waste water treatment technology.Environmental Engineering,2012,30(4):46-47(in Chinese)
    [8] 董永刚,曹建新,刘飞,等.电石渣理化性质的分析与表征.环境科学与技术,2008,31(9):5-8 Dong Yonggang,Cao Jianxin,Liu Fei,et al.Analysis and characterization of physiochemical property of carbide s-lag.Environmental Science & Technology,2008,31(9):5-8(in Chinese)
    [9] 马国清,李兆乾.浅电石渣的综合利用进展.西南科技大学学报,2005,20(2):50-52 Ma Guoqing,Li Zhaoqian.The development of comprehensive utilization for carbide slag.Journal of Southwest University of Science and Thchnolog-y,2005,20(2):50-52(in Chinese)
    [10] 陈宇辉,陶涛.pH值对地下水除铁除锰影响机理的研究.工业用水与废水,2005,36(5):12-14 Chen Yuhui,Tao Tao.Effects of pH value on removal of iron and manganese from groundwater.Industrial Water & Wastewater,2005,36(5):12-14(in Chinese)
    [11] 杨绍章,吴攀,张瑞雪,等.有氧垂直折流式反应池处理煤矿酸性废水.环境工程学报,2011,5(4):789-794 Yang Shaozhang,Wu Pan,Zhang Ruixue,et al.Treatment of acid mine drainage using aerobic baffoled vertical flow reactor.Chinese Journal of Environment Engineering,2011,5(4):789-794(in Chinese)
    [12] 张杰,戴镇生.地下水除铁除锰现代观.给水排水,1996,22(10):13-16 Zhang Jie,Dai Zhensheng.Iron and manganese removal of groundwater in modern view.Water & Wastewater Engineering,1996,22(10):13-16(in Chinese)
    [13] 徐钟际,徐毓荣,徐玮,等.煤矿废水Fe、Mn处理技术研究.贵州环保科技,1999,5(1):5-9 Xu Zhongji,Xu Yurong,Xu Wei,et al.Research on technology of iron, manganese in the treatment of mine wastewater.Guizhou Environmental Protection Science and Technology,1999,5(1):5-9(in Chinese)
    [14] 肖利萍,刘文颖,梁冰.酸性矿山废水中铁锰氧化反应实验研究.华中师范大学学报(自然科学版),2008,42(3):419-421 Xiao Liping,Liu Wenying,Liang Bing.Experimental study on iron and manganese oxidation in acidic mine dra-inage.Journal of Hua Zhong Normal University(Nature.Science),2008,42(3):419-421(in Chinese)
    [15] Kalin M.,Fyson A.,Wheeler W.N. The chemistry of conventional and alternative treatment systems for the neutralization of acid mine drainage.Science of the Total Environment,2006,366(2-3):395-408
    [16] 李福勤,杨久坡,田甜,等.寺湾矿矿井水除铁锰过程中的影响因素分析.矿业安全与环保,2006,33(2):28-29 Li Fuqin,Yang Jiupo,Tian Tian,et al.Analysison affecting factors in ironand manganese removal process for mine water in siwan mine.Mining Safety & Environmental Protection, 2006,33(2):28-29(in Chinese)
    [17] 张吉库,刘明秀.溶解氧和温度对地下水除铁、锰效果的影响.安全与环境工程,2006,13(1):52-54 Zhang Jiku,Liu Mingxiu.The influence of temperature and dissolved oxygen on removing manganese and iron from groundwater.Safety and Environmental Engineering, 2006,13(1) :52-54(in Chinese)
    [18] 叶春松,曾惠明.改性沸石去除地下水中铁锰实验研究.环境工程学报,2009, 3(7):1237-1240 Ye Chunsong,Zeng Huiming.Experimental study on removal of manganese and ferrous ion inground water by modified zeolite.Chinese Journal of Environment Engineering,2009,3(7):1237-1240(in Chinese)
    [19] Charles A.Cravotta III,Mary Kay Trahan. Limestone drains to increase pH and remove dissolved metals from acidic mine drainage.Applied Geochemistry,1999,14:581-606
    [20] 郭娟.煤矿酸性矿井水除铁锰主要影响因素研究.能源技术与管理,2013,38(2):111-113 Guo Juan.Study on the main influencing factors of iron and manganese in acid mine water.Energy Technology a-nd Management,2013,38(2):111-113(in Chinese)
    [21] Robert S.H.,Robert W.N.,Robert L.P.K.Passive treatment of acid mine drainage.U.S.Bureau of Mines IC 9389,1994,35
    [22] 熊玲,张瑞雪,吴攀,等.碳酸盐岩处理煤矿酸性废水的试验研究.水处理技术,2010,36(8):45-48 Xiong Ling,Zhang Ruixue,Wu Pan.et al.Experimental study on acid coal mine drainage treatment with carbonate.Technology of Water Treatment,2010,36(8):45-48(in Chinese)
    [23] 徐根良,陈雪明,陈海辉.废渣法处理酸性重金属废水技术研究.水处理技术,1994,20(2):116-120 Xu Genliang,Chen Xueming,Chen Haihui.Study on treatment of acidicheavy metal wastewater technology residue method.Technology of Water Treatment,1994,20(2):116-120(in Chinese)
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  • 收稿日期:  2014-12-03
  • 刊出日期:  2015-08-13
邵保钧, 瞿丽雅, 康媞, 马博强, 许璟. 圆球型电石渣反应料处理煤矿酸性废水[J]. 环境工程学报, 2015, 9(8): 3889-3894. doi: 10.12030/j.cjee.20150849
引用本文: 邵保钧, 瞿丽雅, 康媞, 马博强, 许璟. 圆球型电石渣反应料处理煤矿酸性废水[J]. 环境工程学报, 2015, 9(8): 3889-3894. doi: 10.12030/j.cjee.20150849
Shao Baojun, Qu Liya, Kang Ti, Ma Boqiang, Xu Jing. Treatment of acid mine drainager using ball-type carbide slag reaction material[J]. Chinese Journal of Environmental Engineering, 2015, 9(8): 3889-3894. doi: 10.12030/j.cjee.20150849
Citation: Shao Baojun, Qu Liya, Kang Ti, Ma Boqiang, Xu Jing. Treatment of acid mine drainager using ball-type carbide slag reaction material[J]. Chinese Journal of Environmental Engineering, 2015, 9(8): 3889-3894. doi: 10.12030/j.cjee.20150849

圆球型电石渣反应料处理煤矿酸性废水

  • 1.  贵州师范大学地理与环境科学学院, 贵阳 550001
  • 2.  贵州省楚天环境工程技术研究中心, 贵阳 550081
  • 3.  贵州省环境保护厅, 贵阳 550002
基金项目:

贵州省环境保护厅环境科技项目(黔环科[2013]2号)

摘要: 采用电石渣制备成圆球型反应料,通过多级处理式实验装置对煤矿酸性废水进行处理。研究了在不曝气和曝气2组实验情况下处理出水的pH变化特征和反应料去除铁、锰的效果。结果表明,在不曝气组, 当水力停留时间(HRT)为17.6 h,总出水pH值由进水2.84~2.95提高到4.17~11.88,总出水铁平均浓度80.43 mg/L,平均去除率为72.87%,锰平均浓度6.16 mg/L,平均去除率48.21%。在曝气组,当HRT为17.6 h,曝气量为10.50 L/min,总出水pH值由进水2.84~3.00提高到9.10~11.87,总出水铁平均浓度0.03 mg/L,平均去除率为99.99%,锰平均浓度0.14 mg/L,平均去除率为98.72%。因此,利用圆球型电石渣反应料去除煤矿酸性废水中的铁、锰以及提高pH有很好的效果。

English Abstract

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